journal article·2024-11Open access

The effect of in-situ ZrO2 on compressive properties of molybdenum-rhenium alloys and strengthening mechanism

Qiurui Wu, Lu Yang, Zhaoning Xu, Xun Dai, Ming Shu, Shizhong Wei, Jinshu Wang

Abstract

Molybdenum-rhenium alloys has a low recrystallization temperature and insufficient high temperature strength , making it unable to serve as structural parts for a long time in high temperature environments above 1300 ℃ for a long time. ZrO 2 dispersion strengthened Mo-Re alloy was prepared by liquid-liquid doping combined with hydrogen reduction . The morphology and distribution of ZrO 2 were adjusted by liquid-liquid doping-coprecipitation-codeposition technology, with ZrO 2 dispersed in the grain of Mo-Re alloy to refine the grain. The average grain size is reduced from 14.99 μm to 8.41 μm, and the yield strength is 539 MPa, representing an increase of 16.2 %. When the strain is 43 %, the high temperature compression performance at 1400 ℃ reaches 214 MPa, which is 28.1 % higher than that of Mo-Re. The enhanced performance is attributed to the dislocation pinning of ZrO 2 and the formation of a semi-conformal interface between ZrO 2 and the matrix, which addresses the issue of weak interfacial bonding to reinforce Mo-Re alloys. It provides a new idea for the design of Mo-Re alloys structural components such as space fission reactors fuel cladding in ultra-high temperature environment.
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Research context

OpenAlex topics: Advanced materials and composites · Aluminum Alloys Composites Properties · Metal and Thin Film Mechanics

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References (55)

