Selective oxidation of benzyl alcohol over sulphated zirconia incorporated ordered mesoporous carbon by a hard template method
Source abstract
Abstract
An ordered mesoporous carbon (OMC) support was prepared by a hard template method using cellulose (C source) and SBA-16 (silica source) as templates. The silica-carbon composite was treated with 10 % HF to completely remove silica from the composite to create a mesoporous nature. Afterwards, Zr (10–30 wt%) and 4 % of SO 4 2- were incorporated over OMC by a hydrolysis method. The prepared catalysts were characterized by various techniques such as XRD, Raman, BET, Py-FT-IR, TGA, SEM, Elemental mapping, and TEM. The detailed investigation of selective oxidation of benzyl alcohol (BzOH) to benzaldehyde (BzH). This study exhibited the SO 4 2- /Zr-OMC (30) catalyst showed its superior activity in the oxidation of benzyl alcohol (about>97 % of the conversion and BzH selectivity of>98 %) under the optimized reaction conditions. Furthermore, the reusability of the SO 4 2-/Zr-OMC (30) catalyst up to the 5th run. This result revealed the stability of the prepared SO 4 2-/Zr-OMC (30) catalyst, which was associated with its physicochemical properties.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Mesoporous Materials and Catalysis · Chemical Synthesis and Reactions · Oxidative Organic Chemistry Reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (54)
Show source-provided references
1. Phosphorization-derived MoP@MoO3-x nanowires for selective photocatalytic oxidation of benzyl alcohol to benzaldehyde10.1016/j.jcat.2020.11.001 ↗
2. Enhanced selective oxidation of benzyl alcohol via in situ H2O2 production over supported Pd-based catalysts10.1021/acscatal.0c04586 ↗
3. Catalytic activity of ratio-dependent SBA-15 supported zirconia catalysts for highly selective oxidation of benzyl alcohol to benzaldehyde and environmental pollutant heavy metal ions detection10.1016/j.molstruc.2018.09.007 ↗
4. Highly selective oxidation of benzyl alcohol over Pt-sulphated zirconia supported on SBA-15 catalyst by using a high-pressure fixed bed reactor10.1016/j.poly.2018.08.053 ↗
5. TiO2/Ti3C2 as an efficient photocatalyst for selective oxidation of benzyl alcohol to benzaldehyde10.1016/j.apcatb.2021.119885 ↗
6. Cobalt single atoms embedded in nitrogen-doped graphene for selective oxidation of benzyl alcohol by activated peroxymonosulfate
7. Metal-free g-C3N4 photocatalyst by sulfuric acid activation for selective aerobic oxidation of benzyl alcohol under visible light10.1016/j.materresbull.2014.06.021 ↗
8. Selective photocatalytic oxidation of benzyl alcohol to benzaldehyde by using metal-loaded g-C3N4 photocatalysts10.1016/j.cattod.2016.11.023 ↗
9. High-performance benzyl alcohol oxidation catalyst: Au-Pd alloy with ZrO2 as promoter10.1016/j.apsusc.2020.148059 ↗
10. Highly tunable selectivity to benzaldehyde over Pd/ZrO2 catalysts in Oppenauer oxidation of benzyl alcohol using acetone as H-acceptor10.1016/j.apcata.2021.118022 ↗
11. Facile synthesis of highly stable and well-dispersed mesoporous ZrO2/carbon composites with high performance in oxidative dehydrogenation of ethylbenzene10.1039/c004469e ↗
12. Biodiesel from waste cooking oil via heterogeneous superacid catalyst SO42−/ZrO210.1021/ef800751z ↗
13. S. Triwahyono, A.A. Jalil, H. Hamdan, Isomerisation of Cyclohexane to Methylcyclopentane over Pt/so42--zro2 Catalyst, 67, 2006, p. 7.
