Potential for exciton condensation in a highly conductive amorphous polymer
Source abstract
Abstract
An outstanding challenge is to develop molecular materials that exhibit highly efficient energy transfer at ambient conditions. The authors of this study demonstrate the potential of an amorphous material to become an exciton condensate, in which energy can flow with minimal frictional loss. Unlike the Bechgaard salts that support superconductivity only at high pressures, the authors show that the amorphous polymer NiTTFtt, recently synthesized by Xie and Anderson, exhibits the computational signature of exciton condensation at atmospheric pressure and its synthetic geometry. This research supports the realistic possibility of harnessing chemical tunability to achieve ``strongly correlated'' phenomena at more ambient conditions, opening novel avenues for superefficient energy transfer in technologically relevant materials.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Organic and Molecular Conductors Research · Perovskite Materials and Applications · Strong Light-Matter Interactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and The James Franck Institute, The University of Chicago, Chicago, Illinois 60637, USA
Department of Chemistry, The University of Chicago, Chicago, Illinois 60637, USA
Funding
U.S. Department of Energy · Basic Energy Sciences · National Science Foundation
References (78)
Show source-provided references
1. 10.1016/j.physc.2015.02.03010.1016/j.physc.2015.02.030 ↗
2. 10.1051/jphyslet:019800041040950010.1051/jphyslet:0198000410409500 ↗
3. M. Lang · 2004
4. 10.1002/chin.20050728110.1002/chin.200507281 ↗
5. A. G. Lebed · 200810.1007/978-3-540-76672-8 ↗
6. 10.1246/bcsj.57.202510.1246/bcsj.57.2025 ↗
7. 10.1016/j.ccr.2015.05.01410.1016/j.ccr.2015.05.014 ↗
8. 10.1039/C9SC04381K10.1039/C9SC04381K ↗
9. 10.1039/b102865k10.1039/b102865k ↗
10. 10.1021/cr030656l10.1021/cr030656l ↗
11. 10.1038/s41586-022-05261-410.1038/s41586-022-05261-4 ↗
12. 10.1103/PhysRev.72.83810.1103/PhysRev.72.838 ↗
13. 10.1103/PhysRev.104.57610.1103/PhysRev.104.576 ↗
14. 10.1103/PhysRev.108.117510.1103/PhysRev.108.1175 ↗
15. 10.1143/PTP.23.44710.1143/PTP.23.447 ↗
16. 10.1088/1742-6596/449/1/01200110.1088/1742-6596/449/1/012001 ↗
17. 10.1038/s41586-019-1201-810.1038/s41586-019-1201-8 ↗
18. 10.1103/PhysRev.126.169110.1103/PhysRev.126.1691 ↗
19. 10.1103/PhysRevLett.93.03680110.1103/PhysRevLett.93.036801 ↗
20. 10.1103/PhysRevLett.93.03680210.1103/PhysRevLett.93.036802 ↗
21. 10.1063/1.505267410.1063/1.5052674 ↗
22. 10.1103/PhysRevB.98.04512210.1103/PhysRevB.98.045122 ↗
23. 10.1126/science.aam643210.1126/science.aam6432 ↗
24. 10.1038/nphys411610.1038/nphys4116 ↗
25. 10.1038/s41467-017-01660-810.1038/s41467-017-01660-8 ↗
