Dual activation of peroxymonosulfate with FeS2@Co3O4-C catalyst and visible light for the efficient degradation of tetracycline
Source abstract
Abstract
Antibiotics have garnered global attention as a pressing concern due to their wide spread discharge to the environment and resulting significant threats to both human health and the environment. The Sulfate Radical-based Advanced Oxidation Processes (SR-AOPs) technique has already been verified as an effective process for pollutant degradation. Herein, FeS 2@Co 3O 4-C composites, utilizing ZIF-67-derived Co 3O 4-C as the substrate material, were fabricated using a single-step solvothermal technique for the degradation of tetracycline (TC) by activated peroxymonosulfate (PMS) in combination with visible light irradiation. In the FeS 2@Co 3O 4-C/PMS/Vis system, the FeS 2@Co 3O 4-C showed better activation performance than the single chemical activation system or photocatalytic system, with 97.2 % TC removed in 20 min. The FeS 2@Co 3O 4 -C composite material was thoroughly investigated employing X-ray diffraction (XRD) for analyzing its crystal structure, transmission electron microscopy (TEM) for detailed structural insights, scanning electron microscopy (SEM) for morphological examination, and X-ray photoelectron spectroscopy (XPS) for the elemental valence states. The quenching experiments, along with EPR test, revealed that the primary active oxygen species consisted of 1O 2, O 2 ·-, and h +. The results presented here suggest the impressive stability and recyclability of FeS 2@Co 3O 4 -C making it a potential candidate as an efficient catalyst for initiating the activation of PMS in degrading persistent organic pollutants present in water.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced oxidation water treatment · Advanced Photocatalysis Techniques · Advanced Nanomaterials in Catalysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (55)
Show source-provided references
1. Global review of macrolide antibiotics in the aquatic environment: sources, occurrence, fate, ecotoxicity, and risk assessment10.1016/j.jhazmat.2022.129628 ↗
2. Occurrence, distribution, and ecological risk assessment of pharmaceuticals and personal care products in the surface water of the middle and lower reaches of the Yellow River (Henan section)10.1016/j.jhazmat.2022.130369 ↗
3. Occurrence, fate, and ecological risk of antibiotics in wastewater treatment plants in China: a review10.1016/j.jhazmat.2024.133925 ↗
4. Environmental fate of tetracycline antibiotics: degradation pathway mechanisms, challenges, and perspectives
5. Antibiotic occurrence, environmental risks, and their removal from aquatic environments using microalgae: advances and future perspectives10.1016/j.chemosphere.2023.140822 ↗
6. Mechanistic understanding of polychlorinated biphenyls degradation by peroxymonosulfate activated with CuFe2O4 nanoparticles: key role of superoxide radicals10.1016/j.cej.2018.04.215 ↗
7. Molybdenum disulfide (MoS2): a versatile activator of both peroxymonosulfate and persulfate for the degradation of carbamazepine10.1016/j.cej.2019.123264 ↗
8. Fast degradation of atrazine by nZVI-Cu0/PMS: re-evaluation and quantification of reactive species, generation pathways, and application feasibility10.1016/j.watres.2023.120311 ↗
9. Experimental and DFT insights into the visible-light driving metal-free C3N5 activated persulfate system for efficient water purification10.1016/j.apcatb.2021.120023 ↗
10. Role of inorganic anions in improving the oxidizing capacity of heat-activated peroxymonosulfate: identification of primary degradative pathways10.1016/j.cej.2023.147472 ↗
