journal article·2022-02

Ultra-wideband warm white light emission from self-trapped excitons in CsAgCl2

Tingfang Tian, Xuhui Xiong, Yaxuan Zhao, Hao Li, Wei Wang, Li Wang

Publisher page

Abstract

Abstract The materials with self-trapped exciton (STE) emission are considered to have great prospects in application of lighting, due to the large Stokes shift and wide emission band. Here we report a novel STE emission material CsAgCl2 that can emit warm white light with a spectrum covering almost the entire visible range. At room temperature, the peak wavelength of its emission is about 625 nm, and it exhibits a broad half peak width up to 235 nm. A warm white LED was prepared using a 268 nm UV LED as the excitation source. It shows a correlated color temperature (CCT) of 4062 K and a color rendering index (CRI) of 93. The results indicate that CsAgCl2 is an ideal material for high color rendering lighting.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Luminescence Properties of Advanced Materials · Solid-state spectroscopy and crystallography

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. Enhanced emission of Eu3+ in lutetium tungsten molybdenum oxide phosphors: synthesis, optical properties, thermal behavior, and LED packaging10.1016/j.jlumin.2020.117269 ↗
2. Synthesis and photoluminescent properties of Ba2+ ions doped europium formate phosphors for white light-emitting diodes10.1016/j.jlumin.2020.117252 ↗
3. Composition screening in blue-emitting Li4Sr1+xCa0.97-x(SiO4)2:Ce3+ phosphors for high quantum efficiency and thermally stable photoluminescence
4. Enhanced photoluminescence emission and thermal stability from introduced cation disorder in phosphors10.1021/jacs.7b04338 ↗
5. Preparation and properties of the flexible remote phosphor film for blue chip-based white LED10.1016/j.matdes.2016.04.022 ↗
6. A Mn4+-doped oxyfluoride phosphor with remarkable negative thermal quenching and high color stability for warm WLEDs10.1016/j.cej.2019.123657 ↗
7. Strategy for exploiting self-trapped excitons in semiconductor nanocrystals for white light generation10.1021/acsphotonics.9b00212 ↗
8. Phosphors in phosphor-converted white light-emitting diodes Recent advances in materials, techniques and properties10.1016/j.mser.2010.07.001 ↗
9. Inorganic-organic hybrid white light phosphors10.1039/C6CC03184F ↗
10. Nitride and oxynitride phosphors for white LEDs: synthesis, new phosphor discovery, crystal structure10.1016/j.progsolidstchem.2017.11.002 ↗
11. A novel tunable extra-broad yellow-emitting nitride phosphor with zero-thermal-quenching property10.1016/j.cej.2019.124004 ↗
12. Novel zirconium silicate phosphor K2ZrSi2O7:Eu2+ for white light-emitting diodes and field emission displays10.1039/C6TC01449F ↗
13. Enhanced luminescence characteristics of remote yellow silicate phosphors printed on nanoscale surface-roughened glass substrates for white light-emitting diodes10.1002/adom.201500734 ↗
14. A review on the advancements in phosphor-converted light emitting diodes (pc-LEDs): phosphor synthesis, device fabrication and characterization10.1016/j.pmatsci.2019.100622 ↗
15. One-dimensional organic lead halide perovskites with efficient bluish white-light emission10.1038/ncomms14051 ↗
16. Structural diversity in white-light-emitting hybrid lead bromide perovskites10.1021/jacs.8b08691 ↗
17. Mechanism for tunable broadband white photoluminescence of one-dimensional (C4N2H14)2Pb1-xMnxBr4 perovskite microcrystals10.1016/j.jlumin.2020.117045 ↗
