Redox synthesis of poly ( p –phenylenediamine)–reduced graphene oxide for the improvement of electrochemical performance of lithium titanate in lithium–ion battery anode
Source abstract
Abstract
Abstract Poly ( p –phenylenediamine)–reduced graphene oxide/lithium titanate (P p PDA–RGO)/Li 4 Ti 5 O 12 (PG/LTO) nanocomposites were prepared by a simple one–step synthesis procedure using the redox reactions of a graphene oxide/LTO (GO/LTO) suspension and p –phenylenediamine ( p PDA). The effect of p PDA on both the reduction of GO and the electrochemical performance in a lithium battery anode was systematically evaluated at different p PDA loadings. The rate capabilities of the PG/LTO nanocomposites were found to be superior to those of both GO/LTO and pristine LTO. Optimum electrochemical performance was ultimately obtained with a p PDA:GO ratio of 3:1. The use of p PDA increased the reduction of GO/LTO and ensured good contact between the RGO and LTO, thereby increasing the electrical conductivity of the nanocomposites.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
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References (62)
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1. The role of nanotechnology in the development of battery materials for electric vehicles10.1038/nnano.2016.207 ↗
2. Application–specific electrical characterization of high power batteries with lithium titanate anodes for electric vehicles10.1016/j.energy.2016.06.088 ↗
3. Life cycle assessment of high capacity molybdenum disulfide lithium–ion battery for electric vehicles10.1016/j.energy.2017.01.096 ↗
4. Nanoparticles–constructed spinel Li4Ti5O12 with extra surface lithium storage capability towards advanced lithium–ion batteries10.1016/j.electacta.2016.06.046 ↗
5. Conductive inks based on a lithium titanate nanotube gel for high–rate lithium–ion batteries with customized configuration10.1002/adma.201505161 ↗
6. Monodispersed Li4Ti5O12 with controlled morphology as high power lithium ion battery anodes10.1002/cnma.201600106 ↗
7. Simple sol-gel method synthesis of 3–dimension Li4Ti5O12–TiO2nanostructures using butterfly wings as biotemplates for high rate performance lithium–ion batteries
8. Synthesis of lithium titanium oxide (Li4Ti5O12) with ultrathin carbon layer using supercritical fluids for anode materials in lithium batteries10.1007/s10853-016-9920-9 ↗
9. Individually carbon–coated and electrostatic–force–derived graphene–oxide–wrapped lithium titanium oxide nanofibers as anode material for lithium–ion batteries10.1016/j.electacta.2016.03.137 ↗
10. Super high–rate, long cycle life of europium–modified, carbon–coated, hierarchical mesoporous lithium–titanate anode materials for lithium ion batteries10.1039/C6TA03162E ↗
11. Hierarchical carbon–coated acanthosphere–like Li4Ti5O12 microspheres for high–power lithium–ion batteries10.1016/j.jpowsour.2016.02.084 ↗
12. Advanced mesoporous spinel Li4Ti5O12/rGO composites with increased surface lithium storage capability for high–power lithium–ion batteries10.1021/acsami.6b01644 ↗
13. Preparation of Li4Ti5O12 nanosheets/carbon nanotubes composites and application of anode materials for lithium–ion batteries10.1016/j.electacta.2016.04.053 ↗
14. A three–dimensional core–shell nanostructured composite of polypyrrole wrapped MnO2/reduced graphene oxide/carbon nanotube for high performance lithium ion batteries10.1016/j.jcis.2017.01.008 ↗
15. N–doped Li4Ti5O12 nanoflakes derived from 2D protonated titanate for high performing anodes in lithium ion batteries10.1039/C6TA01954D ↗
16. Mesoporous spherical Li4Ti5O12/TiO2 composites as an excellent anode material for lithium–ion batteries10.1016/j.electacta.2016.06.153 ↗
17. Confined growth of Li4Ti5O12 nanoparticles in nitrogen–doped mesoporous graphene fibers for high–performance lithium–ion battery anodes10.1007/s12274-016-1001-5 ↗
18. Double carbon decorated lithium titanate as anode material with high rate performance for lithium–ion batteries10.1016/j.pnsc.2016.05.005 ↗
19. Synthesis and electrochemical performance of Li4Ti5O12 submicrospheres coated with TiN as anode materials for lithium–ion battery10.1016/j.ceramint.2016.06.198 ↗
20. Preparation and electrochemical properties of Mg2+ and F− co–doped Li4Ti5O12 anode material for use in the lithium–ion batteries10.1016/j.electacta.2016.11.073 ↗
21. A strategy for synthesis of nanosheets consisting of alternating spinel Li4Ti5O12 and rutile TiO2 lamellas for high–rate anodes of lithium–ion batteries10.1021/acsami.6b15021 ↗
22. Laser reduced graphene for supercapacitor applications10.1016/j.jpowsour.2016.10.108 ↗
23. Reduced graphene oxide based ternary nanocomposite cathodes for high–performance aqueous asymmetric supercapacitors10.1016/j.electacta.2017.02.095 ↗
24. Comparison of reduction products from graphite oxide and graphene oxide for anode applications in lithium–ion batteries and sodium–ion batteries10.1039/C6NR07650E ↗
25. All–solid–state microscale lithium–ion battery fabricated by a simple process with graphene as anode10.1016/j.sna.2016.10.029 ↗
26. Enhancing the electrochemistry performance of Li4Ti5O12 for Li–ion battery anodes by a sol–gel assisted molten salt method and graphene modification10.1039/C6RA19938K ↗
