Experimental and computational analysis of stacking fault energy in B-doped Fe50−XMn30Co10Cr10BX multi-principal elements alloys
Source abstract
Abstract
The effect of boron doping in Fe 50−XMn 30Co 10Cr 10B X multi-component alloys on the resulting stacking fault energy has been experimentally and computationally assessed to understand the alloys` deformation mechanisms from structural and thermodynamic perspectives. Firstly, the fcc and hcp phases were identified together with stacking faults along their (110) planes using high-resolution transmission electron microscopy. At the same time, they were theoretically predicted through thermodynamic CALPHAD and ab initio calculations. The average stacking fault energy for the boron-free alloy was 23.9 ± 2.4 mJ/m 2 , suggesting that the deformation mechanisms relate to dislocation slip and deformation twinning. The average stacking fault energy for the highest boron content (5.4 at%) was 50.1 ± 14.1 mJ/m 2 , indicating dislocation glide as the possible deformation mechanism. The boron content in the solid solution was modelled. The modelling suggested that the presence of Cr-B, Mn-B and Fe-B bonds points towards forming (Cr,Fe) 2 B borides, which was experimentally confirmed. The borides, fcc phase stability, and the boron in solid solution contribute to increased stacking fault energy, preventing the motion of Shockley partial dislocations and influencing the ɛ-hcp martensitic transformation.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: High Entropy Alloys Studies · Additive Manufacturing Materials and Processes · High-Temperature Coating Behaviors
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. High-entropy alloys with heterogeneous microstructure: processing and mechanical properties10.1016/j.pmatsci.2020.100709 ↗
2. High-entropy alloys: a critical review10.1080/21663831.2014.912690 ↗
3. A critical review of high entropy alloys and related concepts10.1016/j.actamat.2016.08.081 ↗
4. High entropy alloys: a focused review of mechanical properties and deformation mechanisms10.1016/j.actamat.2019.12.015 ↗
5. Machine learning for high-entropy alloys: progress, challenges and opportunities10.1016/j.pmatsci.2022.101018 ↗
6. Akinwekomi · Bibliometr. Mapp. Lit. High. -Entropy/ Multicomponent Alloy. Syst. Rev. Emerg. Appl., Entropy · 2022 · 24
7. Recent experimental and theoretical advances in the design and science of high-entropy alloy nanoparticles10.1016/j.nanoen.2023.108362 ↗
8. High-entropy alloys: emerging materials for advanced functional applications10.1039/D0TA09601F ↗
9. A review on fundamental of high entropy alloys with promising high–temperature properties10.1016/j.jallcom.2018.05.067 ↗
10. Corrosion-resistant high entropy alloy with high strength and ductility10.1016/j.scriptamat.2019.03.028 ↗
11. Corrosion of high entropy alloys10.1038/s41529-017-0009-y ↗
12. The corrosion behavior of ultra-fine grained CoNiFeCrMn high-entropy alloys10.1016/j.jallcom.2019.152583 ↗
13. Influence of plastic deformation on the corrosion behavior of CrCoFeMnNi high entropy alloy10.1016/j.jallcom.2021.161822 ↗
14. CrMnFeCoNi high entropy alloys with carbon and nitrogen: mechanical properties, wear and corrosion resistance10.1007/s42452-021-04814-y ↗
15. Identification of safety gaps for fusion demonstration reactors10.1038/nenergy.2016.154 ↗
16. Phonon broadening in high entropy alloys10.1038/s41524-017-0037-8 ↗
17. Light-weight refractory high-entropy alloys: a comprehensive review10.1016/j.jmst.2022.11.054 ↗
18. High-entropy alloy: challenges and prospects10.1016/j.mattod.2015.11.026 ↗