14. Conversion of glucose into 5-hydroxymethylfurfural and levulinic acid catalyzed by SO42–/ZrO2 in a biphasic solvent system10.1021/acs.energyfuels.0c01823 ↗
15. Selective conversion of cotton cellulose to glucose and 5-hydroxymethyl furfural with SO42−/MxOy solid superacid catalyst10.1016/j.carbpol.2015.05.036 ↗
16. Novel graphene electrochemical transistor with ZrO2/rGO nanocomposites functionalized gate electrode for ultrasensitive recognition of methyl parathion10.1016/j.snb.2020.128936 ↗
17. Structural and morphological studies of V2O5/MWCNTs and ZrO2/MWCNTs composites as photocatalysts
18. Steam-treated CeO2-ZrO2/activated carbon fibers for the efficient removal of Pb(II) from aqueous solutions10.1016/j.colsurfa.2019.01.013 ↗
19. One-pot solvothermal synthesis of carbon dots/Ag nanoparticles/TiO2 nanocomposites with enhanced photocatalytic performance10.1016/j.ceramint.2018.09.017 ↗
20. Grand challenges in carbon-based materials research10.3389/fmats.2014.00006 ↗
21. Nitrogen-dopped ordered mesoporous carbon anchored pd nanoparticles for solvent free selective oxidation of benzyl alcohol to benzaldehyde by using O210.3389/fchem.2019.00458 ↗
22. Selective oxidation of benzyl alcohol with oxygen catalyzed by vanadia supported on nitrogen-containing ordered mesoporous carbon materials10.1007/s10562-021-03699-1 ↗
23. Selective oxidation of alcohols to high value-added carbonyl compounds using air over Co-Co3O4@NC catalysts10.1016/j.cej.2022.134545 ↗
24. Catalytic renovation of non-edible oil to biodiesel production through sulfated Mg-Al2O3 (10) catalysts10.1002/er.6840 ↗
25. Enhanced adsorption properties of organic ZnCr-LDH synthesized by soft template method for anionic dyes10.1007/s11356-021-14035-w ↗
26. Synthesis of mesoporous hollow carbon microcages by combining hard and soft template method for high performance supercapacitors10.1016/j.ceramint.2020.10.170 ↗
27. A facile soft-template synthetic approach of surface integrated nitrogen-rich carbon nanospheres for light-weight supercapacitors10.1016/j.molstruc.2020.129788 ↗
28. An azine-based polymer derived hierarchically porous N–doped carbon for hydrophilic dyes removal10.1016/j.jhazmat.2021.125299 ↗
29. Removal of AV 90 dye using ordered mesoporous carbon materials prepared via nanocasting of KIT-6: Adsorption isotherms, kinetics and thermodynamic analysis10.1016/j.seppur.2020.117657 ↗
30. Hydrodesulfurization studies on SBA-16 supported molybdenum hydrotreating catalysts
31. Synthesis of multiple heteroatom–doped mesoporous carbon/silica composites for supercapacitors10.1016/j.cej.2021.128796 ↗
32. Facile synthesis of hierarchically porous carbons from dual colloidal crystal/block copolymer template approach10.1021/cm070600y ↗
33. Synthesis of nitrogen-doped ordered mesoporous carbon with enhanced lithium storage performance from natural kaolin clay10.1016/j.electacta.2019.135399 ↗
34. Facile one-pot synthesis of mesoporous hierarchically structured silica/carbon nanomaterials10.1039/c2jm32723f ↗
35. Catalytic conversion of glucose to 5-hydroxymethylfurfural productions over sulphated Ti-Al2O3 catalysts10.1016/j.biombioe.2021.106261 ↗
36. Identification of active sites of B/N co-doped nanocarbons in selective oxidation of benzyl alcohol10.1016/j.jcis.2021.11.001 ↗
37. Selectivity oxidation of benzyl alcohol using mesoporous g-C3N4 catalysts prepared by hard template method10.1016/j.colcom.2022.100608 ↗
38. Catalytic hydrodeoxygenation of jojoba oil to the green-fuel application on Ni-MoS/Mesoporous zirconia-silica catalysts10.1016/j.renene.2019.01.076 ↗
39. ZrO2 nano particle catalyzed multi-component synthesis of 3-benzylidene-1-phenylquinoline-2,4(1H,3H)-diones and its antimicrobial activity10.1007/s11164-017-2894-7 ↗
40. Evidence of non-radiative energy transfer from the host to the active ions in monoclinic ZrO2:Sm310.1088/0022-3727/34/14/102 ↗
41. Synthesis of nitrogen-doped ordered mesoporous carbon with enhanced lithium storage performance from natural kaolin clay10.1016/j.electacta.2019.135399 ↗
42. Synthesis, growth mechanism, and electrochemical properties of hollow mesoporous carbon spheres with controlled diameter10.1021/jp205257u ↗
43. Afterglow and thermoluminescence of ZrO2 nanopowders
44. NiMoS over Ti-incorporated mesoporous silicates for the hydrotreating of non-edible oils to bio-jet fuels
45. Highly selective catalytic nitration of 1-nitronaphthalene with NO2 to 1,5-dinitronaphthalene over solid superacid SO42−/ZrO2 promoted by molecular oxygen and acetic anhydride under mild conditions10.1007/s11164-021-04502-x ↗
46. Green synthesis of nitrogen-doped self-assembled porous carbon-metal oxide composite towards energy and environmental applications10.1038/s41598-019-41700-5 ↗
47. Ternary SO42−–ZrO2–TiO2 solid super acid catalyst for one-step synthesis of adipicdihydrazide
48. Superficial effects and catalytic activity of ZrO2–SO42− as a function of the crystal structure10.1016/j.molcata.2014.12.015 ↗
49. Efficient synthesis of glucose into 5-hydroxymethylfurfural with SO42−/ZrO2 modified H+ zeolites in different solvent systems10.1016/j.jtice.2018.12.013 ↗
50. Hydrodeoxygenation of lignin-derived monomers and dimers over a Ru supported solid super acid catalyst for cycloalkane production10.1002/adsu.201900136 ↗
51. Mg/SiO2–Al2O3 supported nickel catalysts for the production of naphthenic hydrocarbon fuel by hydro-de-oxygenation of eugenol10.1016/j.ijhydene.2019.08.024 ↗
52. Tailoring collaborative N–O functionalities of graphene oxide for enhanced selective oxidation of benzyl alcohol10.1016/j.carbon.2021.06.062 ↗
53. Discrimination of active palladium sites in catalytic liquid-phase oxidation of benzyl alcohol10.1021/jp065779z ↗
54. Solvent-free aerobic selective oxidation of benzyl alcohol catalyzed by palladium nanoparticles supported on nitrogen-containing ordered mesoporous carbon