Equation of state of adamite up to 11 GPa: a synchrotron X-ray diffraction study
Source abstract
Abstract
The compression behavior of natural adamite [Zn2AsO4OH] has been investigated up to 11.07 GPa at room temperature utilizing in situ angle-dispersive X-ray diffraction and a diamond anvil cell. No phase transition has been observed within the pressure range investigated. A third-order Birch–Murnaghan equation of state fitted to all of the data points yielded V 0 = 430.1(4) A3, K 0 = 80(3) GPa, K′ 0 = 1.9(5). The K 0 was obtained as 69(1) GPa when K′ 0 was fixed at 4. Analysis of axial compressible moduli shows the intense compression anisotropy of adamite: K a0 = 37(3) GPa, K b0 = 153(6) GPa, K c0 = 168(8) GPa; hence, a axis is the most compressible and the compressibility of b and c axis is comparable. Furthermore, the comparisons among the compressional properties of adamite, libethenite (Cu2PO4OH, also belongs to olivenite group), and andalusite (Al2SiO4O has the similar structure with adamite) at high pressure were made.
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Research context
OpenAlex topics: High-pressure geophysics and materials · Geological and Geochemical Analysis · Crystal Structures and Properties
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References (39)
Show source-provided references
1. Allred A (1961) Electronegativity values from thermochemical data. J Inorg Nucl Chem 17:215–22110.1016/0022-1902(61)80142-5 ↗
2. Angel RJ (2000) Equations of state. Rev Miner Geochem 41:35–5910.2138/rmg.2000.41.2 ↗
3. Angel RJ (2001) EOS–FIT V5.2 computer program. Crystallography Laboratory, Department of Geological Sciences, Virginia Tech, Blacksburg, VA, USA
4. Angel RJ, Bujak M, Zhao J, Gatta GD, Jacobsen SD (2007) Effective hydrostatic limits of pressure media for high-pressure crystallographic studies. J Appl Crystallogr 40:26–3210.1107/S0021889806045523 ↗
5. Arai Y, Lanzirotti A, Sutton S, Newville M, Dyer J, Sparks D (2006) Spatial and temporal variability of arsenic solid-state speciation in historically lead arsenate contaminated soils. Environ Sci Technol 40:673–67910.1021/es051266e ↗
6. Bass JD, Liebermann RC, Weidner DJ, Finch SJ (1981) Elastic properties from acoustic and volume compression experiments. Phys Earth Planet Inter 25:140–15810.1016/0031-9201(81)90147-3 ↗
7. Bennett TJ (1980) Crystal structure of paradamite. Am Miner 65:353–354
8. Birch F (1947) Finite elastic strain of cubic crystals. Phys Rev 71:809–82410.1103/PhysRev.71.809 ↗
9. Burt JB, Ross NL, Angel RJ, Koch M (2006) Equations of state and structures of andalusite to 9.8 GPa and sillimanite to 8.5 GPa. Am Miner 91:319–32610.2138/am.2006.1875 ↗
10. Cordsene A (1978) A crystal structure refinement of libethenite. Can Miner 16:153–157
11. Dubreuil P, Filari E, Sobolev V (1999) Use of andalusite refractories in ferrous metallurgy. Refract Ind Ceram 40:252–25910.1007/BF02762295 ↗
12. Gołębiowska B, Pieczka A, Franus W (2006) Olivenite–adamite solid solution from oxidation zone in Rędziny (West Sudetes, Poland). Mineral Pol 37:101–11010.2478/v10002-007-0001-1 ↗
13. Hammersley J (1996) Fit2D report. European Synchrotron Radiation Facility, Grenoble, France
14. Hawthorne FC (1976) A refinement of the crystal structure of adamite. Can Miner 14:143–148
15. Hazen RM, Finger LW (1979) Bulk modulus—volume relationship for cation-anion polyhedra. J Geophys Res 84:6723–672810.1029/JB084iB12p06723 ↗
16. Hill RJ (1976) The crystal structure and infrared properties of adamite. Am Miner 61:979–986
17. Jacobsen SD (2006) Effect of water on the equation of state of nominally anhydrous minerals. Rev Miner Geochem 62:321–34210.2138/rmg.2006.62.14 ↗
18. Kato T, Miura Y (1977) The crystal structures of adamite and paradamite. Miner J 8:320–32810.2465/minerj.8.320 ↗