18. Boosting self-trapped emissions in zero-dimensional perovskite heterostructures10.1021/acs.chemmater.0c00658 ↗
19. Multiple self-trapped emissions in the lead-free halide Cs3Cu2I510.1021/acs.jpclett.0c01166 ↗
20. Self-trapped excitons in all-inorganic halide perovskites: fundamentals, status, and potential applications10.1021/acs.jpclett.8b03604 ↗
21. Incorporating rare-earth terbium(III) ions into Cs2AgInCl6:Bi nanocrystals toward tunable photoluminescence10.1002/anie.202004562 ↗
22. Manganese-doped, lead-free double perovskite nanocrystals for bright orange-red emission10.1021/acscentsci.0c00056 ↗
23. Highly efficient blue emission from self-trapped excitons in stable Sb3+-doped Cs2NaInCl6 double perovskites10.1021/acs.jpclett.0c00330 ↗
24. Improving lead-free double perovskite Cs2NaBiCl6 nanocrystal optical properties via ion doping10.1002/adom.201901919 ↗
25. 0D Cs3Cu2X5 (X = I, Br, and Cl) nanocrystals: colloidal syntheses and optical properties10.1002/smll.201905226 ↗
26. Near-unity photoluminescence quantum yield in blue-emitting Cs3Cu2Br5-xIx (0 ≤ x ≤ 5)10.1021/acsaelm.9b00015 ↗
27. Photophysics in Cs3Cu2X5 (X = Cl, Br, or I): highly luminescent self-trapped excitons from local structure symmetrization10.1021/acs.chemmater.9b05321 ↗
28. Tuning optical properties of lead-free 2D tin-based perovskites with carbon chain spacers10.1021/acs.jpcc.9b10457 ↗
29. Luminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency10.1039/C7SC04539E ↗
30. Strong electron-phonon coupling and self-trapped excitons in the defect halide perovskites A3M2I9 (A = Cs, Rb; M = Bi, Sb)10.1021/acs.chemmater.7b01184 ↗
31. A highly red-emissive lead-free indium-based perovskite single crystal for sensitive water detection10.1002/anie.201814564 ↗
32. Efficient and stable emission of warm-white light from lead-free halide double perovskites10.1038/s41586-018-0691-0 ↗
33. Lead-free sodium-indium double perovskite nanocrystals through doping silver cations for bright yellow emission10.1002/anie.201909525 ↗
34. Design optimization of lead-free perovskite Cs2AgInCl6:Bi nanocrystals with 11.4% photoluminescence quantum yield10.1021/acs.chemmater.9b00410 ↗
35. White-light emission from layered halide perovskites10.1021/acs.accounts.7b00433 ↗
36. Efficient and reabsorption-free radioluminescence in Cs3Cu2I5 nanocrystals with self-trapped excitons10.1002/advs.202000195 ↗
37. Colloidal synthesis of ternary copper halide nanocrystals for high-efficiency deep-blue light-emitting diodes with a half-lifetime above 100 h10.1021/acs.nanolett.0c00513 ↗
38. Low-dimensional organometal halide perovskites10.1021/acsenergylett.7b00926 ↗
39. Lead-free perovskite variant solid solutions Cs2Sn1-xTexCl6: bright luminescence and high anti-water stability10.1002/adma.202002443 ↗
40. Luminescence and thermal behaviors of free and trapped excitons in cesium lead halide perovskite nanosheets10.1039/C8NR01109E ↗
41. Energy-dependent Huang-Rhys factor of free excitons10.1103/PhysRevB.68.125309 ↗
42. Effect of random field fluctuations on excitonic transitions of individual CdSe quantum dots10.1103/PhysRevB.61.9944 ↗
43. Revealing the nature of photoluminescence emission in the metal-halide double perovskite Cs2AgBiBr610.1039/C9TC02402F ↗
44. High-resolution remote thermometry and thermography using luminescent low-dimensional tin-halide perovskites10.1038/s41563-019-0416-2 ↗
45. Composite perovskites of cesium lead bromide for optimized photoluminescence10.1021/acs.jpclett.7b01302 ↗
46. Negative thermal quenching curves in photoluminescence of solids10.1143/JJAP.37.550 ↗