26. 10.1103/Physics.9.8010.1103/Physics.9.80 ↗
27. 10.1103/PhysRevB.101.08110710.1103/PhysRevB.101.081107 ↗
28. 10.1103/PhysRevResearch.2.04320510.1103/PhysRevResearch.2.043205 ↗
29. 10.1021/acs.jpclett.1c0236810.1021/acs.jpclett.1c02368 ↗
30. 10.1063/5.008456410.1063/5.0084564 ↗
31. 10.1038/s41586-019-1591-710.1038/s41586-019-1591-7 ↗
32. 10.1103/PhysRevResearch.2.04204410.1103/PhysRevResearch.2.042044 ↗
33. 10.1038/s41586-021-03947-910.1038/s41586-021-03947-9 ↗
34. 10.1038/ncomms555510.1038/ncomms5555 ↗
35. 10.1103/PhysRevB.78.12140110.1103/PhysRevB.78.121401 ↗
36. 10.1103/PhysRevB.95.04541610.1103/PhysRevB.95.045416 ↗
37. 10.1103/PhysRevLett.73.30410.1103/PhysRevLett.73.304 ↗
38. 10.3367/UFNe.2017.10.03822710.3367/UFNe.2017.10.038227 ↗
39. 10.1038/nature0308110.1038/nature03081 ↗
40. 10.1038/nphys105510.1038/nphys1055 ↗
41. 10.1007/BF0132732610.1007/BF01327326 ↗
42. A. Einstein · Kgl. Preuss. Akad. Wiss. · 1924 · 261
43. 10.1103/PhysRev.54.94710.1103/PhysRev.54.947 ↗
44. 10.1103/PhysRev.58.71610.1103/PhysRev.58.716 ↗
45. 10.1103/RevModPhys.34.69410.1103/RevModPhys.34.694 ↗
46. 10.1103/PhysRev.138.B133810.1103/PhysRev.138.B1338 ↗
47. 10.1063/1.166477010.1063/1.1664770 ↗
48. 10.1103/RevModPhys.42.110.1103/RevModPhys.42.1 ↗
49. D. A. Mazziotti · 200710.1002/0470106603 ↗
50. 10.1021/cr200049310.1021/cr2000493 ↗
51. 10.1103/PhysRevA.94.03251610.1103/PhysRevA.94.032516 ↗
52. 10.1103/PhysRevLett.106.08300110.1103/PhysRevLett.106.083001 ↗
53. 2012
54. 10.1063/1.136019910.1063/1.1360199 ↗
55. 10.1103/PhysRevLett.93.21300110.1103/PhysRevLett.93.213001 ↗
56. 10.1063/1.163672110.1063/1.1636721 ↗
57. 10.1063/1.222235810.1063/1.2222358 ↗
58. 10.1063/1.298365210.1063/1.2983652 ↗
59. 10.1103/PhysRevLett.105.21300310.1103/PhysRevLett.105.213003 ↗
60. 10.1103/PhysRevLett.108.26300210.1103/PhysRevLett.108.263002 ↗
61. 10.1103/PhysRevLett.108.21300110.1103/PhysRevLett.108.213001 ↗
62. 10.1021/acs.jpclett.5b0254710.1021/acs.jpclett.5b02547 ↗
63. 10.1103/PhysRevLett.119.06300210.1103/PhysRevLett.119.063002 ↗
64. 10.1021/acs.jpclett.0c0124810.1021/acs.jpclett.0c01248 ↗
65. 10.1063/5.005027710.1063/5.0050277 ↗
66. 10.1039/C6CP07563K10.1039/C6CP07563K ↗
67. 10.1021/jacs.0c0830710.1021/jacs.0c08307 ↗
68. 10.1039/C9CP03361K10.1039/C9CP03361K ↗
69. 10.1103/RevModPhys.35.66810.1103/RevModPhys.35.668 ↗
70. 10.1016/S0038-1098(03)00312-010.1016/S0038-1098(03)00312-0 ↗
71. 10.1038/nature0513110.1038/nature05131 ↗
72. 10.1021/cr030664210.1021/cr0306642 ↗
73. 10.1073/pnas.68.12.312010.1073/pnas.68.12.3120 ↗
74. 10.1039/cs991200035510.1039/cs9912000355 ↗
75. 10.1021/ja901001810.1021/ja9010018 ↗
76. 10.1021/ja503690m10.1021/ja503690m ↗
77. 10.1039/C9CC00218A10.1039/C9CC00218A ↗
78. 10.1103/PhysRevB.88.02410510.1103/PhysRevB.88.024105 ↗