journal article·2023-01

VO2 (D) submicron-spherical hierarchical structures as novel anode materials for aqueous lithium-ion batteries

Yining Ma, Dandan Zhu, Huaijuan Zhou, Yue Tang, Chenchen Hu, Xinyu Meng, Xiaodong Jin, Tongxiang Xu, Xun Cao

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Abstract

Vanadium dioxide (VO 2) material has been deemed as a potential anode candidate for aqueous lithium-ion batteries. Among its diversified polymorphs, the latest discovered VO 2 (D) receives the fewest reports on its application in energy storage. Herein, we successfully utilized a template-free solvothermal method to prepare VO 2 (D) submicron-spherical hierarchical structures, constructed with colibacillus-like nanorods. The VO 2 (D) submicron-spheres were applied as an active anode material into the aqueous lithium-ion battery, which exhibited suitable working potential. Furthermore, VO 2 (D)-based full cell with LiMn 2O 4 as the cathode demonstrated high discharge capacity, good rate capability, and excellent cycling stability. The structural evolution, valence states of the VO 2 (D) electrode, and impedance variation of the full cell during cycling were investigated. The work reveals the potential of VO 2 (D) as a novel anode material for aqueous lithium-ion batteries.
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Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · Advanced battery technologies research · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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