Neutron diffraction study of aluminous hydroxide δ-AlOOD
Source abstract
Abstract
We have determined the position of deuterium atoms in δ-AlOOD by neutron powder diffraction at ambient pressure. As previously reported by theoretical and experimental studies, the deuterium atoms are located in the tunnel formed by the chains of AlO6 octahedra. The data are best fit with the P21 nm structure, producing bond lengths of D–O1 of 1.552(2) A, O2–D of 1.020(2) A and O1–O2 of 2.571(2). This study confirms that the hydrogen bond is asymmetric at ambient conditions in agreement with recent single-crystal synchrotron study for δ-AlOOH.
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Research context
OpenAlex topics: Advanced Condensed Matter Physics · Nuclear materials and radiation effects · X-ray Diffraction in Crystallography
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References (19)
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