27. Li4Ti5O12/reduced graphene oxide composite as a high–rate anode material for lithium ion batteries10.1016/j.electacta.2016.05.077 ↗
28. Nanosized Li4Ti5O12/graphene hybrid materials with low polarization for high rate lithium ion batteries10.1016/j.jpowsour.2011.06.002 ↗
29. A facial solvothermal reduction route for the production of Li4Ti5O12/graphene composites with enhanced electrochemical performance10.1016/j.ceramint.2015.08.115 ↗
30. Single–layer graphene–wrapped Li4Ti5O12 anode with superior lithium storage capability10.1016/j.carbon.2016.12.022 ↗
31. Synthesis and characterization of Li4Ti5O12/graphene composite as anode material with enhanced electrochemical performance10.1007/s11581-012-0813-x ↗
32. 2D MoS2/polyaniline hetero structures with enlarged interlayer spacing for superior lithium and sodium storage
33. SnO2/polypyrrole hollow spheres with improved cycle stability as lithium–ion battery anodes10.1016/j.jallcom.2016.08.229 ↗
34. Effect of PEDOT: PSS coating on manganese oxide nanowires for lithium ion battery anodes10.1016/j.electacta.2015.11.061 ↗
35. Functionalization and reduction of graphene oxide with p–phenylene diamine for electrically conductive and thermally stable polystyrene composites10.1021/am201654b ↗
36. Gas sensor based on p–phenylenediamine reduced graphene oxide10.1016/j.snb.2012.01.016 ↗
37. Structure of functionalized nitrogen–doped graphene hydrogels derived from isomers of phenylenediamine and graphene oxide based on their high electrochemical performance10.1016/j.electacta.2016.07.054 ↗
38. Size–Controlled TiO2 nanocrystals with exposed {001} and {101} facets strongly linking to graphene oxide via p–Phenylenediamine for efficient photocatalytic degradation of fulvic acids10.1016/j.jhazmat.2016.04.026 ↗
39. Chemical functionalization of graphene sheets by solvothermal reduction of a graphene oxide suspension in N–methyl–2–pyrrolidone10.1039/C0JM02790A ↗
40. Poly (p–phenylenediamine)/graphene nanocomposites for supercapacitor applications10.1039/C2JM33627H ↗
41. Synthesis and electrochemical performance of nano–sized Li4Ti5O12 with double surface modification of Ti(III) and carbon10.1039/b908025b ↗
42. Preparation of crumpled reduced graphene oxide–poly(p–phenylenediamine) hybrids for the detection of dopamine10.1039/c3ta12594g ↗
43. Graphene oxide/lithium titanate composite with binder–free as high capacity anode material for lithium–ion batteries10.1016/j.jpowsour.2014.09.154 ↗
44. Improved electrochemical performance of Li4Ti5O12 with a variable amount of graphene as a conductive agent for rechargeable lithium–ion batteries by solvothermal method10.1016/j.matchemphys.2012.08.048 ↗
45. Reduced chemically modified graphene oxide for supercapacitor electrode10.1186/1556-276X-9-535 ↗
46. Covalently bonded reduced graphene oxide/polyaniline composite for electrochemical sensors and capacitors10.1016/j.jelechem.2015.10.023 ↗
47. On the polymerization of p-phenylenediamine10.1016/0014-3057(95)00118-2 ↗
48. Raman spectra of graphite oxide and functionalized graphene sheets10.1021/nl071822y ↗
49. Black mesoporous Li4Ti5O12−δ nanowall arrays with improved rate performance as advanced 3D anodes for micro batteries10.1039/C6TA06699B ↗
50. Individually carbon–coated and electrostatic–force–derived graphene–oxide–wrapped lithium titanium oxide nanofibers as anode material for lithium-ion batteries10.1016/j.electacta.2016.03.137 ↗
51. A double core–shell modification of bulk TiO2 microspheres into porous N–doped–graphene carbon nanoflakes/N–doped TiO2 microspheres for lithium–ion battery anodes10.1039/C5RA06573A ↗
52. Phenolic resin–grafted reduced graphene oxide as a highly stable anode material for lithium ion batteries10.1039/C4CP04556D ↗
53. Li4Ti5O12/reduced graphene oxide composite as a high rate capability material for lithium ion batteries10.1016/j.ssi.2013.02.004 ↗
54. Investigation of effects of carbon coating on the electrochemical performance of Li4Ti5O12/C nanocomposites10.1039/c3ta00114h ↗
55. Percolation threshold of graphene nanosheets as conductive additives in Li4Ti5O12 anodes of Li–ion batteries10.1039/c2nr33099g ↗
56. The effect of diethylenetriamine on the solvothermal reactions of polyethyleneimine–graphene oxide/lithium titanate nanocomposites for lithium battery anode10.1016/j.jpowsour.2014.11.069 ↗
57. Controlled Ag–driven superior rate–capability of Li4Ti5O12 anodes for lithium rechargeable batteries10.1007/s12274-013-0313-y ↗
58. A facile strategy to prepare nano–crystalline Li4Ti5O12/C anode material via polyvinyl alcohol as carbon source for high–rate rechargeable li–ion batteries10.1016/j.electacta.2013.01.112 ↗
59. Different effect of the atmospheres on the phase formation and performance of Li4Ti5O12 prepared from ball–milling–assisted solid–phase reaction with pristine and carbon–precoated TiO2 as starting material10.1021/jp111353e ↗
60. Exploring the use of electrochemical impedance spectroscopy (EIS) in microbial fuel cell studies10.1039/B814914C ↗
61. Graphene as a conductive additive to enhance the high–rate capabilities of electrospun Li4Ti5O12 for lithium–ion batteries10.1016/j.electacta.2010.05.029 ↗
62. Application of a bio–derivative, rosin, as a binder additive for lithium titanium oxide electrodes in lithium–ion batteries10.1016/j.jpowsour.2014.09.160 ↗