journal article·2023-02

Circumventing strength-ductility paradox in high entropy alloys through deformation processing

Mayank Garg, Harpreet S. Grewal, Ram K. Sharma, Bharat Gwalani, Harpreet S. Arora

Publisher page

Abstract

Engineering materials are known to show trade-off between high tensile strength and ductility. The simultaneous enhancement of strength and ductility can make them more appealing for various structural applications. In this study, we demonstrate a facile technique to address the conflicting strength-ductility trade-off in crystalline materials. AlCoCrFeNi high entropy alloy (HEA), one of the most popular multi-principal alloy system, was considered for the investigation. The as-cast AlCoCrFeNi alloy showed a coarse grain microstructure with BCC/B2 phase. The as-cast alloy was subjected to severe plastic deformation using a facile technique known as stationary friction processing (SFP). The SFP for only 15 min resulted in an order of magnitude reduction in the grain size along with BCC to FCC phase transformation. The processed sample demonstrated more than 2 times higher ultimate tensile strength (∼650 MPa) compared to as-cast HEA (∼310 MPa). Further, the ductility of the processed HEA was enhanced from 11 % to 18 %. The combination of fine grain structure along with BCC to FCC transition through SFP enabled exceptional mechanical properties in the HEA. This approach can easily be extended to other alloy systems for designing high tensile strength and superior ductility.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: High Entropy Alloys Studies · Additive Manufacturing Materials and Processes · High-Temperature Coating Behaviors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (68)

