Reduction of Native Singly Ionized Zinc Vacancies Content by 2.5 MeV Electron Irradiation of ZnGeP₂Single Crystals

An experimental study on how to reduce the content of singly ionized zinc vacancy (V⁻_Zn) in ZnGeP₂crystals to improve their optical quality is presented. Their electron paramagnetic resonance signal has been studied in samples treated in different ways. The data provide a scheme of the reductions that can be obtained by the different methods or by their combinations. The adding of Sn during the synthesis phase helps the production of large‐size single crystals and the reduction of the V⁻_Zncontent. Thermal treatment and electron irradiation are then needed for further reduction. At the fluence of 2 × 10¹⁷e cm⁻², the V⁻_Zndecrease does not reach a minimum value, so with higher fluences, additional reduction of V⁻_Zncontent is expected.