19. Enhancing radiation tolerance by controlling defect mobility and migration pathways in multicomponent single-phase alloys10.1038/ncomms13564 ↗
20. High-entropy oxides for catalysis: a diamond in the rough10.1016/j.cej.2022.138659 ↗
21. High-entropy materials for catalysis: a new frontier10.1126/sciadv.abg1600 ↗
22. Understanding the enhanced catalytic activity of high entropy alloys: from theory to experiment10.1039/D1TA02718B ↗
23. A freestanding nanoporous NiCoFeMoMn high-entropy alloy as an efficient electrocatalyst for rapid water splitting10.1016/j.cej.2022.134898 ↗
24. High-entropy alloys as a platform for catalysis: progress, challenges, and opportunities10.1021/acscatal.0c03617 ↗
25. Recent research progress on high-entropy alloys as electrocatalytic materials10.1016/j.jallcom.2022.165585 ↗
26. High-throughput discovery of hydrogen evolution electrocatalysts in the complex solid solution system Co-Cr-Fe-Mo-Ni10.1039/D2TA01652D ↗
27. Bulk CrCoNiFe alloy with high conductivity and density of grain boundaries for oxygen evolution reaction and urea oxidation reaction10.1016/j.jcis.2023.04.055 ↗
28. High entropy alloy electrocatalysts: a critical assessment of fabrication and performance10.1039/D0TA05176D ↗
29. Recent progress on the development of high entropy alloys (HEAs) for solid hydrogen storage: a review10.1016/j.ijhydene.2022.01.141 ↗
30. A quick screening approach for design of multi-principal element alloy with solid solution phase10.1016/j.matdes.2019.107882 ↗
31. Understanding the enhanced catalytic activity of high entropy alloys: from theory to experiment10.1039/D1TA02718B ↗
32. Multicomponent and high entropy alloys10.3390/e16094749 ↗
33. Microstructural development in equiatomic multicomponent alloys10.1016/j.msea.2003.10.257 ↗
34. Multicomponent high-entropy cantor alloys10.1016/j.pmatsci.2020.100754 ↗
35. Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off10.1038/nature17981 ↗
36. Interstitial atoms enable joint twinning and transformation induced plasticity in strong and ductile high-entropy alloys
37. Evolution of microstructure and mechanical properties in gas tungsten arc welded dual-phase Fe50Mn30Co10Cr10 high entropy alloy10.1016/j.msea.2023.145233 ↗
38. Bidirectional transformation enabled improvement in strength and ductility of metastable Fe50Mn30Co10Cr10 complex concentrated alloy under dynamic deformation10.1016/j.ijplas.2023.103633 ↗
39. Strengthening mechanisms in high entropy alloys: fundamental issues10.1016/j.scriptamat.2020.06.019 ↗
40. Short-range order strengthening in boron-doped high-entropy alloys for cryogenic applications10.1016/j.actamat.2020.04.052 ↗
41. Research status of tribological properties optimization of high-entropy alloys: a review10.1007/s10853-023-08255-3 ↗
42. Effect of carbon content and annealing on structure and hardness of the CoCrFeNiMn-based high entropy alloys10.1016/j.jallcom.2016.06.103 ↗
43. Corrosion behaviour of friction stir processed, metastable, dual-phase, Fe49.5Mn30Co10Cr10C0.5, multi-principal element alloy10.1016/j.jallcom.2023.169967 ↗
44. Crystallographic orientation-dependent deformation characteristics of additive manufactured interstitial-strengthened high entropy alloys10.1016/j.scriptamat.2022.115049 ↗
45. Interstitial atoms enable joint twinning and transformation induced plasticity in strong and ductile high-entropy alloys
46. Heavy carbon alloyed FCC-structured high entropy alloy with excellent combination of strength and ductility10.1016/j.msea.2018.01.045 ↗
