Ultrasonic synthesis and characterization of SnFe12O19/GO nanocomposite: Application of multivariate optimization in magnetic solid-phase extraction
Source abstract
Abstract
Abstract In this work, tin hexaferrite (SnFe12O19) nanostructures are successfully synthesized using starch as non-toxic reagents. Also, for the first time, the nanostructures are applied in solid-phase extraction. To achieve the desired sample for solid-phase extraction applications, modeling and multivariate optimization are used in the two steps. The first step is the green ultrasonic-assisted synthesis of SnFe12O19 nanostructures and the second step is simultaneous magnetic solid-phase extraction of multiple heavy metals. The effect of experimental and instrumental parameters is optimized using sonochemical method based on the smaller crystal size of the nanostructures for the synthesis step. For achieving the best nano-sized product, a design using the Box-Behnken method and response surface methodology are selected as statistical methods. The strategy causes a reducing in the number of runs, which will decrease overall cost by saving in chemicals and time. The size of the SnFe12O19 nanostructures is studied by XRD. The studies show the molar ratio of Sn+2 to Fe+3, sonication power and sonication time can affect the size of the samples. Characterization of the nanostructures is accomplished by XRD, FT-IR, EDS, FE-SEM, HRTEM, BET and VSM analysis. At the second step, a nanocomposite based on SnFe12O19 and magnetic graphene oxide (SnFe12O19/GO) is prepared. The nanocomposite is used as a new nano-adsorbent for simultaneous separation as well as detection of some heavy metals containing Pb, Cu, Cd, Zn ions. Flame atomic absorption spectrometry is applied for analyzing the metal ions. Using the study, the limits of detection are obtained 0.10, 0.11, 0.14 and 0.32 μg L−1 for Pb2+, Cu2+, Cd2+ and Zn2+, respectively. Finally, the proposed procedure is performed for analysis of different real samples containing tap water, seawater and human hair, and satisfactory data are observed. The results show that the proposed magnetic solid-phase is a potential method for environmental and biological samples analysis.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Advancements in Battery Materials · Extraction and Separation Processes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (72)
Show source-provided references
1. Response surface methodology (RSM) as a tool for optimization in analytical chemistry10.1016/j.talanta.2008.05.019 ↗
2. Application of factorial designs and response surface methodology in modern experimental design and optimization10.1080/10408340600969478 ↗
3. Some new three level designs for the study of quantitative variables10.1080/00401706.1960.10489912 ↗
4. Process optimization for green synthesis of silver nanoparticles by Sclerotinia sclerotiorum MTCC 8785 and evaluation of its antibacterial properties10.1186/s40064-016-2558-x ↗
5. Size-dependent magnetic properties of iron oxide nanoparticles10.1016/j.jpcs.2015.09.008 ↗
6. A new strategy based on thermodiffusion of ceramic nanopigments into metal surfaces and formation of anti-corrosion coatings10.1016/j.micromeso.2015.06.039 ↗
7. Design principles of ion selective nanostructured membranes for the extraction of lithium ions10.1038/s41467-019-13648-7 ↗
8. A novel composite of nanomagnetite-immobilized-baker’s yeast on the surface of activated carbon for magnetic solid phase extraction of Hg(II)10.1016/j.fuel.2014.09.002 ↗
9. Synthesis, characterization and electrochemical sensing application of CoFe2O4/graphene magnetic nanocomposite for analysis of atenolol10.1016/j.poly.2020.114479 ↗
10. New molecular understanding of hydrated ion trapping mechanism during thermally-driven desalination by pervaporation using GO membrane10.1016/j.memsci.2019.117687 ↗
11. A sensitive lead titanate nano-structured sensor for electrochemical determination of pentoxifylline drug in real samples10.1007/s40097-019-0295-8 ↗
12. Spaldin · 2010
13. Perspectives on permanent magnetic materials for energy conversion and power generation10.1007/s11661-012-1278-2 ↗
