journal article·2025-04

Polyoxometalates as multifunctional electrolyte and electrode materials: Innovations in supercapacitors, sensors, and batteries

Chou-Yi Hsu, Anjan Kumar, Prakash Kanjariya, Asha Rajiv, Aditya Kashyap, Helen Merina Albert, Sumit Pokhriyal, M. Dehghanipour

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Polyoxometalates: Synthesis and Applications · Advanced Nanomaterials in Catalysis · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Q. Li, L. Zhang, J. Dai, H. Tang, Q. Li, H. Xue, H. Pang, Polyoxometalate-based materials for advanced electrochemical energy conversion and storage, 351 (2018) 441-461.10.1016/j.cej.2018.06.074 ↗
2. Estimating and tracking the remaining carbon budget for stringent climate
3. Lithium batteries: 50 years of advances to address the next 20 years of climate issues
4. M. Najafloo, L. Naji, Binary solvent-reinforced poly (vinyl alcohol)/sodium alginate double network hydrogel as a highly ion-conducting, resilient, and self-healing gel polymer electrolyte for flexible supercapacitors, 279 (2024) 135008.10.1016/j.ijbiomac.2024.135008 ↗
5. Horn · Dubal · 2021 · 14 · 1652
6. Polyoxometalate–Dicarboxylate Hybrid Dimers with {SiW10Cr2} Nodes: Syntheses, Structures, and Mass Spectrometric
7. Yu · Multiscale assembly of polyoxometalates: from clusters to materials · 2023 · 2 · 20
8. Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical
9. Weinstock · Dioxygen in polyoxometalate mediated reactions · 2017 · 118 · 2680
10. Polyoxometalate clusters: inorganic ligands for functional
11. Miras · Engineering polyoxometalates with emergent properties · 2012 · 41 · 7403
12. Kondinski · Keggin structure, quō vādis? · 2018 · 6 · 346
13. F. Berry, G. Derrick, M. Mortimer, Identification and characterisation of stable phases of silicotungstic acid, H4SiW12O40· nH2O, 68 (2014) 17-22.10.1016/j.poly.2013.10.014 ↗
14. Duval · Synthesis of a large dodecameric cerium cluster stabilized by the [SiW9O34] 10− polyoxometalate · 2017 · 83 · 52
15. Noncovalent Complexes Formed between Metal-Substituted Polyoxometalates and Hen Egg White
16. B. Dawson, The structure of the 9 (18)-heteropoly anion in potassium 9 (18)-tungstophosphate, K6 (P2W18O62). 14H2O, 6 (2) (1953) 113-126.10.1107/S0365110X53000466 ↗
17. Synthesis and Characterization of Polyvanadium and Heteropoly-Tungsten Based Inorganic Wells Dawson Polyoxometalates
18. Polyoxometalates as promising materials for electrochromic
19. Lindqvist · On the structure of the paratungstate ion · 1952 · 5 · 667
20. Ligand Substituent Effects on the Electronic Properties of Lindqvist-Type Polyoxometalate Multi-Level-Switches in the Gas Phase
21. Huang · A new family of polyoxometalates: tris-functionalized lindqvist-type hexatungstovanadates · 2021 · 60 · 545
22. Subintoro · Structural and vibrational properties of lanthanide Lindqvist polyoxometalate complexes · 2024 · 53 · 9526
23. One-pot synthesis of polyoxometalate decorated polyindole for energy storage
24. Synthesis and characterization of polyoxometalate/graphene oxide nanocomposites for
25. Ruiz · Hybrid electrodes based on polyoxometalate–carbon materials for electrochemical supercapacitors · 2012 · 24 · 35
26. Mu · The composite material based on Dawson-type polyoxometalate and activated carbon as the supercapacitor electrode · 2015 · 55 · 149
27. Chu · A polyoxometalate based electrochemical sensor for efficient detection of L-cysteine · 2022 · 4 · 138
28. Nanostructured Polyoxometalate-Based Heterogeneous Electrode Materials for Electrochemical
29. Polyoxometalate-based electrolyte materials in redox flow batteries
30. Sustainable Self-Healing Gel Polymer Electrolyte Based on Water-in-Deep Eutectic Solvent for Flexible
31. Polyoxometalate/hydroquinone dual redox electrolyte for hybrid energy storage
32. A novel SWCNT-polyoxometalate nanohybrid material as an electrode for electrochemical
33. Polyoxometalate Li3PW12O40 and Li3PMo12O40 Electrolytes for High-energy All-solid-state Lithium
34. J. Friedl, M.V. Holland-Cunz, F. Cording, F.L. Pfanschilling, C. Wills, W. McFarlane, B. Schricker, R. Fleck, H. Wolfschmidt, U. Stimming, E. Science, Asymmetric polyoxometalate electrolytes for advanced redox flow batteries, 11 (10) (2018) 3010-3018.10.1039/C8EE00422F ↗
35. Ni · Self-assembled polyoxometalate nanodots as bidirectional cluster catalysts for polysulfide/sulfide redox conversion in lithium–sulfur batteries · 2021 · 15 · 12222
