In situ construction of a multifunctional interlayer for garnet-type electrolytes to suppress lithium dendrite formation in solid-state lithium batteries
Source abstract
Abstract
Garnet-type solid-state electrolytes (SSEs) have great potential to be applied in all-solid-state lithium batteries (ASSLBs) due to their high ionic conductivity and excellent electrochemical stability with Li metal. However, the poor interface contact and the high electronic conductivity issues resulting in lithium dendrites growth remain challenging. Herein, we constructed a multifunctional interlayer LiF/Li-Ag alloy (LFA) in situ on the surface of garnet-type Li 6.5La 3Zr 1.5Ta 0.5O 12 (LLZTO) to suppress Li dendrite growth. The matrix of the interlayer is a three-dimensional porous structure LiF and it is filled with Li-Ag alloy. The LiF blocks electron access to the LLZTO and the Li-Ag alloy ensures a good interface contact during cycling. The Li/LFA-LLZTO/Li symmetrical cells exhibit an ultralow interfacial resistance of 1.8 Ω cm 2, a high critical current density of 1.1 mA cm −2 and outstanding galvanostatic cycling stability at 0.2 mA cm −2 for 2000 h. Moreover, the LiFePO 4/LFA -LLZTO/Li full cell delivers a high discharge capacity of 155 mAh g −1 at 0.1 C with a capacity retention of 93% after 100 cycles.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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