47. Trace B doping Fe50Mn30Co10Cr10 high entropy alloy: mechanical response and multi-microstructure evolution under TWIP and TRIP effects10.1016/j.msea.2023.145037 ↗
48. Structure characterization of special boundaries in Fe47Mn30Co10Cr10B3 dual-phase high-entropy alloy10.1016/j.jallcom.2020.157642 ↗
49. Characterization of deformation substructure evolution in metastable Fe49Mn30Co10Cr10B1 interstitial high entropy alloy10.1016/j.intermet.2022.107508 ↗
50. Effect of boronizing on the microstructure and mechanical properties of CoCrFeNiMn High-Entropy Alloy
51. The effect of boron content on the microstructure and mechanical properties of Fe 50-X Mn 30 Co 10 Cr 10 B X (x = 0, 0.3, 0.6 and 1.7 wt%) multi-component alloys prepared by arc-melting10.1016/j.msea.2019.01.088 ↗
52. Boron addition in a non-equiatomic Fe50Mn30Co10Cr10 alloy manufactured by laser cladding: microstructure and wear abrasive resistance10.1016/j.apsusc.2020.146084 ↗
53. Effect of B4C particles addition on microstructure and mechanical properties of Fe50Mn30Co10Cr10 high-entropy alloy10.1016/j.msea.2021.141642 ↗
54. A facile strengthening method by co-doping boron and nitrogen in CoCrFeMnNi high-entropy alloy10.1016/j.msea.2022.143307 ↗
55. Boron doped ultrastrong and ductile high-entropy alloys10.1016/j.actamat.2018.04.004 ↗
56. Thermodynamic and Ab Initio Design of Multicomponent Alloys Based on (Fe50Mn30Co10Cr10)-xBx (x = 0, 5, 7, 10, and 15 at%)10.3390/ma16165579 ↗
57. Significant improvement in wear resistance of CoCrFeNi high-entropy alloy via boron doping10.3390/lubricants11090386 ↗
58. Twinning-induced plasticity (TWIP) steels10.1016/j.actamat.2017.06.046 ↗
59. Stacking fault energy analyses of additively manufactured stainless steel 316L and CrCoNi medium entropy alloy using in situ neutron diffraction10.1038/s41598-020-58273-3 ↗
60. Stacking fault energies in austenitic stainless steels10.1016/j.actamat.2016.03.042 ↗
61. The influence of stacking faults on mechanical behavior of advanced materials10.1016/j.msea.2020.140696 ↗
62. A general mechanism of martensitic nucleation: Part I. General concepts and the FCC → HCP transformation
63. Effect of stacking fault energy on mechanism of plastic deformation in nanotwinned FCC metals10.1088/0965-0393/23/5/055003 ↗
64. Effect of the stacking fault energy on the mechanical properties of pure Cu and Cu-Al alloys subjected to severe plastic deformation
65. Effect of temperature on the stacking fault energy and deformation behaviour in 316L austenitic stainless steel
66. Correlating temperature-dependent stacking fault energy and in-situ bulk deformation behavior for a metastable austenitic stainless steel10.1016/j.msea.2021.142403 ↗
67. Significance of stacking fault energy in bulk nanostructured materials: insights from Cu and its binary alloys as model systems10.1016/j.pmatsci.2018.11.001 ↗
68. Towards stacking fault energy engineering in FCC high entropy alloys10.1016/j.actamat.2021.117472 ↗
69. Twinning-induced plasticity (TWIP) steels10.1016/j.actamat.2017.06.046 ↗
70. Materials selection for hot stamped automotive body parts: an application of the Ashby approach based on the strain hardening exponent and stacking fault energy of materials10.1016/j.matdes.2014.06.011 ↗
71. Correlating work hardening with co-activation of stacking fault strengthening and transformation in a high entropy alloy using in-situ neutron diffraction10.1038/s41598-020-79492-8 ↗
72. Strain hardening mechanisms during cold rolling of a high-Mn steel: Interplay between submicron defects and microtexture10.1016/j.msea.2019.03.116 ↗
