journal article·2023-12

Ti-Zr-Nb based BCC alloy containing Mo prepared by laser directed energy deposition—ω phase and cellular structure

Muhammad Akmal, Wonjong Jeong, Ho Jin Ryu

Publisher page

Abstract

This study focuses on the fabrication of Ti-Zr-Nb β-Ti alloys via laser direct energy deposition (DED) technique using pre-alloyed powder with and without having Mo traces. Microstructural analysis revealed the presence of cellular structures within the grains, resembling dendritic solidification, although no discernible dendritic segregation was observed. Nano-scale solute element clustering, particularly the formation of Nb depletion pockets, led to the development of the ω phase within the β matrix. Strengthening effects resulting from the presence of the ω phase were confirmed through TEM analysis. The DED-fabricated β-Ti alloy exhibited enhanced strength (∼1 GPa), significant elongation (∼15%), and a low elastic modulus (∼65 GPa), positioning it as a promising candidate for load-bearing biomedical implants.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Titanium Alloys Microstructure and Properties · Additive Manufacturing Materials and Processes · High Entropy Alloys Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (58)

Show source-provided references
1. Additive manufacturing of metals10.1016/j.actamat.2016.07.019 ↗
2. Additive manufacturing of titanium alloys in the biomedical field: processes, properties and applications
3. Ti based biomaterials, the ultimate choice for orthopaedic implants – A review10.1016/j.pmatsci.2008.06.004 ↗
4. 3D Printing/additive manufacturing single titanium dental implants: a prospective multicenter study with 3 years of follow-up10.1155/2016/8590971 ↗
5. Effect of the direction of the gradient on the mechanical properties and energy absorption of additive manufactured Ti-6Al-4 V functionally graded lattice structures10.1016/j.jallcom.2023.171874 ↗
6. Microstructure and mechanical properties of Ti-6Al-4V cruciform structure fabricated by coaxial electron beam wire-feed additive manufacturing10.1016/j.jallcom.2023.170943 ↗
7. Design of a low Young’s modulus Ti-Zr-Nb-Sn biocompatible alloy by in situ laser powder bed fusion additive manufacturing process10.1016/j.jallcom.2023.171539 ↗
8. Force enhanced wire laser additive manufacturing of aluminum and titanium alloys10.1016/j.jallcom.2022.168617 ↗
9. Phase transformation and microstructure control of Ti2AlNb-based alloys: A review10.1016/j.jmst.2020.11.022 ↗
10. Characterization of nickel-titanium alloy graded materials using double wire alternating current cross arc additive manufacturing10.1016/j.jallcom.2022.164912 ↗
11. Biomedical Mo particles reinforced titanium alloy fabricated by laser additive manufacturing10.1016/j.jallcom.2023.170512 ↗
12. Crystallographic texture control of beta-type Ti–15Mo–5Zr–3Al alloy by selective laser melting for the development of novel implants with a biocompatible low Young’s modulus10.1016/j.scriptamat.2016.12.038 ↗
13. Direct metal deposition of refractory high entropy alloy MoNbTaW10.1016/j.phpro.2016.08.065 ↗
14. Perspectives on additive manufacturing enabled beta- titanium alloys for biomedical applications10.18063/ijb.v8i1.478 ↗
15. Laser metal deposition of a refractory TiZrNbHfTa high-entropy alloy
16. Selective electron beam melting of Al0.5CrMoNbTa0.5 high entropy alloys using elemental powder blend10.1016/j.heliyon.2019.e01188 ↗
17. Laser metal deposition of compositionally graded TiZrNbTa refractory high-entropy alloys using elemental powder blends
18. Synthesis of Ti-5Al, Ti-6Al-7Nb, and Ti-22Al-25Nb alloys from elemental powders using powder-bed fusion additive manufacturing10.1016/j.jallcom.2018.05.325 ↗
19. Microstructural homogeneity and mechanical behavior of a selective laser melted Ti-35Nb alloy produced from an elemental powder mixture10.1016/j.jmst.2020.05.052 ↗
20. Influence of processing parameters on density, surface morphologies and hardness of as-built Ti-5Al-5Mo-5V–3Cr alloy manufactured by selective laser melting10.1016/j.jallcom.2022.164760 ↗
21. Microstructure and mechanical property of Ti–5Al–5Mo–5V–3Cr–1Zr alloy fabricated by selective laser melting with a preheated substrate10.1002/adem.202100265 ↗
22. The ageing response of direct laser deposited metastable β-Ti alloy, Ti–5Al–5Mo–5V–3Cr
23. Microstructure and mechanical properties of the near-beta titanium alloy Ti-5553 processed by selective laser melting10.1016/j.matdes.2016.04.103 ↗
24. Selective laser melting of high-strength, low-modulus Ti–35Nb–7Zr–5Ta alloy10.1016/j.mtla.2020.100941 ↗
25. Microstructure and mechanical properties of β-21S Ti alloy fabricated through laser powder bed fusion10.1007/s40964-021-00181-7 ↗