Show source-provided references
1. Enhanced mechanical properties and thermal conductivity of high-pressure die-cast AlMg6Si2MnZr alloy by controlling the externally solidified crystals10.1016/j.jmatprotec.2022.117645 ↗
2. Fine tuning in-sync the mechanical and magnetic properties of FeCoNiAl0.25Mn0.25 high-entropy alloy through cold rolling and annealing treatment10.1016/j.jmatprotec.2020.116945 ↗
3. In situ X-ray and thermal imaging of refractory high entropy alloying during laser directed deposition10.1016/j.jmatprotec.2021.117363 ↗
4. Oxidation behavior of arc melted AlCoCrFeNi multi-component high-entropy alloys10.1016/j.jallcom.2016.02.257 ↗
5. Effect of microwave processing on the oxidation behavior of refractory high entropy alloy10.1016/j.matchemphys.2021.124256 ↗
6. High oxidation resistance of AlCoCrFeNi high entropy alloy through severe shear deformation processing
7. Breaking the property trade-offs by using entropic conceptions
8. Investigation on the microstructure and mechanical properties of CoCrFeNi high-entropy alloy joint bonded with BNi2 interlayer10.1016/j.jmatprotec.2021.117144 ↗
9. Microstructure and properties research of Al-Zn-Mg-Cu alloy with high strength and high elongation fabricated by wire arc additive manufacturing10.1016/j.jmatprotec.2022.117665 ↗
10. Microstructure, microhardness and residual stress of laser additive manufactured CoCrFeMnNi high-entropy alloy subjected to laser shock peening10.1016/j.jmatprotec.2020.116806 ↗
11. A precipitation-hardened high-entropy alloy with outstanding tensile properties10.1016/j.actamat.2015.08.076 ↗
12. High-entropy Al0.3CoCrFeNi alloy fibers with high tensile strength and ductility at ambient and cryogenic temperatures10.1016/j.actamat.2016.10.038 ↗
13. Microstructure and tensile behaviors of FCC Al0.3CoCrFeNi high entropy alloy10.1016/j.jallcom.2008.12.088 ↗
14. High-strength and high-ductility AlCoCrFeNi2.1 eutectic high-entropy alloy achieved via precipitation strengthening in a heterogeneous structure10.1016/j.scriptamat.2020.04.035 ↗
15. Enhancement of strength-ductility trade-off in a high-entropy alloy through a heterogeneous structure10.1016/j.actamat.2018.12.012 ↗
16. Heterogeneous lamella structure unites ultrafine-grain strength with coarse-grain ductility10.1073/pnas.1517193112 ↗
17. Dynamically reinforced heterogeneous grain structure prolongs ductility in a medium-entropy alloy with gigapascal yield strength10.1073/pnas.1807817115 ↗
18. Polymer layered silicate nanocomposites10.1002/adma.19960080104 ↗
19. Simultaneously enhanced strength and ductility for 3D-printed stainless steel 316L by selective laser melting10.1038/s41427-018-0018-5 ↗
20. A novel technique for developing bimodal grain size distributions in low carbon steels10.1016/j.scriptamat.2007.08.035 ↗
21. Metastable high-entropy dual-phase alloys overcome the strength–ductility trade-off10.1038/nature17981 ↗
22. High tensile ductility in a nanostructured metal10.1038/nature01133 ↗
23. Phase-transformation ductilization of brittle high-entropy alloys via metastability engineering10.1002/adma.201701678 ↗
24. Strong and ductile non-equiatomic high-entropy alloys: design, processing, microstructure, and mechanical properties10.1007/s11837-017-2540-2 ↗
25. dual-phase high-entropy alloy: Grain size and phase fraction effects on deformation behavior10.1016/j.actamat.2017.03.069 ↗
26. Interstitial atoms enable joint twinning and transformation induced plasticity in strong and ductile high-entropy alloys10.1038/srep40704 ↗
27. Alloy design for intrinsically ductile refractory high-entropy alloys10.1063/1.4966659 ↗
28. Enhanced strength and ductility in a friction stir processing engineered dual phase high entropy alloy10.1038/s41598-017-16509-9 ↗
29. Mechanical properties of ultrafine grained ferritic steel sheets fabricated by rolling and annealing of duplex microstructure10.1007/s10853-008-2971-9 ↗
30. Effects of thermal aging on mechanical properties and microstructures of an interstitial high entropy alloy with ultrasonic surface mechanical attrition treatment10.1016/j.msea.2022.142755 ↗
31. Effects of ultrasonic surface mechanical attrition treatment on microstructures and mechanical properties of high entropy alloys10.1016/j.intermet.2017.11.018 ↗
32. Dual mechanisms of grain refinement in a FeCoCrNi high-entropy alloy processed by high-pressure torsion10.1038/srep46720 ↗
33. Designing (Ultra)fine-grained high-entropy alloys by spark plasma sintering and equal-channel angular pressing10.3390/cryst10121157 ↗
34. Microstructure and properties of a CoCrFeNiMn high-entropy alloy processed by equal-channel angular pressing10.1016/j.msea.2017.08.083 ↗
35. Tensile ductility of an AlCoCrFeNi multi-phase high-entropy alloy through hot isostatic pressing (HIP) and homogenization10.1016/j.msea.2015.08.078 ↗
36. Investigation on microstructure and properties of AlxCoCrFeMnNi high entropy alloys by ultrasonic impact treatment10.1016/j.jallcom.2019.152626 ↗
37. Microstructure and mechanical properties of CoCrFeMnNi high entropy alloy with ultrasonic nanocrystal surface modification process10.1016/j.jmst.2020.02.083 ↗
38. Effect of Zr content on microstructure and mechanical properties of AlCoCrFeNi high entropy alloy10.1016/j.matdes.2016.01.033 ↗
39. Powder metallurgical processing of equiatomic AlCoCrFeNi high entropy alloy: microstructure and mechanical properties10.1016/j.msea.2016.09.062 ↗
40. Heat treatment impacts the micro-structure and mechanical properties of AlCoCrFeNi high entropy alloy10.1016/j.jallcom.2016.05.034 ↗
41. Effect of Co content on phase formation and mechanical properties of (AlCoCrFeNi)100-xCox high-entropy alloys10.1016/j.msea.2017.10.088 ↗
42. Friction stir processing of stainless steel for ascertaining its superlative performance in bioimplant applications10.1021/acsami.7b11064 ↗
43. Improving the high temperature oxidation resistance of high entropy alloy by surface modification
44. A review of dynamic recrystallization phenomena in metallic materials10.1016/j.matdes.2016.09.012 ↗
45. Enhanced oxidation resistance of ultrafine grain microstructure AlCoCrFeNi high entropy alloy10.1021/acsomega.1c06014 ↗
46. Relationship between grain size and Zener–Holloman parameter during friction stir processing in AZ31 Mg alloys10.1016/j.scriptamat.2004.05.043 ↗
47. Phase separation in equiatomic AlCoCrFeNi high-entropy alloy10.1016/j.ultramic.2012.12.015 ↗
48. Relationship between the microstructure and mechanical properties of an equiatomic AlCoCrFeNi high-entropy alloy fabricated by selective electron beam melting10.1016/j.msea.2016.01.019 ↗
49. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element
50. Modifying transformation pathways in high entropy alloys or complex concentrated alloys via thermo-mechanical processing10.1016/j.actamat.2018.05.009 ↗
51. Phase transformation during friction stir processing of dual-phase 600 steel10.1007/s10853-019-04270-5 ↗
52. First-principles study of BCC/FCC phase transition promoted by interstitial carbon in iron10.2320/matertrans.M2018014 ↗
53. Study of the plastic deformation mechanism of TRIP–TWIP high entropy alloys at the atomic level10.1016/j.ijplas.2019.102649 ↗
54. Transformation stress modeling in new FeMnAlNi shape memory alloy10.1016/j.ijplas.2016.08.003 ↗
55. Transformation-enhanced strength and ductility in a FeCoCrNiMn dual phase high-entropy alloy10.1016/j.msea.2020.139182 ↗
56. Grain refinement strengthening of a micro-crystalline high nitrogen austenitic stainless steel10.1016/S0167-577X(02)01076-5 ↗
57. Enhanced strength and ductility of bulk CoCrFeMnNi high entropy alloy having fully recrystallized ultrafine-grained structure10.1016/j.matdes.2017.07.054 ↗
58. Tensile deformation
59. The strengthening effects of relatively lightweight AlCoCrFeNi high entropy alloy10.1016/j.matchar.2019.03.006 ↗
60. A design of TiZr-rich body-centered cubic structured multi-principal element alloys with outstanding tensile strength and ductility10.1016/j.msea.2021.141135 ↗
61. Optimize the mechanical properties of Al0.6CoCrFeNi high-entropy alloys by thermo-mechanical processing
62. Strengthening in Al0.25CoCrFeNi high-entropy alloys by cold rolling10.1016/j.msea.2017.09.089 ↗
63. X-ray line broadening from filed aluminium and wolfram10.1016/0001-6160(53)90006-6 ↗
64. Dislocation densities in some annealed and cold-worked metals from measurements on the X-ray debye-scherrer spectrum10.1080/14786435608238074 ↗
65. Estimation of lattice strain in nanocrystalline silver from X-ray diffraction line broadening10.1007/s10853-007-2300-8 ↗
66. On the relationship between uniaxial yield strength and resolved shear stress in polycrystalline materials10.1016/S0022-3115(00)00378-0 ↗
67. Dynamic strain aging of Al0.3CoCrFeNi high entropy alloy single crystals10.1016/j.scriptamat.2015.06.022 ↗
68. Optimizing the coupled effects of Hall-Petch and precipitation strengthening in a Al0.3CoCrFeNi high entropy alloy10.1016/j.matdes.2017.02.072 ↗