Structural, morphological and mechanical analysis of Mg2+ substituted calcium zirconium phosphate [CaZr4(PO4)6]
Source abstract
Abstract
Abstract The current study aims to investigate the potential of Mg2+ substituted CaZr4(PO4)6 for load bearing orthopedic applications. A series of Mg2+ substitution in CaZr4(PO4)6 and the subsequent structural and mechanical evaluation have been performed in the current investigation. The characterization studies confirmed the structural stability of Mg2+ substituted CaZr4(PO4)6 until 1550 °C, while the substitution limit of Mg2+ in CaZr4(PO4)6 is determined as 40 mol.%. Microstructural analysis revealed the improved surface morphology and densification of Mg2+ substituted CaZr4(PO4)6 compared to pure CaZr4(PO4)6. Young’s modulus and hardness values derived from nanoindentation and further the bending and compressive data affirmed the enhanced mechanical behaviour of CaZr4(PO4)6 until 20 mol. % of Mg2+ substitution and thereafter a marginal reduction is noticed during further increments.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Bone Tissue Engineering Materials · Advanced materials and composites · Orthopaedic implants and arthroplasty
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. Characterization and dissolution–reprecipitation behavior of biphasic tricalcium phosphate powders10.1016/j.jallcom.2011.03.158 ↗
2. Biomedical materials and techniques to improve the tribological, mechanical and biomedical properties of orthopedic implants – a review article10.1016/j.jallcom.2017.04.231 ↗
3. Preparation and antimicrobial activity of the porous hydroxyapatite nanoceramics10.1016/j.jallcom.2018.03.162 ↗
4. Enhanced osteogenic protein expression on human osteoblast-osteoclast co-culture system using doped hydroxyapatite plasma coatings for orthopedic and dental applications10.1016/j.mtcomm.2019.05.010 ↗
5. The enhancement of hydroxyapatite thermal stability by Al doping10.1016/j.jmrt.2019.10.032 ↗
6. Synthesis, structural analysis and fabrication of coatings of the Cu2+ and Sr2+ co-substitutions in β-Ca3(PO4)210.1039/c3ra43171a ↗
7. Research into the mechanical properties, sintering mechanism and microstructure evolution of Al2O3-ZrO2 composites fabricated by a stereolithography-based 3D printing method10.1016/j.matchemphys.2017.12.021 ↗
8. Compressive strain-dependent bending strength property of Al2O3-ZrO2 (1.5mol% Y2O3) composites performance by HIP10.1016/j.matchemphys.2008.10.044 ↗
9. Fast Na+-ion transport in skeleton structures10.1016/0025-5408(76)90077-5 ↗
10. Chemistry and properties of solids with the [NZP] skeleton10.1016/0167-2738(93)90158-Y ↗
11. Synthesis of nanocrystalline CeO2 −ZrO2 solid solutions by a citrate complexation route: a thermochemical and structural study10.1021/jp808825c ↗
12. Americium and plutonium in trigonal phosphates (NZP type) Am1/3[Zr2(PO4)3] and Pu1/4[Zr2(PO4)3]10.1134/S1066362206030052 ↗
13. A family of phosphates of langbeinite structure. Crystal-chemical aspect of radioactive waste immobilization10.1134/S1066362211010073 ↗
14. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
15. Actinide phosphates AiMIVPO43 (Ai = Li, Na, K, or Rb; MIV = U, Np, or Pu)
16. Synthesis and crystal structure of NZP-type Thorium−Zirconium phosphate10.1021/ic9013812 ↗
17. Highly enterprising calcium zirconium phosphate [CaZr4(PO4) 6 :Dy3+, Ce3+] phosphor for white light emission10.1039/C5RA07306E ↗
18. Comparison of sodium zirconium phosphate and calcium zirconium phosphate structures for the retention of fluoride10.1007/s10967-013-2741-2 ↗
19. The functional expression of osteoblasts grown on rapidly resorbable calcium phosphates10.4028/www.scientific.net/KEM.240-242.679 ↗