26. Additive manufacturing of a novel Ti-Al-V-Fe alloy using selective laser melting
27. On the existence of orthorhombic martensite in a near-α titanium base alloy used for additive manufacturing10.1016/j.jallcom.2021.163155 ↗
28. Densification, microstructure evolution and fatigue behavior of Ti-13Nb-13Zr alloy processed by selective laser melting10.1016/j.powtec.2018.09.073 ↗
29. Microstructure and mechanical properties of selective laser melted biomaterial Ti-13Nb-13Zr compared to hot-forging10.1016/j.msea.2018.04.001 ↗
30. Selective laser melting of Ti-45Nb alloy10.3390/met5020686 ↗
31. Mechanical properties of a newly additive manufactured implant material based on Ti-42Nb10.3390/ma11010124 ↗
32. Microstructure and corrosion resistance of novel β-type titanium alloys manufactured by selective laser melting10.1016/j.jmrt.2022.07.021 ↗
33. Role of laser powder bed fusion process parameters in crystallographic texture of additive manufactured Nb–48Ti alloy10.1016/j.jmrt.2021.06.054 ↗
34. Transformation-induced plasticity and high strength in beta titanium alloy manufactured by selective laser melting10.1016/j.mtla.2019.100299 ↗
35. Additive manufacturing of TTFNZ (Ti-4.5Ta-4Fe-7.5Nb-6Zr), a novel metastable β-titanium alloy for advanced engineering applications10.1016/j.jallcom.2022.165899 ↗
36. Evolution of microstructural complex transitions in low-modulus β-type Ti-35Nb-2Ta-3Zr alloy manufactured by laser powder bed fusion
37. Effect of laser power on anisotropic microstructure and mechanical behavior of biomedical Ti-35Nb-15Zr (at%) alloy fabricated by laser powder bed fusion
38. A study of microstructural factors governing strength and ductility of titanium alloys fabricated by powder bed fusion additive manufacturing10.1016/j.jallcom.2023.170094 ↗
39. TiZrNbTaMo high-entropy alloy designed for orthopedic implants: As-cast microstructure and mechanical properties10.1016/j.msec.2016.12.057 ↗
40. Elastic properties of the TiZrNbTaMo multi-principal element alloy studied from first principles10.1016/j.intermet.2018.12.014 ↗
41. Mo and Ta addition in NbTiZr medium entropy alloy to overcome tensile yield strength-ductility trade-off10.1016/j.jmst.2021.08.073 ↗
42. Systematic study of (MoTa)xNbTiZr medium- and high-entropy alloys for biomedical implants- in vivo biocompatibility examinations10.1016/j.jmst.2020.10.049 ↗
43. Mechanical properties of low modulus ββ titanium alloys designed from the electronic approach10.1016/j.jmbbm.2010.07.001 ↗
44. Study of the intrinsic mechanisms of nickel additive for grain refinement and strength enhancement of laser aided additively manufactured Ti–6Al–4V10.1088/2631-7990/ac6b61 ↗
45. Effects of boron addition on microstructures and mechanical properties of Ti-6Al-4V manufactured by direct laser deposition10.1016/j.matdes.2019.108191 ↗
46. Microstructure and mechanical performance tailoring of Ti-13Nb-13Zr alloy fabricated by selective laser melting after post heat treatment10.1016/j.jallcom.2018.10.030 ↗
47. J.A. Ballor, T. Li, F. Prima, C.J. Boehlert, A. Devaraj, A review of the metastable omega phase in beta titanium alloys: the phase transformation mechanisms and its effect on mechanical properties, Https://Doi.Org/10.1080/09506608.2022.2036401. (2022). 〈https://doi.org/10.1080/09506608.2022.2036401〉.10.1080/09506608.2022.2036401 ↗
48. Laser deposition and deformation behavior of Ti-Nb-Zr-Ta alloys for orthopedic implan10.1016/j.jmbbm.2012.08.014 ↗
49. Kinetic features of the isothermal ω-phase formation in superelastic Ti-Nb-Zr alloys10.1016/j.matlet.2022.132820 ↗
50. Omega phase transformation – morphologies and mechanisms
51. Origin of dislocation structures in an additively manufactured austenitic stainless steel 316L10.1016/j.actamat.2020.07.063 ↗
52. Dislocation network in additive manufactured steel breaks strength–ductility trade-off
53. Planar-cellular-dendritic transformation in the fusion zone of a GH909 superalloy weldment10.1016/j.jmrt.2020.12.033 ↗
54. The origin of striation in the metastable β phase of titanium alloys observed by transmission electron microscopy10.1107/S1600576717004150 ↗
55. Experimental evidence of concurrent compositional and structural instabilities leading to ω precipitation in titanium–molybdenum alloys10.1016/j.actamat.2011.10.008 ↗
56. Origin of ω-phase formation in metastable β-type Ti-Mo alloys: cluster structure and stacking fault10.1038/s41598-020-65254-z ↗
57. ω phase acts as a switch between dislocation channeling and joint twinning- and transformation-induced plasticity in a metastable β titanium alloy10.1016/j.actamat.2018.03.053 ↗
58. Origin of the ductile-to-brittle transition of metastable β-titanium alloys: Self-hardening of ω-precipitates10.1016/j.actamat.2019.03.034 ↗