11. Enhanced humic acid degradation by Fe3O4/ultrasound-activated peroxymonosulfate: synergy index, non-radical effect and mechanism10.1016/j.seppur.2021.118466 ↗
12. Effect of UV/peroxymonosulfate pretreatment on disinfection byproduct (DBP) formation during post-chlorination of humic acid
13. Construction of Sn-Bi-MOF/Ti3C2 Schottky junction for photocatalysis of tetracycline: performance and degradation mechanism10.1016/j.apsusc.2022.155191 ↗
14. MIL-101(Fe)/WS2 composites activated Na2S2O8 with visible light for removal of tetracycline10.1007/s11356-023-30914-w ↗
15. Efficient activation of K2S2O8 by MoS2-ZnFe2O4 composite for the rapid degradation of tetracycline10.1016/j.matlet.2022.132204 ↗
16. One-step solvothermal construction of coral reef-like FeS2/biochar to activate peroxymonosulfate for efficient organic pollutant removal10.1016/j.seppur.2022.122976 ↗
17. Enhanced activation of PMS by a novel Fenton-like composite Fe3O4/S-WO3 for rapid chloroxylenol degradation10.1016/j.cej.2022.137067 ↗
18. MOF-template derived hollow CeO2/Co3O4 polyhedrons with efficient cathode catalytic capability in Li-O2 batteries10.1016/j.cclet.2021.02.010 ↗
19. Enhanced photo-Fenton activity and stability for sulfamethoxazole degradation by FeS2@TiO2 heterojunction derived from MIL-12510.1016/j.chemosphere.2023.138221 ↗
20. MOF-derived Co3O4-C@FeOOH as an efficient catalyst for catalytic ozonation of norfloxacin10.1016/j.jhazmat.2020.123697 ↗
21. Ag doped Co3O4 nanoparticles for high-performance supercapacitor application10.1016/j.heliyon.2023.e13286 ↗
22. High efficient PMS activation by synergistic effects of bimetallic sulfide FeS2@MoS2 for rapid OFX degradation10.1016/j.cej.2023.146023 ↗
23. Iron-doped cobalt oxide nanoarray for efficient electrocatalytic nitrate-to-ammonia conversion10.1016/j.jcis.2022.01.186 ↗
24. One-step solvothermal construction of coral reef-like FeS2/biochar to activate peroxymonosulfate for efficient organic pollutant removal10.1016/j.seppur.2022.122976 ↗
25. Investigation of Au/Co3O4 nanocomposites in glycol oxidation by tailoring Co3O4 morphology10.1039/D1NA00053E ↗
26. Simple and versatile one-step synthesis of FeS2 nanoparticles by ultrasonic irradiation10.1016/j.jcis.2016.02.055 ↗
27. Hierarchical nanocomposites of Co3O4/polyaniline nanowire arrays/reduced graphene oxide sheets for amino acid detection10.1016/j.snb.2014.07.054 ↗
28. Novel flower-like Fe-Mo composite for peroxydisulfate activation toward efficient degradation of carbamazepine10.1016/j.seppur.2022.122487 ↗
29. Facile synthesis of FeS2/MoS2 composite intertwined on rGO nanosheets as a high-performance anode material for sodium-ion battery10.1016/j.jallcom.2019.153222 ↗
30. Facile solvent-deficient synthesis of mesoporous γ-alumina with controlled pore structures10.1016/j.micromeso.2012.07.052 ↗
31. In-situ growth of C-F@CCS@ZIF8/67-1/1 photocatalysts with internal electric field and interfacial enhancement on cobalt-copper foam surface for simultaneous removal of ciprofloxacin and Cr(VI)10.1016/j.apcatb.2023.122857 ↗
32. Photocatalytic activity of Co3O4@C enhanced by induction of amorphous cobalt-based MOF10.1016/j.colsurfa.2022.130597 ↗
33. Synthesis and characterization of composite catalysts comprised of ZnO/MoS2/rGO for photocatalytic decolorization of BR 18 dye10.1016/j.colsurfa.2021.126945 ↗
34. Activation of Na2S2O8 by MIL-101(Fe)/Co3O4 composite for degrading tetracycline with visible light assistance10.1016/j.inoche.2022.109902 ↗
35. A nanoreactor with Z-scheme FeS2/MoS2 heterojunctions encapsulated inside the carbon capsule: insight on preparation method and enhanced performance in photo-Fenton reaction10.1016/j.cej.2022.138221 ↗