36. Song · Rapid and highly sensitive detection of formaldehyde gas via a polyoxometalate–CuBi2O4 composite gas sensor · 2024 · 3 · 9140053
37. M. Zhang, Y. Yang, D. Li, H. Yu, X. Dong, T. Wang, First polyoxometalate-modified SnS2 composite nanostructure gas sensor toward enhanced sensitivity and high selectivity for NO2 detection, 409 (2024) 135641.10.1016/j.snb.2024.135641 ↗
38. R.-L. Liu, Y. Chen, X. Su, W. Zhu, Z. Liu, Y. Chen, D.-Y. Wang, G. Li, Proton conductive polyoxometalates, 522 (2025) 216224.10.1016/j.ccr.2024.216224 ↗
39. Wei · Adhesive, conductive, self-healing, and antibacterial hydrogel based on chitosan–polyoxometalate complexes for wearable strain sensor · 2020 · 2 · 2541
40. Vannathan · High-performance electrochemical supercapacitors based on polyoxometalate integrated into polyaniline and activated carbon nanohybrid · 2023 · 29 · 4227
41. Compounds, Synergistic effects of polyoxometalate with MoS2 sheets on multi-walled carbon nanotubes backbone for high-performance
42. P. Gómez-Romero, J.A. Asensio, S. Borrós, Hybrid proton-conducting membranes for polymer electrolyte fuel cells: phosphomolybdic acid doped poly (2, 5-benzimidazole)—(ABPBI-H3PMo12O40), 50 (24) (2005) 4715-4720.10.1016/j.electacta.2005.02.029 ↗
43. Zhai · Polyoxometalate–Polymer hybrid materials as proton exchange membranes for fuel cell applications · 2019 · 24 · 3425
44. Cui · In situ synthesized heteropoly acid/polyaniline/graphene nanocomposites to simultaneously boost both double layer-and pseudo-capacitance for supercapacitors · 2012 · 14 · 12823
45. rGO Functionalized with a Highly Electronegative Keplerate-Type Polyoxometalate for High-Energy-Density Aqueous Asymmetric
46. Solid asymmetric electrochemical capacitors using proton-conducting polymer
47. Gao · Proton-conducting polymer electrolytes and their applications in solid supercapacitors: a review · 2014 · 4 · 33091
48. Meng · Proton-conducting crystalline porous materials · 2017 · 46 · 464
49. Nakamura · Electrical conductivities of some hydrates of dodecamolybdophosphoric acid and dodecatungstophosphoric acid and their mixed crystals · 1982 · 17 · 231
50. Cai · Synthesis and high proton conductive performance of a quaternary vanadomolybdotungstosilicic heteropoly acid · 2016 · 45 · 14238
51. Bocarsly · 2011
52. Slade · ac and dc conductivity studies of pelletised 12-tungstophosphoric acid and 12-tungstosilicic acid hexahydrates · 1990 · 38 · 207
53. Gao · AH5BW12O40–polyvinyl alcohol polymer electrolyte and its application in solid supercapacitors · 2016 · 4 · 9585
54. Cheng · Proton-conducting polyoxometalates as redox electrolytes synergistically boosting the performance of self-healing solid-state supercapacitors with polyaniline · 2021 · 3 · 1649
55. Yuan · A polyoxometalate-based polymer electrolyte with an improved electrode interface and ion conductivity for high-safety all-solid-state batteries · 2019 · 7 · 15924
56. M.J. da Silva, C.M. de Oliveira, Catalysis by Keggin heteropolyacid salts, 7 (1) (2018) 26-34.10.2174/2211544707666171219161414 ↗
57. Coronel · Lacunar keggin heteropolyacid salts: soluble, solid and solid-supported catalysts · 2018 · 29 · 195
58. Wu · Reversible phase transformation-type electrolyte based on layered shape polyoxometalate · 2014 · 2 · 5780
59. Tong · Hybrid gel electrolytes derived from keggin-type polyoxometalates and imidazolium-based ionic liquid with enhanced electrochemical stability and fast ionic conductivity · 2015 · 119 · 7621
60. Chen · Polypyrrole–polyoxometalate/reduced graphene oxide ternary nanohybrids for flexible, all-solid-state supercapacitors · 2015 · 51 · 12377
61. Lian · Solid polymer electrochemical capacitors using heteropoly acid electrolytes · 2009 · 11 · 22
62. Tuning Redox Active Polyoxometalates for Efficient Electron-Coupled Proton-Buffer-Mediated Water
63. He · Electrochemically active phosphotungstic acid assisted prevention of graphene restacking for high-capacitance supercapacitors · 2018 · 1 · 88
64. Gao · Proton conducting H5BW12O40 electrolyte for solid supercapacitors · 2015 · 3 · 21511
65. Rausch · Decoupled catalytic hydrogen evolution from a molecular metal oxide redox mediator in water splitting · 2014 · 345 · 1326
66. Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem
67. Li · Recent advances in transition-metal-containing Keggin-type polyoxometalate-based coordination polymers · 2019 · 392 · 49
68. Transition metal substitution effects on metal-to-polyoxometalate charge
