journal article·2012-11Open access

Co3O4 nanoparticles on the surface of halloysite nanotubes

Yi Zhang, Huaming Yang

Physics and Chemistry of Minerals· Volume 39· Issue 10

Abstract

Co3O4 nanoparticles were successfully deposited on the surface of natural halloysite nanotubes (HNTs) to produce Co3O4/HNTs composites. The structure and morphology of the samples were characterized using X-ray diffraction, field-emission scanning electron microscope, transmission electron microscope and Fourier transform infrared. The results indicated that Co3O4 nanoparticles were uniformly attached on the surface of HNTs with narrow size distribution. Co3O4/HNTs exhibited an excellent photocatalytic efficiency for degradation of methyl blue under UV light, better than Co3O4 and HNTs mixture, HNTs and pure Co3O4. The mechanism of enhanced photocatalytic activity of Co3O4/HNTs was also proposed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Clay minerals and soil interactions · Iron oxide chemistry and applications · Mineralogy and Gemology Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Abdullayev E, Price R, Shchukin D, Lvov Y (2009) Halloysite tubes as nanocontainers for anticorrosion coating with benzotriazole. ACS Appl Mater Interfaces 1:1437–144310.1021/am9002028 ↗
2. Artero V, Chavarot-Kerlidou M, Fontecave M (2011) Splitting water with cobalt. Angew Chem Int Ed 50:7238–726610.1002/anie.201007987 ↗
3. Azadi P, Farnood R, Meier E (2010) Preparation of multiwalled carbon nanotube-supported nickel catalysts using incipient wetness method. J Phys Chem A 114:3962–396810.1021/jp907403b ↗
4. Cao AM, Hu JS, Liang HP, Song WG, Wan LJ, He XL, Gao XG, Xia SH (2006) Hierarchically structured cobalt oxide (Co3O4) the morphology control and its potential in sensors. J Phys Chem B 110:15858–1586310.1021/jp0632438 ↗
5. Casas-Cabanas M, Binotto G, Larcher D, Lecup A, Giordani V, Tarascon J (2009) Defect chemistry and catalytic activity of nanosized Co3O4. Chem Mater 174:1939–194710.1021/cm900328g ↗
6. Chen L, Yin S-F, Huang R, Zhang Q, Luo SL, Au CT (2012) Hollow peanut-like m-BiVO4: facile synthesis and solar-light-induced photocatalytic property. CrystEngComm 14:4217–422210.1039/c2ce06684j ↗
7. Delannoy L, El Hassan N, Musi A, Le To NN, Krafft J-M, Louis C (2006) Preparation of supported gold nanoparticles by a modified incipient wetness impregnation method. J Phys Chem B 110:22471–2247810.1021/jp062130l ↗
8. Du ML, Guo BC, Jia DM (2010) Newly emerging applications of halloysite nanotubes: a review. Polym Int 59:574–58210.1002/pi.2754 ↗
9. Endo M, Strano MS, Ajayan PM (2008) Potential applications of carbon nanotubes. Carbon Nanotubes 111:13–6210.1007/978-3-540-72865-8_2 ↗
10. Gualtieri AF (2001) Synthesis of sodium zeolites from a natural halloysite. Phys Chem Miner 28:719–72810.1007/s002690100197 ↗
11. Guimarães L, Enyashin AN, Seifert G, Duarte HA (2010) Structural, electronic, and mechanical properties of single-walled halloysite nanotube models. J Phys Chem C 114:11358–1136310.1021/jp100902e ↗
12. Hu PW, Yang HM (2012) Sb-SnO2 nanoparticles onto kaolinite rods: assembling process and interfacial investigation. Phys Chem Miner 39:339–34910.1007/s00269-012-0492-1 ↗
13. Hu LH, Peng Q, Li YD (2008) Selective synthesis of Co3O4 nanocrystal with different shape and crystal plane effect on catalytic property for methane combustion. J Am Chem Soc 130:16136–1613710.1021/ja806400e ↗
