journal article·2019-02

Enhanced formic acid electrooxidation reaction enabled by 3D PtCo nanodendrites electrocatalyst

Chunyang Zhai, Hongmin Zhang, Jiayue Hu, Lixi Zeng, Mianqiang Xue, Yukou Du, Mingshan Zhu

Publisher page

Abstract

Abstract The lack of high-performance anodic electrocatalysts for the electrooxidation of liquid fuel remains a prohibited challenge in realizing the large-scale application fuel cells technique. To this end, we herein demonstrated a simple wet-chemical approach for preparing the composition-tunable PtCo nanocatalysts with the three-dimensional (3D) dendrites structure and active surface composition. These unique properties have enabled them to exhibit superior electrocatalytic activity towards formic acid electrooxidation with the mass/specific activities of 1216.9 mA mg−1Pt and 3.36 mA cm−2, 4.3 and 8.2 times higher than that of the commercial Pt/C catalyst. Moreover, the Pt4Co1 nanodendrites can endure the durability test for at least 500 cycles with less decay, showing an advanced class of electrocatalysts for fuel cells. This work paves up a new avenue to promote the electrocatalytic performances of catalyst by designing their morphologies and pushes Pt-based nanocatalysts system much stronger for commercial application in fuel cells and beyond.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. One-dimensional noble metal electrocatalysts: a promising structural paradigm for direct methanol fuel cells10.1039/C0EE00197J ↗
2. Bimetallic PdPt nanowire networks with enhanced electrocatalytic activity for ethylene glycol and glycerol oxidation10.1039/C5EE01988E ↗
3. Trimetallic PtAgCu@PtCu core@shell concave nanooctahedrons with enhanced activity for formic acid oxidation reaction10.1016/j.nanoen.2015.01.041 ↗
4. Size-controlled synthesis of platinum-copper hierarchical trigonal bipyramid nanoframes10.1002/anie.201408399 ↗
5. Formic acid-reduced ultrasmall Pd nanocrystals on graphene to provide superior electocatalytic activity and stability toward formic acid oxidation10.1016/j.nanoen.2014.10.008 ↗
6. Bimetallic Cu–Pd alloy multipods and their highly electrocatalytic performance for formic acid oxidation and oxygen reduction10.1039/C6TA10476B ↗
7. Porous AgPt@Pt nanooctahedra as an efficient catalyst toward formic acid oxidation with predominant dehydrogenation pathway10.1021/acsami.6b11895 ↗
8. The simple synthesis of single crystalline palladium arrow-headed tripods and their application in formic acid electro-oxidation10.1039/C5CC00353A ↗
9. Au@Pt Core–Shell mesoporous nanoballs and nanoparticles as efficient electrocatalysts toward formic acid and glucose oxidation10.1021/acs.jpcc.5b09417 ↗
10. Nanoporous AuPt alloy with low Pt content: a remarkable electrocatalyst with enhanced activity towards formic acid electro-oxidation10.1016/j.electacta.2016.01.001 ↗
11. Simple synthesis of PtAu alloy nanoparticles with high activity for formic acid oxidation10.1016/j.jpowsour.2009.08.054 ↗
12. Atomic structure of Pt3Ni nanoframe electrocatalysts by in situ X-ray absorption spectroscopy10.1021/jacs.5b09639 ↗
13. PtAg nanowires: simple synthesis and their applications as excellent oxygen reduction electrocatalysts for label-free electrochemical immunoassay10.1039/c3ta13071a ↗
14. Pt–CoP/C as an alternative PtRu/C catalyst for direct methanol fuel cells10.1039/C6TA07896F ↗
15. Excavated cubic platinum-tin alloy nanocrystals constructed from ultrathin nanosheets with enhanced electrocatalytic activity10.1002/anie.201602592 ↗
16. Ternary Pd2/PtFe networks supported by 3D graphene for efficient and durable electrooxidation of formic acid10.1039/c2cc37413g ↗
17. FePt and CoPt nanowires as efficient catalysts for the oxygen reduction reaction10.1002/anie.201209871 ↗
18. Synthesis of bimetallic Au@Pt nanoparticles with Au core and nanostructured Pt shell toward highly active electrocatalysts10.1021/cm102074w ↗