Show source-provided references
1. Embrittlement of molybdenum–rhenium welds under low and high temperature neutron irradiation10.1016/j.jnucmat.2013.10.027 ↗
2. Investigation of mechanical properties and microstructure of various molybdenum-rhenium alloys
3. Extremely uniform nanosized oxide particles dispersion strengthened tungsten alloy with high tensile and compressive strengths fabricated involving liquid-liquid method10.1016/j.jallcom.2021.160335 ↗
4. Effect of Mo-Re alloy on drop critical safety
5. Radiation-damage in molybdenum–rhenium alloys for space reactor applications10.1016/j.jnucmat.2007.03.028 ↗
6. Concerning sigma-phase in molybdenum-rhenium alloys10.1007/BF02645854 ↗
7. Microstructure refinement and second phase particle regulation of Mo-Y2O3 alloys by minor TiC additive10.1007/s12613-022-2462-z ↗
8. Evaluating compressive property and hot deformation behavior of molybdenum alloy reinforced by nanoscale zirconia particles10.1016/j.jallcom.2020.158289 ↗
9. Achieving an unprecedented strength-ductility balance of molybdenum alloy by homogeneously distributing yttrium-cerium oxide10.1016/j.jallcom.2021.163110 ↗
10. Low-temperature accelerated sintering of high-performance oxide dispersion strengthened ultrafine grained Mo alloy10.1016/j.jallcom.2022.163982 ↗
11. Microstructure and high temperature deformation behavior of the Mo-ZrO2 alloys10.1016/j.jallcom.2017.05.013 ↗
12. Evaluating compressive property and hot deformation behavior of molybdenum alloy reinforced by nanoscale zirconia particles10.1016/j.jallcom.2020.158289 ↗
13. Excellent high-temperature strength and ductility of the ZrC nanoparticles dispersed molybdenum10.1016/j.actamat.2022.117725 ↗
14. Preparation and characterization of Mo/Al2O3 composites10.1016/j.ijrmhm.2015.07.033 ↗
15. Influences of annealing temperature on microstructure and mechanical properties of Mo–La2O310.1016/j.ijrmhm.2011.03.003 ↗
16. Achieving high strength and ductility in ODS-W alloy by employing oxide@ W core-shell nanopowder as precursor10.1038/s41467-021-25283-2 ↗
17. Nanostructured high-strength molybdenum alloys with unprecedented tensile ductility10.1038/nmat3544 ↗
18. Compressive properties and deformation behaviors of sintered W-m-ZrO2 alloy under different temperature10.1016/j.msea.2022.144238 ↗
19. Microstructure characterization and properties of YSZ particles doped tungsten alloy prepared by liquid phase method10.1016/j.msea.2021.142483 ↗
20. Hot compression behaviors and microstructural evolution of Mo-42 wt% Re alloy10.1016/j.matlet.2022.132252 ↗
21. A novel method for preparing ultrafine molybdenum‑rhenium alloy powders10.1016/j.ijrmhm.2023.106429 ↗
22. Effect of Mo oxides on the phase composition and characteristics of Mo-10Re pre-alloyed powders Co-reduced with NH4ReO410.3390/ma16175936 ↗
23. Corrosion behavior of Mo–Re based alloys in liquid Li10.1016/S0022-3115(98)00459-0 ↗
24. Preparation and characterization of Mo/ZrO2–Y2O3 composites10.1016/j.ijrmhm.2018.04.018 ↗
25. Compressive properties and deformation behaviors of sintered W-m-ZrO2 alloy under different temperature10.1016/j.msea.2022.144238 ↗
26. Prediction of sintered density of binary W(Mo) alloys using machine learning10.1007/s12598-022-02238-0 ↗
27. Strain hardening of rhenium and two typical molybdenum-rhenium alloys manufactured by powder sintering10.1515/ijmr-2000-911011 ↗
28. Mechanical properties and strengthening mechanism of the hydrothermal synthesis of nano-sized α-Al2O3 ceramic particle reinforced molybdenum alloy10.1016/j.ceramint.2020.01.038 ↗
29. Evaluating low cycle fatigue property of nanoscale ZrO2 particles strengthening molybdenum alloy10.1016/j.vacuum.2022.111170 ↗
30. Enhancing the high-temperature creep properties of Mo alloys via nanosized La2O3 particle addition10.1016/j.jmst.2022.04.043 ↗
31. Refined microstructure and enhanced mechanical properties in Mo-Y2O3 alloys prepared by freeze-drying method and subsequent low temperature sintering10.1016/j.jmst.2021.01.064 ↗
32. Phase interface engineering: a new route towards ultrastrong yet ductile Mo alloy10.1016/j.msea.2023.145867 ↗
33. Synthesis and characterization of nano TiC dispersed strengthening W alloys via freeze-drying10.1016/j.jallcom.2020.157774 ↗
34. Hot compression behaviors and microstructural evolution of Mo-42 wt% Re alloy10.1016/j.matlet.2022.132252 ↗
35. Effect of zirconia on low cycle fatigue and energy absorption of molybdenum alloy10.1016/j.jallcom.2021.159118 ↗
36. Mechanical and microstructural responses in molybdenum-rhenium alloys under hot compressions10.1016/j.jmrt.2024.04.063 ↗
37. Heterogeneous precipitate microstructure in titanium alloys for simultaneous improvement of strength and ductility10.1016/j.jmst.2022.02.025 ↗
38. On the deformation behavior of heterogeneous microstructure and its effect on the mechanical properties of die cast AZ91D magnesium alloy10.1016/j.jma.2021.09.006 ↗
39. L. Yang, A. Si, S. Wei, X. Wang, Effects of Al2O3 and Cr2O3 on the Microstructure and Properties of Mo Composites Prepared Via Vacuum Sintering, Available at SSRN 4687539.
40. Evaluation of tensile property and strengthening mechanism of molybdenum alloy bars doped with different ultrafine oxides10.1016/S1003-6326(23)66319-8 ↗
41. Effect mechanism of oxide doping on the microstructure and mechanical properties of Mo-Y2O3 alloys10.1016/j.msea.2021.142344 ↗
42. Enhanced high-temperature strength of HfNbTaTiZrV refractory high-entropy alloy via Al2O3 reinforcement10.1016/j.jmst.2022.01.025 ↗
43. Effect of Sn addition on the deformation behavior and microstructural evolution of Mg-Gd-Y-Zr alloy during hot compression10.1016/j.msea.2021.142026 ↗
44. Effects of Cr addition on the constitutive equation and precipitated phases of copper alloy during hot deformation10.1016/j.matdes.2020.108613 ↗
45. Dynamic recrystallization behavior of a Mo-2.0 % ZrO2 alloy during hot deformation10.1016/j.ijrmhm.2022.105983 ↗
46. Strain-rate effects on the recrystallization of molybdenum-based MZ17 alloy
47. Microstructure evolution of W-1.0 m-ZrO2 alloy during high temperature deformation10.1016/j.jallcom.2022.166153 ↗
48. Investigation of stress-strain response, microstructure and texture of hot deformed pure molybdenum10.1016/j.ijrmhm.2018.02.011 ↗
49. Dynamic recrystallization behavior and strengthening mechanism of a novel Mo-Ti3AlC2 alloy at ultrahigh temperature10.1007/s12598-024-02669-x ↗
50. Dynamic recrystallization mechanism and improved mechanical properties of a near α high temperature Titanium alloy processed by severe plastic deformation10.1016/j.matchar.2020.110281 ↗
51. Grain growth behavior and mechanical properties of zirconium microalloyed and nano-size zirconium carbide dispersion strengthened tungsten alloys10.1016/j.ijrmhm.2015.03.019 ↗
52. Hot deformation behaviour of Mo-TZM and understanding the restoration processes involved10.1016/j.actamat.2018.10.037 ↗
53. Effect of heat treatment condition on the flow behavior and recrystallization mechanisms of aluminum alloy 705510.3390/ma12020311 ↗
54. Particle-stimulated nucleation of recrystallization in the hot-deformed molybdenum alloy MZ-1710.1016/j.ijrmhm.2018.01.021 ↗
55. role of solute in the texture modification during hot deformation of Mg-rare earth alloys10.1007/s11661-011-0923-5 ↗