14. Hughes AD, King MR (2010) Use of naturally occurring halloysite nanotubes for enhanced capture of flowing cells. Langmuir 26:12155–1216410.1021/la101179y ↗
15. Jiao F, Frei H (2009) Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. Angew Chem Int Ed 48:1841–184410.1002/anie.200805534 ↗
16. Joussein E, Pettit S, Churchman J, Theng B, Righi D, Delvaux B (2005) Halloysite clay minerals a review. Clay Miner 40:383–42610.1180/0009855054040180 ↗
17. Levis SR, Deasy PB (2002) Characterisation of halloysite for use as a microtubular drug delivery system. Int J Pharm 243:125–13410.1016/S0378-5173(02)00274-0 ↗
18. Li W, Jung H, Hoa ND, Kim D, Hong S-K, Kim H (2010) Nanocomposite of cobalt oxide nanocrystals and single-walled carbon nanotubes for a gas sensor application. Sens Actuators B Chem 150:160–16610.1016/j.snb.2010.07.023 ↗
19. Liang YY, Li YG, Wang HL, Zhou JG, Wang J, Regier T, Dai HJ (2011) Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. Nat Mater 10:780–78610.1038/nmat3087 ↗
20. Liu B, Aydil ES (2009) Growth of oriented single-crystalline rutile TiO2 nanorods on transparent conducting substrates for dye-sensitized solar cells. J Am Chem Soc 131:3985–399010.1021/ja8078972 ↗
21. Lvov YM, Shchukin DG, Möhwald H, Price RR (2008) Halloysite clay nanotubes for controlled release of protective agents. ACS Nano 2:814–82010.1021/nn800259q ↗
22. Natile MM, Glisenti A (2002) Study of surface reactivity of cobalt oxides interaction with methanol. Langmuir 14:3090–3099
23. Pauporté T, Mendoza L, Cassir M, Bernard MC, Chivot J (2005) Direct low-temperature deposition of crystallized CoOOH films by potentiostatic electrolysis. J Electrochem Soc 152:C49–C5310.1149/1.1842044 ↗
24. Shchukin DG, Lamaka SV, Yasakau KA, Zheludkevich ML, Ferreira MGS, Mohwald H (2008) Active anticorrosion coatings with halloysite nanocontainers. J Phys Chem C 112:958–96410.1021/jp076188r ↗
25. Takada S, Fujii M, Kohiki S (2001) Intraparticle magnetic properties of Co3O4 nanocrystals. Nano Lett 1:379–38210.1021/nl015538x ↗
26. Veerabadran NG, Mongayt D, Torchilin V, Price RR, Lvov YM (2009) Organized shells on clay nanotubes for controlled release of macromolecules. Macromol Rapid Commun 30:99–10310.1002/marc.200800510 ↗
27. Wang L, Chen J, Ge L, Zhu Z, Rudolph V (2011) Halloysite-nanotube-supported ru nanoparticles for ammonia catalytic decomposition to produce COx-free hydrogen. Energy Fuels 25:3408–341610.1021/ef200719v ↗
28. Woan K, Pyrgiotakis G, Sigmund W (2009) Photocatalytic carbon-nanotube-TiO2 composites. Adv Mater 21:2233–223910.1002/adma.200802738 ↗
29. Wöllenstein J, Burgmair M, Plescher G, Sulima T, Hildenbrand J, Böttner H, Eisele I (2003) Cobalt oxide based gas sensors on silicon substrate for operation at low temperatures. Sens Actuators B Chem 93:442–44810.1016/S0925-4005(03)00168-0 ↗
30. Yeo BS, Bell AT (2011) Enhanced activity of gold-supported cobalt oxide for the electrochemical evolution of oxygen. J Am Chem Soc 133:5587–559310.1021/ja200559j ↗
31. Zhai R, Zhang B, Liu L, Xie YD, Zhang HQ, Liu JD (2010) Immobilization of enzyme biocatalyst on natural halloysite nanotubes. Catal Commun 12:259–26310.1016/j.catcom.2010.09.030 ↗
32. Zhang Y, Yang HM (2012) Halloysite nanotubes coated with magnetic nanoparticles. Appl Clay Sci 56:97–10210.1016/j.clay.2011.11.028 ↗