69. Recent advances in paramagnetic-TM-substituted polyoxometalates (TM= Mn, Fe, Co, Ni
70. Zeng · Transition metal-substituted polyoxometalate-ionic liquids with remarkable flame retardancy performance · 2024 · 11 · 3604
71. Anwar · Transition metal ion-substituted polyoxometalates entrapped in polypyrrole as an electrochemical sensor for hydrogen peroxide · 2012 · 137 · 624
72. Temperature-dependent gel-type ionic liquid compounds based on vanadium-substituted polyoxometalates with
73. Zhang · Polyoxometalate-based materials for sustainable and clean energy conversion and storage · 2019 · 1 · 100021
74. Horn · Polyoxometalates (POMs): from electroactive clusters to energy materials · 2021 · 14 · 1652
75. Yamada · Keggin-type heteropolyacids as electrode materials for electrochemical supercapacitors · 1998 · 145 · 737
76. Zhang · State-of-the-art advances in the syntheses, structures, and applications of polyoxometalate-based metal–organic frameworks · 2023 · 2 · 9140017
77. Gao · Spherical phosphomolybdic acid immobilized on graphene oxide nanosheets as an efficient electrochemical sensor for detection of diphenylamine · 2020 · 158 · 105158
78. Confinement of PMo 12 in hollow SiO 2-PMo 12@ rGO nanospheres for high-performance lithium
79. Cheng · Recent advances in supramolecular self-assembly derived materials for high-performance supercapacitors · 2023 · 5 · 2394
80. Dubal · Asymmetric supercapacitors based on reduced graphene oxide with different polyoxometalates as positive and negative electrodes · 2017 · 10 · 2742
81. A. Dehnavi, A. Soleymanpour, Highly sensitive voltammetric electrode for the trace measurement of methyldopa based on a pencil graphite modified with phosphomolibdate/graphene oxide, 157 (2020) 104969.10.1016/j.microc.2020.104969 ↗
82. Polyoxometalate-coupled graphene via polymeric ionic liquid linker for
83. Huang · Pyrene-Anderson-modified CNTs as anode materials for lithium-ion batteries · 2015 · 21 · 18799
84. Maity · Electrochemical performance of activated carbon-supported vanadomolybdates electrodes for energy conversion · 2021 · 47 · 27132
85. Single-Molecule Confinement Induced Intrinsic Multi-Electron Redox-Activity to Enhance Supercapacitor
86. A. Ambrosi, C.K. Chua, A. Bonanni, M.Pumera, Electrochemistry of graphene and related materials, 114(14) (2014) 7150-7188.10.1021/cr500023c ↗
87. Oghli · Polyoxometalate/reduced graphene oxide modified pencil graphite sensor for the electrochemical trace determination of paroxetine in biological and pharmaceutical media · 2020 · 108 · 110407
88. W. Chen, L. Huang, J. Hu, T. Li, F. Jia, Y. Song, Connecting carbon nanotubes to polyoxometalate clusters for engineering high-performance anode materials, 16(36) (2014) 19668-19673.10.1039/C4CP03202K ↗
89. H. Hu, Y. Yang, X. Jiang, J. Wang, D. Cao, L. He, W. Chen, Y. Song, Double-Shelled Hollow SiO2@ N-C Nanofiber Boosts the Lithium Storage Performance of [PMo12O40] 3−, 27(53) (2021) 13367-13375.10.1002/chem.202101638 ↗
90. Selective separation of single-walled carbon nanotubes in aqueous solution by assembling redox
91. Insight into the Structural Variation and Sodium Storage Behavior of Polyoxometalates Encapsulated within Single-Walled Carbon
92. D. Zhang, H. Ma, Y. Chen, H. Pang, Y. Yu, Amperometric detection of nitrite based on Dawson-type vanodotungstophosphate and carbon nanotubes, 792 (2013) 35-44.10.1016/j.aca.2013.07.010 ↗
93. Boussema · Polyoxometalate [PMo11O39] 7−/carbon nanocomposites for sensitive amperometric detection of nitrite · 2016 · 222 · 402
94. Hybrid energy storage: high voltage aqueous supercapacitors based on activated carbon–phosphotungstate hybrid
95. Palomino · Influence of texture in hybrid carbon-phosphomolybdic acid materials on their performance as electrodes in supercapacitors · 2017 · 111 · 74
96. M. Wang, Y. Yu, M. Cui, X. Cao, W. Liu, C. Wu, X. Liu, T. Zhang, Y. Huang, Development of polyoxometalate-anchored 3D hybrid hydrogel for high-performance flexible pseudo-solid-state supercapacitor, 329 (2020) 135181.10.1016/j.electacta.2019.135181 ↗
97. Advanced materials for printed wearable electrochemical devices
98. Polyoxometalate–conductive polymer composites for energy conversion, energy storage and nanostructured
99. Recent advances in separation membranes based on porous organic molecular
100. Zeb · Advanced developments in nonstoichiometric tungsten oxides for electrochromic applications · 2021 · 2 · 6839