Enhancement of magnetocaloric effect in all-d-metal Heusler Mn52.6Ni30.5Co7.8Ti9.1/PVA/PET flexible composite by mechanical strains
Source abstract
Abstract
The prominent enhancement of magnetocaloric effect (MCE) and the extension of effective magnetic refrigeration temperature region near room temperature (RT) are urgent needs for efficient and clean refrigeration technologies. Here, we report that a flexible composite is made up of all- d -metal Heusler ferromagnetic shape memory alloys (FSMAs) Mn 52.6Ni 30.5Co 7.8Ti 9.1 (Mn-Ni-Co-Ti) ribbon and polyethylene terephthalate (PET) substrate with polyvinyl alcohol (PVA) coating, exhibiting a tunable martensitic transformation (MT) by applying mechanical strains and accompanying a remarkably enhanced MCE near RT. The MT temperature of the Mn-Ni-Co-Ti/PVA/PET flexible composite obviously shifts, leading to the bidirectional control of the magnetization difference (ΔM) with the increase of tensile/compressive strains. Especially, the magnetic entropy change (ΔS M ) and refrigeration capacity (RC) are remarkably improved under the tensile strain (ε = 6.0%) state. As a result, the MCE can be controlled and the effective magnetic refrigeration temperature region can be expanded by adjusting the mechanical strains in the Mn-Ni-Co-Ti/PVA/PET flexible composite, which is beneficial to improve the refrigerating efficiency in promising applications of magnetic devices.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Shape Memory Alloy Transformations · Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (53)
Show source-provided references
1. Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration10.1016/j.jallcom.2020.153810 ↗
2. Magnetic properties and excellent cryogenic magnetocaloric performances in b-site ordered RE2ZnMnO6 (RE = Gd, Dy and Ho) perovskites10.1016/j.actamat.2020.05.036 ↗
3. Achievement of giant cryogenic refrigerant capacity in quinary rare-earths based high-entropy amorphous alloy10.1016/j.jmst.2021.06.028 ↗
4. Large magnetocaloric effect in gadolinium borotungstate Gd3BWO910.1039/D0TC02449J ↗
5. Cryogenic magnetocaloric effect in distorted double-perovskite Gd2ZnTiO610.1039/D1TC01789F ↗
6. Materials with giant mechanocaloric effects: cooling by strength10.1002/adma.201603607 ↗
7. Recent progress in exploring magnetocaloric materials10.1002/adma.200901072 ↗
8. Review of the structural, magnetic and magnetocaloric properties in ternary rare earth RE2T2X type intermetallic compounds10.1016/j.jallcom.2019.02.175 ↗
9. Glass forming ability, magnetic properties and cryogenic magnetocaloric effects in RE60Co20Al20 (RE = Ho, Er, Tm) amorphous ribbons10.1016/j.jallcom.2021.162633 ↗
10. Polymer-buried van der waals magnets for promising wearable room-temperature spintronics10.1039/D1MH01439K ↗
11. Martensitic transformation and related magnetic effects in Ni-Mn-based ferromagnetic shape memory alloys
12. Enhanced magnetocaloric effects driven by two successive magneto-structural transformations in Ni55.5Mn17.8Ga26.7 alloy under hydrostatic pressure10.1016/j.ssc.2019.113691 ↗
13. Magnetocaloric effect and its relation to shape-memory properties in ferromagnetic Heusler alloys10.1088/0953-8984/21/23/233201 ↗
14. Colossal elastocaloric effect in ferroelastic Ni-Mn-Ti alloys10.1103/PhysRevLett.122.255703 ↗
15. Magnetostructural martensitic transformations with large volume changes and magneto-strains in all-d-metal Heusler alloys10.1063/1.4961382 ↗
16. Giant elastocaloric effect in a Mn-rich Ni44Mn46Sn10 directionally solidified alloy
17. Large refrigeration capacity in a Ni48Co1Mn37In14 polycrystalline alloy with low thermal hysteresis10.1016/j.intermet.2020.106888 ↗
18. Designed materials with the giant magnetocaloric effect near room temperature10.1016/j.actamat.2019.09.023 ↗
19. Tuning martensite transformation behavior and magneto-caloric effect in Ni44Mn36In14Co6 alloy through doping the fifth element Cu10.1016/j.jallcom.2019.153150 ↗
20. Dynamic observation of joule heating-induced structural and domain transformation in smart shape-memory alloy10.1016/j.actamat.2020.01.006 ↗
21. Effect of solidification rate on martensitic transformation behavior and adiabatic magnetocaloric effect of Ni50Mn35In15 ribbons10.1016/j.jallcom.2018.03.074 ↗
