Porous CoP/P-C nanofilm grown on lightweight carbon cloth as a binder/additive-free lithium-ion anode with high-performance
Source abstract
Abstract
Cobalt phosphide is a promising anode material for lithium-ion batteries (LIBs) due to a high theoretical capacity at low potentials when reaction with lithium. While, capacity-decay upon cycling and unsatisfied rate performance limited the practical application in LIBs. Herein, we report the design and synthesis of free-standing electrode composed of CoP/P-C nanofilm and lightweight carbon cloth (denoted as PCC@CoP/P-C) as an anode material for LIBs. The facile and in situ strategy for the synthesis of PCC@CoP/P-C involves phytic acid (PA) complexed with Co 2+ and subsequent annealing treatments. Owing to the unique structural merits of CoP/P-C nanofilm and the lightweight PCC , the PCC@CoP/P-C free-standing electrode exhibits an ultrahigh specific stability capacity and nice cycle stability when direct used as anode for LIBs. This work offers an easy and environment friendly method to boost lithium performance for transition metal phosphides anode materials.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (56)
Show source-provided references
1. Chemomechanics of rechargeable batteries: status, theories, and perspectives10.1021/acs.chemrev.2c00002 ↗
2. From materials to cell: state-of-the-art and prospective technologies for lithium-ion battery electrode processing10.1021/acs.chemrev.1c00565 ↗
3. Interfacial evolution of the solid electrolyte interphase and lithium deposition in graphdiyne-based lithium-ion batteries10.1021/jacs.2c01412 ↗
4. Strongly coupled interfacial engineering inspired by robotic arms enable high-performance sodium-ion capacitors10.1002/adfm.202205453 ↗
5. SiO-induced thermal instability and interplay between graphite and SiO in graphite/SiO composite anode10.1038/s41467-022-35769-2 ↗
6. Fast charging of energy-dense lithium-ion batteries10.1038/s41586-022-05281-0 ↗
7. High-entropy mechanism to boost ionic conductivity10.1126/science.abq1346 ↗
8. Graphene aerogel encapsulated Fe-Co oxide nanocubes derived from prussian blue analogue as integrated anode with enhanced Li-ion storage properties10.1016/j.apsusc.2018.12.040 ↗
9. Facile synthesis of MOF-derived hollow NiO microspheres integrated with graphene foam for improved lithium-storage properties10.1016/j.jallcom.2019.01.157 ↗
10. Insights into the deposition chemistry of Li ions in nonaqueous electrolyte for stable Li anodes10.1039/D0CS01017K ↗
11. Promises and challenges of next-generation "beyond Li-ion" batteries for electric vehicles and grid decarbonization10.1021/acs.chemrev.0c00767 ↗
12. Drastically enhancing the cycle stability of copper-dicarboxylate as an anode material for lithium-ion batteries by rational fluorination10.1016/j.apsusc.2022.155877 ↗
13. Ultra-low-dose pre-metallation strategy served for commercial metal-ion capacitors10.1007/s40820-022-00792-x ↗
14. Engineering Co-P alloy foil to a well-designed integrated electrode toward high-performance electrochemical energy storage10.1002/adma.202209924 ↗
15. Introducing high-valence iridium single atoms into bimetal phosphides toward high-efficiency oxygen evolution and overall water splitting10.1002/smll.202207253 ↗
16. Easy encapsulation of Sn4P3 nanoparticles into honeycomb-like nitrogen-doped carbon matrix with enhanced electrochemical performance for li-ion batteries10.1016/j.jallcom.2021.159531 ↗
17. Template-directed synthesis of Co2P/MoSe2 in a N-doped carbon hollow structure for efficient and stable sodium/potassium ion storage10.1016/j.nanoen.2021.106897 ↗
18. Bimetallic phosphide Ni2P/CoP@rGO heterostructure for high-performance lithium/sodium-ion batteries10.1016/j.jpowsour.2023.232715 ↗
19. Li Migration, Nucleation and growth behavior regulated by a lithiophilic cobalt phosphide-doped carbon nanofibers derived ion/electron conductive framework10.1016/j.ensm.2021.11.009 ↗
20. Halogen-doped carbon dots on amorphous cobalt phosphide as robust electrocatalysts for overall water splitting10.1002/aenm.202102573 ↗
21. Electronic structure modulation in MoO2/MoP heterostructure to induce fast electronic/ionic diffusion kinetics for lithium storage10.1002/advs.202104504 ↗
22. Well-controlled 3D flower-like CoP3/CeO2/C heterostructures as bifunctional oxygen electrocatalysts for rechargeable Zn-air batteries10.1016/j.apcatb.2022.122029 ↗
23. Tailored chemically bonded metal phosphide@carbon nanowire arrays on foam metal as an all-in-one anode for ultrahigh-area-capacity sodium-ion batteries10.1016/j.cej.2022.140402 ↗
24. Advanced strategies for improving lithium storage performance under cryogenic conditions10.1002/aenm.202203719 ↗