14. Simultaneous determination of cholesterol, ascorbic acid and uric acid as three essential biological compounds at a carbon paste electrode modified with copper oxide decorated reduced graphene oxide nanocomposite and ionic liquid10.1016/j.jcis.2019.10.007 ↗
15. 3D reduced graphene oxide/FeNi3-ionic liquid nanocomposite modified sensor; an electrical synergic effect for development of tert-butylhydroquinone and folic acid sensor10.1016/j.compositesb.2019.05.065 ↗
16. Gold nanorods conjugated porous silicon nanoparticles encapsulated in calcium alginate nano hydrogels using microemulsion templates10.1021/acs.nanolett.7b05210 ↗
17. Sol-gel synthesis and micro-Raman characterization of ε-Fe2O3 micro- and nanoparticles10.1021/acs.chemmater.5b03566 ↗
18. Magnetic and electrical properties of M-type nano-strontium hexaferrite prepared by sol-gel combustion method10.1016/j.jmmm.2017.08.065 ↗
19. Synthesis of magnetic γ-Fe2O3-based nanomaterial for ultrasonic assisted dyes adsorption: modeling and optimization10.1016/j.ultsonch.2016.04.011 ↗
20. Sonochemical synthesis of CoFe2O4 nanoparticles and their application in magnetic polystyrene nanocomposites10.1016/j.jiec.2014.01.010 ↗
21. Optimization of nickel oxide nanoparticle synthesis through the sol-gel method using Box-Behnken design10.1016/j.matdes.2015.07.176 ↗
22. Box · 1987
23. Box-Behnken design based optimization of solar induced photo catalytic decolourization of textile dye effluent
24. A review on heavy metal pollution, toxicity and remedial measures: current trends and future perspectives10.1016/j.molliq.2019.111197 ↗
25. Mercury (II) and methyl mercury speciation on Streptococcus pyogenesloaded Dowex Optipore SD-210.1016/j.jhazmat.2009.03.100 ↗
26. Magnetic solid-phase extraction using carbon nanotubes as sorbents: a review10.1016/j.aca.2015.07.046 ↗
27. Recent advances in graphene-based magnetic composites for magnetic solid-phase Extraction10.1016/j.trac.2018.01.009 ↗
28. Synthesis and characterization of the core-shell magnetic molecularly imprinted polymers (Fe₃O₄@MIPs) adsorbents for effective extraction and determination of sulfonamides in the poultry feed10.1016/j.chroma.2012.04.061 ↗
29. EDTA functionalized magnetic graphene oxide for removal of Pb(II), Hg(II) and Cu(II) in water treatment: adsorption mechanism and separation property10.1016/j.cej.2015.06.043 ↗
30. Yuezhong Xian, Synthesis of water-soluble magnetic graphene nanocomposites for recyclable removal of heavy metal ions10.1039/C2TA00294A ↗
31. Simultaneous removal of Cd(II) and ionic dyes from aqueous solution using magnetic graphene oxide nanocomposite as an adsorbent10.1016/j.cej.2013.04.045 ↗
32. Facile synthesis of smart magnetic graphene for safe drinking water: heavy metal removal and disinfection control10.1021/sc300112z ↗
33. Highly dispersed magnetic molecularly imprinted nanoparticles with well-defined thin film for the selective extraction of glycoprotein10.1039/C6TB00409A ↗
34. Chemical synthesis of Fe3O4-graphene oxide nanohybrids as building blocks for magnetic and conductive membranes10.1016/j.mseb.2014.07.004 ↗
35. Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications10.1021/cr3000412 ↗
36. Graphene-ZnO nanocomposite for highly efficient photocatalytic degradation of methyl orange dye under solar light irradiation10.1007/s11814-015-0145-4 ↗
37. Controlled assembly of Fe3O4 magnetic nanoparticles on Graphene oxide10.1039/c0nr00776e ↗
38. Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal10.1021/nn1008897 ↗
39. Reduced graphene oxide-metal/metal oxide composites: facile synthesis and application in water purification10.1016/j.jhazmat.2010.11.100 ↗
40. One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal10.1016/j.carbon.2012.01.057 ↗
41. Efficient removal of uranium from aqueous solution by zero-valent iron nanoparticle and its graphene composite10.1016/j.jhazmat.2015.02.028 ↗
42. Preparation and characterization of porous reduced graphene oxide based inverse spinel nickel ferrite nanocomposite for adsorption removal of radionuclides10.1016/j.jhazmat.2016.12.035 ↗
43. Grafting of CuFe12O19 nanoparticles on CNT and graphene: eco-friendly synthesis, characterization and photocatalytic activity10.1016/j.jclepro.2017.11.177 ↗
44. Facile synthesis, characterization and magnetic property of CuFe12O19 nanostructures via a sol-gel auto-combustion process10.1016/j.jmmm.2015.10.049 ↗