73. XRD measurement of stacking fault energy of Cr–Ni austenitic steels: influence of temperature and alloying elements10.1007/s10853-020-04953-4 ↗
74. Stacking fault energy of face-centered-cubic high entropy alloys10.1016/j.intermet.2017.10.004 ↗
75. Screw dislocation driven martensitic nucleation: a step toward consilience of deformation scenario in fcc materials10.1016/j.actamat.2019.05.050 ↗
76. Stacking fault energies in austenitic stainless steels10.1016/j.actamat.2016.03.042 ↗
77. Stacking fault energy analyses of additively manufactured stainless steel 316L and CrCoNi medium entropy alloy using in situ neutron diffraction10.1038/s41598-020-58273-3 ↗
78. The influence of manganese content on the stacking fault and austenite/ε-martensite interfacial energies in Fe-Mn-(Al-Si) steels investigated by experiment and theory10.1016/j.actamat.2014.01.001 ↗
79. High entropy alloys: advanced synchrotron X-Ray and neutron scattering studies
80. Investigating the deformation mechanisms of a highly metastable high entropy alloy using in-situ neutron diffraction
81. Microstructure and magnetic behavior of FeCoNi(Mn–Si) x ( x = 0.5, 0.75, 1.0) high-entropy alloys10.1557/jmr.2019.34 ↗
82. Mechanical behavior in boron-microalloyed CoCrNi medium-entropy alloy studied by in situ high-energy X-ray diffraction10.1016/j.msea.2020.139600 ↗
83. Strain hardening mechanisms during cold rolling of a high-Mn steel: Interplay between submicron defects and microtexture10.1016/j.msea.2019.03.116 ↗
84. XRD measurement of stacking fault energy of Cr–Ni austenitic steels: influence of temperature and alloying elements10.1007/s10853-020-04953-4 ↗
85. Development of Mn-Cr-(C-N) corrosion resistant twinning induced plasticity steels: thermodynamic and diffusion calculations, production, and characterization10.1007/s11661-010-0334-z ↗
86. The stacking fault energy and its dependence on the interstitial content in various austenitic steels10.4028/www.scientific.net/MSF.706-709.2193 ↗
87. A critical review of high entropy alloys and related concepts10.1016/j.actamat.2016.08.081 ↗
88. A review of solid-solution models of high-entropy alloys based on Ab initio calculations10.3389/fmats.2017.00036 ↗
89. Ab initio assisted design of quinary dual-phase high-entropy alloys with transformation-induced plasticity10.1016/j.actamat.2017.07.023 ↗
90. Ab initio study of the effect of interstitial alloying on the intrinsic stacking fault energy of paramagnetic γ-Fe and austenitic stainless steel10.1016/j.actamat.2023.118967 ↗
91. M.C.G.J. Yeh, P.K. Liaw, Y. Zhang, High-Entropy Alloys:Fundamentals and applications, Springer Berlin Heidelberg, 2016.
92. Mechanical properties and stacking fault energies of NiFeCrCoMn high-entropy alloy10.1007/s11837-013-0771-4 ↗
93. Stacking fault energy of face-centered-cubic high entropy alloys10.1016/j.intermet.2017.10.004 ↗
94. Stacking fault energies of face-centered cubic concentrated solid solution alloys10.1016/j.actamat.2017.05.001 ↗
95. Can experiment determine the stacking fault energy of metastable alloys10.1016/j.matdes.2020.109396 ↗
96. Hierarchically activated deformation mechanisms to form ultra-fine grain microstructure in carbon containing FeMnCoCr twinning induced plasticity high entropy alloy10.1016/j.msea.2021.141803 ↗
97. A general mechanism of martensitic nucleation= Part I. General concepts and the FCC HCP
98. Strengthening via deformation twinning in a nickel alloy10.1016/j.msea.2007.06.072 ↗
99. Thermodynamics of stacking faults10.1007/BF03038365 ↗
100. Efficient stochastic generation of special quasirandom structures10.1016/j.calphad.2013.06.006 ↗