19. Kerrick DM (1990) Metamorphic reactions. In: Kerrick DM (Ed) The Al2SiO5 polymorphs. Rev Mineral 22:223–253. Mineralogical Society of America, Chantilly, Virginia10.1515/9781501509094-012 ↗
20. Kolencik M, Urik M, Gardosova K, Littera P, Matus P (2011) Biological and chemical leaching of arsenic and zinc from adamite. Chem Listy 105:961–965
21. Lager GA, Downs RT, Origlieri M, Garoutte R (2002) High-pressure single-crystal X-ray diffraction sudy of katoite hydrogarnet: evidence for a phase transition from Ia3d → I $$\bar{4}$$ 4 ¯ symmetry at 5 GPa. Am Miner 87:642–64710.2138/am-2002-5-606 ↗
22. Larson AC, Von Dreele RB (2004) General Structure Analysis System (GSAS). Los Alamos National Laboratory Report LAUR 86–748
23. Malavi PS, Karmakar S, Karmakar D, Mishra AK, Bhatt H, Patel NN, Sharma SM (2013) High pressure structural and vibrational properties of the spin-gap system Cu2PO4(OH). J Phys Condens Mater 25:1–1010.1088/0953-8984/25/4/045402 ↗
24. Mao HK, Bell P, Shaner J, Steinberg D (1978) Specific volume measurements of Cu, Mo, Pd, and Ag and calibration of the ruby R1 fluorescence pressure gauge from 0.06 to 1 Mbar. J Appl Phys 49:3276–328310.1063/1.325277 ↗
25. Matsui M (1996) Molecular dynamics study of the structures and bulk moduli of crystals in the system CaO–MgO–Al2O3–SiO2. Phys Chem Miner 23:345–35310.1007/BF00199500 ↗
26. Oganov AR, Price GD, Brodholt JP (2001) Theoretical investigation of metastable Al2SiO5 polymorphs. Acta Cryst A 57:548–55710.1107/S0108767301007644 ↗
27. O’Neill B, Bass JD, Rossman GR (1993) Elastic properties of hydrogrossular garnet and implications for water in the upper mantle. J Geophys Res 98:20031–2003710.1029/93JB02005 ↗
28. Pavese A, Davide L, Pischedda V (2001) Elastic properties of andradite and grossular, by synchrotron X-ray diffraction at high pressure conditions. Eur J Miner 13:929–93710.1127/0935-1221/2001/0013/0929 ↗
29. Ralph RL, Finger LW, Hazen RM, Ghose S (1984) Compressibility and crystal structure of andalusite at high pressure. Am Miner 69:513–519
30. Shannon R (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst A 32:751–76710.1107/S0567739476001551 ↗
31. Smyth JR, Frost DJ, Nestola F (2005) Hydration of olivine and the Earth’s deep water cycle. Geochim Cosmochim Acta 69:A746
32. Sumin VI (1974) Infrared spectroscopic investigation of the structure of some natural arsenates and the nature of H-bonds in their structures. Can Miner 12:262–268
33. Vaughan MT, Weidner DJ (1978) The relationship of elasticity and crystal structure in andalusite and sillimanite. Phys Chem Miner 3:133–14410.1007/BF00308117 ↗
34. Wei S, Ma M, Fan D, Yang J, Zhou W, Li B, Chen Z, Xie H (2013) Compressibility of mimetite and pyromorphite at high pressure. High Press Res 33:27–3410.1080/08957959.2013.765003 ↗
35. Winkler B, Hytha M, Warren M, Milman V, Gale J, Schreuer J (2001) Calculation of the elastic constants of the Al2SiO5 polymorphs andalusite, sillimanite and kyanite. Z Kristallogr 216:67–7010.1524/zkri.216.2.67.20336 ↗
36. Winter JK, Ghose S (1979) Thermal expansion and high-temperture crystal chemistry of the Al2 SiO5 polymorphs. Am Miner 64:573–586
37. Yang H, Hazen R, Finger L, Prewitt C, Downs R (1997) Compressibility and crystal structure of sillimanite, Al2SiO5, at high pressure. Phys Chem Miner 25:39–4710.1007/s002690050084 ↗
38. Yusa H, Inoue T (1997) Compressibility of hydrous wadsleyite (β-phase) in Mg2SiO4 by high pressure X-ray diffraction. Geophys Res Lett 24:1831–183410.1029/97GL51794 ↗
39. Zha CS, Duffy TS, Downs RT, Mao HK, Hemley RJ (1998) Brillouin scattering and X-ray diffraction of San Carlos olivine: direct pressure determination to 32 GPa. Earth Planet Sci Lett 159:25–3310.1016/S0012-821X(98)00063-6 ↗