22. Giant solid-state barocaloric effect in the Ni-Mn-In magnetic shape-memory alloy10.1038/nmat2731 ↗
23. Achieving a broad refrigeration temperature region through the combination of successive caloric effects in a multiferroic Ni50Mn35In15 alloy10.1016/j.actamat.2020.03.043 ↗
24. Magnetocaloric and barocaloric effects associated with two successive magnetostructural transformations in Ni55.5Mn17.8Ga26.7 alloy10.1016/j.jallcom.2019.153356 ↗
25. Impact of annealing on the martensitic transformation and magnetocaloric properties in all-3d-metal Mn50Ni32Co8Ti10 alloy ribbons10.1016/j.intermet.2020.106882 ↗
26. Electronic structure, magnetic, optical and thermodynamic properties of Ni2Mn1−xRexSn and NiMn1−xRexSn Heusler alloys-ab-initio study10.1016/j.jallcom.2019.06.223 ↗
27. Giant and reversible room-temperature magnetocaloric effect in Ti-doped Ni-Co-Mn-Sn magnetic shape memory alloys10.1016/j.actamat.2017.06.010 ↗
28. Low-pressure-induced giant barocaloric effect in an all-d-metal Heusler Ni35.5Co14.5Mn35Ti15 magnetic shape memory alloy
29. Pressure induced magnetic and magnetocaloric properties in NiCoMnSb Heusler alloy10.1063/1.3208064 ↗
30. High sensitivity on caloric effects induced by stress or magnetic field in a polycrystalline Ni-Mn-In-Co-Cu shape-memory alloy10.1016/j.scriptamat.2019.03.005 ↗
31. Achievement of a reversible giant magnetocaloric effect via exerting external hydrostatic pressure on a Ni45Co5Mn35In15 metamagnetic Heusler alloy
32. Effects of hydrostatic pressure on the magnetism and martensitic transition of Ni-Mn-In magnetic superelastic alloys10.1063/1.2830999 ↗
33. Electric field control of the magnetocaloric effect10.1002/adma.201404725 ↗
34. Nonvolatile manipulation of the magnetocaloric effect in Ni43Co7Mn39Sn11/(011)PMN-PT composite by electric fields10.1016/j.scriptamat.2019.03.041 ↗
35. Efficient strain modulation of 2D materials via polymer encapsulation10.1038/s41467-020-15023-3 ↗
36. Two-dimensional magneto-photo conductivity in non-van der waals manganese selenide10.1039/D1MH00009H ↗
37. Strain-mediated insulator-metal transition in topotactically hydro-reduced SrFeO210.1007/s11433-021-1713-4 ↗
38. Strain-sensitive magnetization reversal of a van der waals magnet
39. Flexible quasi-two-dimensional CoFe2O4 epitaxial thin films for continuous strain tuning of magnetic properties10.1021/acsnano.7b02637 ↗
40. Mechanical strain manipulation of exchange bias field and spin dynamics in FeCo/IrMn multilayers grown on flexible substrates10.1021/acsami.8b21421 ↗
41. Strain control of phase transition and exchange bias in flexible Heusler alloy thin films10.1021/acsami.1c03701 ↗
42. Enhanced stress-invariance of magnetization direction in magnetic thin films10.1063/1.4990571 ↗
43. Flexible epsilon iron oxide thin films10.1021/acsami.0c23104 ↗
44. Torsional refrigeration by twisted, coiled, and supercoiled fibers10.1126/science.aax6182 ↗
45. Realization of multifunctional shape-memory ferromagnets in all-d-metal Heusler phases10.1063/1.4927058 ↗
46. Martensitic transformation and giant magneto-functional properties in all-d-metal Ni-Co-Mn-Ti alloy ribbons10.1016/j.jallcom.2019.03.173 ↗
47. Giant enhancement of the magnetocaloric response in Ni-Co-Mn-Ti by rapid solidification10.1016/j.actamat.2019.05.004 ↗
48. Influence of chemical substitution, magnetic field, and hydrostatic pressure effect on martensitic and intermartensitic transition in bulk Ni49−xCuxMn38Sn13 (0.5≤ x ≤ 2) Heusler alloys10.1063/1.4867234 ↗
49. Magnetic-field-induced metamagnetic reverse martensitic transformation and magnetocaloric effect in all-d-metal Ni36.0Co14.0Mn35.7Ti14.3 alloy ribbons10.1016/j.intermet.2019.106472 ↗
50. Tuning the reversible magnetocaloric effect in Ni-Mn-In-based alloys through Co and Cu Co-doping10.1002/aelm.201800845 ↗
51. Giant low-field magnetocaloric effect in Si alloyed Ni-Co-Mn-In alloys10.1016/j.scriptamat.2018.09.029 ↗
52. Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width10.1038/nmat1593 ↗
53. Hydrostatic pressure effect on the martensitic transition, magnetic, and magnetocaloric properties in Ni50−XMn37+XSn13 Heusler alloys10.1063/1.3651375 ↗