journal article·2004-05-01

Kinetics of the graphite?diamond transformation in aqueous fluid determined by in-situ X-ray diffractions at high pressures and temperatures

T. Okada, W. Utsumi, H. Kaneko, V. Turkevich, N. Hamaya, O. Shimomura

Physics and Chemistry of Minerals· Volume 31· Issue 4
Publisher page

Abstract

The graphite-diamond transformation was investigated by in situ time-resolved X-ray diffraction experiments using aqueous fluid containing dissolved MgO as the diamond-forming catalyst under conditions of 6.6–8.9 GPa and 1400–1835 °C. The transformed volume fractions of diamond as a function of time under various pressure-temperature conditions were obtained and analyzed using the JMAK rate equation. Variations in the nucleation and growth processes during diamond formation as a function of pressure and temperature were clarified.
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Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Force Microscopy Techniques and Applications · High-pressure geophysics and materials

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