45. Efficient Reduction of graphite oxide by sodium borohydride and its effect on electrical conductance10.1002/adfm.200900167 ↗
46. Application of Box-Behnken design to determine the optimal conditions of reductive leaching of MnO2 from manganese mine tailings10.3103/S1067821215020029 ↗
47. 1985
48. Using very toxic or especially hazardous chemical substances in a research and teaching institution10.1016/j.ssci.2016.04.019 ↗
49. In situ synthesis and characterization of CuFe10Al2O19/MWCNT nanocomposites for supercapacitor and microwave-absorbing applications10.1021/ie4005783 ↗
50. Synthesis of barium ferrite ultrafine powders by a sol–gel combustion method using glycine gels10.1016/j.jallcom.2013.08.156 ↗
51. Hydrothermal synthesis of zinc oxide nanoparticles using rice as soft biotemplate10.1186/1752-153X-7-136 ↗
52. Preparation and characterization of Pt/TiO2 nanotubes catalyst for methanol electro-oxidation10.1016/j.apcatb.2011.06.022 ↗
53. Adsorption of heavy metals from electroplating wastewater by wood sawdust10.1016/j.biortech.2005.12.014 ↗
54. Low loss MnZn ferrites for applications in the frequency region of 1-3 MHz10.1016/j.jmmm.2018.06.056 ↗
55. Synthesis of hollow spheres of BiFeO3 from nitrate solutions with tartaric acid: morphology and magnetic properties10.1016/j.jallcom.2018.10.387 ↗
56. Hydrogen-rich syngas production with tar elimination via biomass chemical looping gasification (BCLG) using BaFe2O4/Al2O3 as oxygen carrier10.1016/j.cej.2020.124107 ↗
57. Structural evolution and characteristics of the phase transformations between α-Fe2O3, Fe3O4 and γ-Fe2O3 nanoparticles under reducing and oxidizing atmosphere10.1039/c3ce41269e ↗
58. Enhanced photocatalytic removal of phenazopyridine by using silver-impregnated SiO2-TiO2 nanoparticles: optimization of synthesis variables10.1007/s11164-015-2000-y ↗
59. Investigation of experimental and instrumental parameters on properties of PbFe12O19 nanostructures prepared by sonochemical method, Ultrason10.1016/j.ultsonch.2017.06.023 ↗
60. Synthesis of Pd-Sn nanoparticles by ultrasonic irradiation and their electrocatalytic activity for oxygen reduction10.1016/j.electacta.2008.12.054 ↗
61. Graphene as a new sorbent in analytical chemistry10.1016/j.trac.2013.05.011 ↗
62. Thiol-functionalised mesoporous silica-coated magnetite nanoparticles for high efficiency removal and recovery of Hg from water10.1016/j.watres.2012.04.032 ↗
63. Anodic stripping voltammetry for direct determination of heavy metals in bovine seminal plasma using thick film modified graphite electrodes10.1016/j.microc.2019.03.091 ↗
64. Preparation and characterization of magnetic allylamine modified graphene oxide-poly(vinyl acetate-co-divinylbenzene) nanocomposite for vortex assisted magnetic solid phase extraction of some metal ions10.1016/j.talanta.2015.08.032 ↗
65. Determination and health risk assessment of heavy metals in imported rice bran oil in Iran10.1016/j.jfca.2019.103384 ↗
66. Polypyrrole/multi -walled carbon nanotube composite for the solid phase extraction of lead(II) in water samples10.1016/j.talanta.2013.11.044 ↗
67. Solid phase extraction of lead, cadmium and zinc on biodegradable polyhydroxybutyrate diethanol amine (PHB-DEA) polymer and their determination in water and food samples10.1016/j.foodchem.2016.04.079 ↗
68. SiO2-coated magnetic graphene oxide modified with polypyrrole–polythiophene: a novel and efficient nanocomposite for solid phase extraction of trace amounts of heavy metals10.1016/j.talanta.2017.02.066 ↗
69. In situ synthesis and properties of reduced graphene oxide/Bi nanocomposites: as an electroactive material for analysis of heavy metals10.1016/j.bios.2012.12.031 ↗
70. A smart-phone-based electrochemical platform with programmable solid-state-microwaveflow digestion for determination of heavy metals in liquid food10.1016/j.foodchem.2019.125378 ↗
71. Multi-colour bipolar electrochemiluminescence for heavy metal ion detection10.1039/C8CC08472F ↗
72. Modification of carbon screen-printed electrodes by adsorption of chemically synthesized Bi nanoparticles for the voltammetric stripping detection of Zn(II), Cd(II) and Pb(II)10.1016/j.talanta.2009.07.039 ↗