36. Oxidation of organic pollutants by peroxymonosulfate activated with low-temperature-modified nanodiamonds: understanding the reaction kinetics and mechanism10.1016/j.apcatb.2018.04.067 ↗
37. Peroxymonosulfate activation by boron doped C3N5 metal-free materials with n → π* electronic transitions for tetracycline degradation under visible light: insights into the generation of reactive species10.1016/j.cej.2023.147693 ↗
38. Peroxymonosulfate-based photocatalytic oxidation of tetracycline by Fe2(MoO4)3/Cd0.5Ni0.5S heterostructure; DFT simulation10.1016/j.chemosphere.2022.136423 ↗
39. Visible light assisted peroxymonosulfate activation by NiO/SnO2 composite for efficient tetracycline degradation10.1016/j.apsusc.2022.154537 ↗
40. Synergistic effect of facet-regulated and photocatalytic-peroxymonosulfate activation of Fe(II)/decahedron monoclinic BiVO4 composites for efficient degradation of tetracycline10.1016/j.jclepro.2024.142425 ↗
41. Visible-light enhanced peroxymonosulfate activation on Co3O4/MnO2 for the degradation of tetracycline: cooperation of radical and non-radical mechanisms10.1016/j.seppur.2023.123779 ↗
42. The synergy of sulfur vacancies and heterostructure on CoS@FeS nanosheets for boosting the peroxymonosulfate activation10.1016/j.cej.2022.136759 ↗
43. Studies on the removal of tetracycline by multi-walled carbon nanotubes10.1016/j.cej.2011.09.127 ↗
44. Efficient generation of singlet oxygen (1O2) by hollow amorphous Co/C composites for selective degradation of oxytetracycline via Fenton-like process10.1016/j.cej.2021.129594 ↗
45. Electro-assisted heterogeneous activation of peroxymonosulfate by g-C3N4 under visible light irradiation for tetracycline degradation and its mechanism10.1016/j.cej.2022.135278 ↗
46. Revealing the fundamental role of MoO2 in promoting efficient and stable activation of persulfate by iron carbon based catalysts: efficient Fe2+/Fe3+cycling to generate reactive species10.1016/j.watres.2022.119142 ↗
47. Bi3TaO7/Ti3C2 heterojunctions for enhanced photocatalytic removal of water-borne contaminants10.1016/j.envres.2020.109409 ↗
48. Facile synthesis of oxygen vacancies enriched α-Fe2O3 for peroxymonosulfate activation: a non-radical process for sulfamethoxazole degradation10.1016/j.jhazmat.2021.126447 ↗
49. High-performance alkaline freshwater and seawater hydrogen catalysis by sword-head structured Mo2N-Ni3Mo3N tunable interstitial compound electrocatalysts
50. Enhanced catalytic peroxymonosulfate activation for sulfonamide antibiotics degradation over the supported CoSx-CuSx derived from ZIF-L(Co) immobilized on copper foam10.1016/j.jhazmat.2021.128134 ↗
51. Hydrothermal synthesis of FeS2 as a highly efficient heterogeneous electro-Fenton catalyst to degrade diclofenac via molecular oxygen effects for Fe (II)/Fe(III) cycle10.1016/j.seppur.2020.117022 ↗
52. α-Fe2O3 nanodisk/bacterial cellulose hybrid membranes as high-performance sulfate-radical-based visible light photocatalysts under stirring/flowing states10.1021/acsami.8b10128 ↗
53. Two facile synthesis routes for magnetic recoverable MnFe2O4/g-C3N4 nanocomposites to enhance visible light photo-Fenton activity for methylene blue degradation10.1016/j.jece.2021.105621 ↗
54. Enhanced catalytic sulfamethoxazole degradation via peroxymonosulfate activation over amorphous CoSx@SiO2 nanocages derived from ZIF-6710.1016/j.jhazmat.2021.126998 ↗
55. Highly efficient catalysis of chalcopyrite with surface bonded ferrous species for activation of peroxymonosulfate toward degradation of bisphenol A: a mechanism study10.1016/j.jhazmat.2018.09.078 ↗