25. Dynamics and control of active sites in hierarchically nanostructured cobalt phosphide/chalcogenide-based electrocatalysts for water splitting, Energ
26. In-Situ reducing synthesis of MoP@nitrogen-doped carbon nanofibers as an anode material for lithium/sodium-ion batteries10.1016/j.electacta.2020.136921 ↗
27. Conversion of polysulfides on core-shell CoP@C nanostructures for lithium-sulfur batteries10.1016/j.cej.2022.140460 ↗
28. Davarani, Fabrication of nanosheet-assembled hollow copper-nickel phosphide spheres embedded in reduced graphene oxide texture for hybrid supercapacitors10.1039/D2NR06305K ↗
29. Green preparation of nanostructured beta-MoO3/hexagonal-shaped MoS2/Graphene with enhanced lithium-ion storage performance10.1016/j.jallcom.2022.167724 ↗
30. Hierarchical microcables constructed by CoP@C⊂carbon framework intertwined with carbon nanotubes for efficient lithium storage10.1002/aenm.201902913 ↗
31. Supramolecular self-assembly synthesis of hemoglobin-like amorphous CoP@N, P-doped carbon composites enable ultralong stable cycling under high-current density for lithium-ion battery anodes10.1007/s42114-022-00607-y ↗
32. Atomic interface catalytically synthesizing SnP/CoP hetero-nanocrystals within dual-carbon hybrids for ultrafast lithium-ion batteries10.1016/j.eng.2021.11.026 ↗
33. Durable flexible dual-layer and free-standing silicon/carbon composite anode for lithium-ion batteries10.1016/j.jallcom.2022.167687 ↗
34. Self-standing 3D hollow nanoporous SnO2-modified CuxO nanotubes with nanolamellar metallic Cu inwalls: a facile in situ synthesis protocol toward enhanced Li storage properties10.1002/adfm.202212654 ↗
35. Si nanoparticles embedded in porous N-doped carbon fibers as a binder-free and flexible anode for high-performance lithium-ion batteries
36. High-performance and flexible lithium-ion battery anodes using modified buckypaper10.1016/j.jallcom.2022.167424 ↗
37. Surface reconstruction on Ni2P@CC to form an ultrathin layer of Ni(OH)2 for enhancing the capture and catalytic conversion of polysulfides in lithium-sulfur batteries10.1039/D2TA09295F ↗
38. In situ growth of CoP nanosheet arrays on carbon cloth as binder-free electrode for high-performance flexible lithium-ion batteries10.1002/smll.202204970 ↗
39. Organocatalysis-inspired palladium molecule as a robust polysulfide-confinement-scissors catalyst for advanced lithium-sulfur battery10.1021/acsaem.2c01078 ↗
40. A water-free in situ hf treatment for ultrabright InP quantum dots10.1021/acs.chemmater.2c02800 ↗
41. Phase transformations and phase segregation during potassiation of SnxPy anodes10.1021/acs.chemmater.2c01570 ↗
42. Ternary all-lithium-reactive AlGeP solid solution as an advanced anode material for lithium-ion batteries10.1016/j.jallcom.2022.167622 ↗
43. Improving the rate capacity and cycle stability of FeP anodes for lithium-ion batteries via in situ carbon encapsulation and copper doping10.1016/j.jcis.2022.12.054 ↗
44. A class of Ga-Al-P-Based compounds with disordered lattice as advanced anode materials for Li-ion batteries10.1016/j.jechem.2022.12.036 ↗
45. Boosting oxygen electrocatalytic activity of Fe-N-C catalysts by phosphorus incorporation10.1021/jacs.2c12933 ↗
46. Highly active and stable catalysts of phytic acid-derivative transition metal phosphides for full water splitting10.1021/jacs.6b08491 ↗
47. Solvation and interfacial engineering enable -40°c operation of graphite/NCM batteries at energy density over 270 wh kg−1
48. Enabling rapid pseudocapacitive multi-electron reactions by heterostructure engineering of vanadium oxide for high-energy and high-power lithium storage10.1039/D2EE02888C ↗
49. Shape-controlled cobalt phosphide nanoparticles as volatile organic solvent sensor10.1039/C6TC00949B ↗
50. Phytic acid-assisted formation of hierarchical porous CoP/C nanoboxes for enhanced lithium storage and hydrogen generation10.1021/acsnano.8b06039 ↗
51. Constructing sub 10 nm scale interfused TiO2/SiOx bicontinuous hybrid with mutual-stabilizing effect for lithium storage10.1021/acsnano.2c10381 ↗
52. Prussian blue nanocubes supported on graphene foam as superior binder-free anode of lithium-ion batteries10.1016/j.jallcom.2018.03.378 ↗
53. Electronic synergy to boost the performance of NiCoP-NWs@FeCoP-NSs anodes for flexible lithium-ion batteries10.1039/D2NR01787C ↗
54. Formation of nitrogen-doped carbon-coated CoP nanoparticles embedded within graphene oxide for lithium-ion batteries anode10.1002/ente.201901089 ↗
55. A multidimensional and hierarchical carbon-confined cobalt phosphide nanocomposite as an advanced anode for lithium and sodium storage10.1039/C8NR07076H ↗
56. Phytic acid-derived Co2P/N-doped carbon nanofibers as flexible free-standing anode for high performance lithium/sodium ion batteries10.1016/j.jallcom.2020.156256 ↗