journal article·2024-03

Facile preparation of bimetallic cobalt-copper selenide nanosheets as stable cathode materials for rechargeable magnesium batteries

Zhitao Wang, Fuhao Zhang, Song Chen, Shengbo Gao, Liyuan Wang, Xupo Liu, Miao Li, Enbo Shangguan

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Abstract

The pursuit of novel cathode materials with excellent performance is the key to promoting the application of rechargeable magnesium batteries (RMBs). Herein, bimetallic copper-cobalt selenide (CuCo 2Se 4) as a cathode material for RMBs, synthesized via a microwave-assisted method. In contrast to the monometallic selenide (Co 0.85Se), CuCo 2Se 4 exhibits a high reversible capacity of 108 mAh g −1 at 50 mA g −1 after 80 cycles, and a superior rate capability (90 mAh g −1 at 200 mA g −1 ). The crystal phase transition of the conversion electrode material during the cycles is analyzed using ex-situ XRD technology. The enhanced stability of bimetallic selenide provides a good experimental support for the preparation of high-performance rechargeable magnesium batteries based on bimetallic strategy.
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Research context

OpenAlex topics: Advancements in Battery Materials · MXene and MAX Phase Materials · Layered Double Hydroxides Synthesis and Applications

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