Influence of La/Al ratio on the structure and spectroscopy of Tm3+ doped Al2O3La2O3SiO2 glasses

Abstract Lanthanum aluminosilicate (LAS) glasses with compositions (Tm 2 O 3 ) 0.8 -(Al 2 O 3 ) 12- x (La 2 O 3 ) x -(SiO 2 ) 87.2 (x = 0, 1.2, 4.5 mol%; La/Al = 0, 1/9, 3/5) were prepared via a sol–gel method combined with high temperature sintering. The total amount of Al 2 O 3 and La 2 O 3 was 12 mol%. The effect of the La/Al ratio on the structure and spectroscopic properties of Tm 3+ has been studied in detail. The structure of Tm 3+ doped LAS glasses was studied via 27 Al nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. The spinning sideband patterns of the 27 Al NMR spectra showed that the population of Tm 3+ ions in the vicinity of Al 3+ decreased with an increase in the La 2 O 3 concentration. FTIR and Raman spectra suggest that glasses with high La/Al ratios have less interconnected glass networks. The spectroscopic properties of Tm 3+ ions were investigated via the Judd–Ofelt method using the measurement of absorption and emission spectra. Both the 1.8 μm fluorescence intensity and the relative intensity of up-conversion emission of Tm 3+ ions decrease with an increase in the La/Al ratio. This indicates reduced cross relaxation between Tm 3+ ions in glass with a high La/Al ratio. We conclude that the spatial distribution homogeneity of Tm 3+ ions in LAS glass improves when the La/Al ratio increases.