20. Bone anchorage and surface condition of the implant. Validity of extraction tests
21. Do calcium zirconium phosphate ceramics inhibit mineralization?
22. Inhibition of mineralization by a calcium zirconium phosphate coating10.1002/jbm.b.31037 ↗
23. Magnesium substitution in carbonated hydroxyapatite: structural and microstructural characterization by Rietveld’s refinement10.1016/j.matchemphys.2015.12.058 ↗
24. Mg-doped biphasic calcium phosphate by a solid state reaction route: characterization and evaluation of cytotoxicity10.1016/j.matchemphys.2015.05.055 ↗
25. Fabrication of calcium phosphate coating on pure magnesium substrate via simple chemical conversion coating: surface properties and corrosion performance evaluations10.1016/j.jmrt.2018.06.017 ↗
26. Mechanochemical-hydrothermal synthesis of calcium phosphate powders with coupled magnesium and carbonate substitution10.1016/j.jssc.2003.09.012 ↗
27. Magnesia-doped HA/β-TCP ceramics and evaluation of their biocompatibility10.1016/S0142-9612(03)00538-6 ↗
28. Magnesium and osteoporosis: current state of knowledge and future research directions10.3390/nu5083022 ↗
29. Effect of nano-HA content on the mechanical properties, degradation and biocompatible behavior of Mg-Zn/HA composite prepared by spark plasma sintering10.1016/j.matchar.2019.03.048 ↗
30. Preparation and characterization of biodegradable Mg-Zn-Ca/MgO nanocomposites for biomedical applications10.1016/j.matchar.2018.06.028 ↗
31. Nanocrystalline hydroxyapatite doped with magnesium and zinc: synthesis and characterization10.1016/j.msec.2006.09.036 ↗
32. Structural and bio-mineralization features of alumina zirconia composite influenced by the combined Ca2+ and PO43− additions10.1016/j.msec.2018.12.144 ↗
33. Synthesis and thermal expansion of MZr4P6O24 (M= Mg, Ca, Sr, Ba)10.1111/j.1151-2916.1987.tb04884.x ↗
34. Preferential occupancy of strontium in the hydroxyapatite lattice in biphasic mixtures formed from non-stoichiometric calcium apatites10.1039/C5DT00173K ↗
35. Formation of hydroxyapatite onto glasses of the CaO–MgO–SiO2 system with B2O3, Na2O, CaF2 and P2O5 additives10.1016/j.biomaterials.2005.10.033 ↗
36. Phase stabilization of ZrO2 polymorph by combined additions of Ca2+ and PO43− ions through an in situ synthetic Approach10.1111/jace.13182 ↗
37. Calcium phosphate-based resorbable ceramics: influence of MgO, ZnO, and SiO2 dopants10.1111/j.1551-2916.2006.01207.x ↗
38. Structural model for thermal expansion in MZr2P3O12 (M= Li, Na, K, Rb, Cs)10.1007/BF01160546 ↗
39. Low thermal expansion of alkali-zirconium phosphates10.1016/0025-5408(84)90258-7 ↗
40. Synthesis and thermal expansion hysteresis of Ca1-xSrxZr4P6O2410.1007/BF02711152 ↗
41. Microstructure and microcracking behaviour of barium zirconium phosphate (BaZr4P6O24) ceramics10.1007/BF01105050 ↗
42. Highly enterprising calcium zirconium phosphate [CaZr4(PO4)6:Dy3+, Ce3+] phosphor for white light emission10.1039/C5RA07306E ↗
43. Crystal structure of Ca1− x SrxZr4(PO4)6 (0≤ x≤ 1)10.1154/1.1643051 ↗
44. Mg/Cu co-substituted hydroxyapatite–Biocompatibility, mechanical properties and antimicrobial activity10.1016/j.ceramint.2019.07.219 ↗
45. Mechanical and tribological properties of the tricalcium phosphate-magnesium oxide composites10.1016/j.msec.2018.11.070 ↗
46. The mechanical properties of human tibial trabecular bone as a function of metaphyseal location10.1016/0021-9290(83)90097-0 ↗
47. Bioceramics: from concept to clinic10.1111/j.1151-2916.1991.tb07132.x ↗