19. Trimetallic PtCuCo hollow nanospheres with a dendritic shell for enhanced electrocatalytic activity toward ethylene glycol electrooxidation10.1039/C5NR01679G ↗
20. In situ development of highly concave and composition-confined PtNi octahedra with high oxygen reduction reaction activity and durability10.1007/s12274-015-0927-3 ↗
21. Ultrasonic-assisted synthesis of carbon nanotube supported bimetallic Pt–Ru nanoparticles for effective methanol oxidation10.1039/C5TA00695C ↗
22. Bioethanol as a new sustainable fuel for anion exchange membrane fuel cells with carbon nanotube supported surface dealloyed PtCo nanocomposite anodes10.1016/j.cej.2017.02.111 ↗
23. High-Quality and deeply excavated Pt3Co nanocubes as efficient catalysts for liquid fuel electrooxidation10.1021/acs.chemmater.7b03406 ↗
24. One-Pot synthesis of concave platinum-cobalt nanocrystals and their superior catalytic performances for methanol electrochemical oxidation and oxygen electrochemical reduction10.1021/acsami.7b10209 ↗
25. Self-supported porous 2D AuCu triangular nanoprisms as model electrocatalysts for ethylene glycol and glycerol oxidation10.1039/C7TA04598K ↗
26. Hollow AuxAg/Au core/shell nanospheres as efficient catalysts for electrooxidation of liquid fuels10.1039/C7NR04409G ↗
27. Porous dandelion-like gold@ palladium core-shell nanocrystals in-situ growth on reduced graphene oxide with improved electrocatalytic properties10.1016/j.electacta.2016.03.098 ↗
28. Dendrite-like PtAg alloyed nanocrystals: highly active and durable advanced electrocatalysts for oxygen reduction and ethylene glycol oxidation reactions10.1016/j.jcis.2017.05.089 ↗
29. The facile synthesis of single crystalline palladium arrow-headed tripods and their application in formic acid electro-oxidation10.1039/C5CC00353A ↗
30. Enhanced electro-photo synergistic catalysis of Pt (Pd)/ZnO/graphene composite for methanol oxidation under visible light irradiation10.1016/j.electacta.2015.11.149 ↗
31. Nanoporous AuPt alloy with low Pt content: a remarkable electrocatalyst with enhanced activity towards formic acid electro-oxidation10.1016/j.electacta.2016.01.001 ↗
32. Au@Pt core–shell mesoporous nanoballs and nanoparticles as efficient electrocatalysts toward formic acid and glucose oxidation10.1021/acs.jpcc.5b09417 ↗
33. Novel flower-like PdAu(Cu) anchoring on a 3D rGO-CNT sandwich-stacked framework for highly efficient methanol and ethanol electro-oxidation10.1016/j.electacta.2017.01.046 ↗
34. Low Pt-content ternary PdCuPt nanodendrites: an efficient electrocatalyst for oxygen reduction reaction10.1039/C6NR06646A ↗
35. A dendritic core-shell Cu@PtCu alloy electrocatalyst resulting in an enhanced electron transfer ability and boosted surface active sites for an improved methanol oxidation reaction10.1039/C7CC01559C ↗
36. Synthesis of dendritic Pt-Ni-P alloy nanoparticles with enhanced electrocatalytic properties10.1039/C5CC04277A ↗
37. Ternary Pd-Ni-P hybrid electrocatalysts derived from Pd-Ni core-shell nanoparticles with enhanced formic acid oxidation activity10.1039/C6CC04382H ↗
38. Excavated octahedral Pt-Co alloy nanocrystals built with ultrathin nanosheets as superior multifunctional electrocatalysts for energy conversion applications10.1016/j.nanoen.2017.07.041 ↗
39. Synthesis, characterization and electrocatalytic activity of Co@Pt nanoparticles supported on carbon-ceramic substrate for fuel cell applications10.1016/j.ijhydene.2015.02.103 ↗
40. Surface engineering of hierarchical platinum-cobalt nanowires for efficient electrocatalysis10.1038/ncomms11850 ↗
41. A facile and general strategy for the synthesis of porous flowerlike Pt-based nanocrystals as effective electrocatalysts for alcohol oxidation10.1039/C6NR04927C ↗
42. Preparation and catalytic activity of PVP-protected Au/Ni bimetallic nanoparticles for hydrogen generation from hydrolysis of basic NaBH4 solution10.1016/j.ijhydene.2013.10.122 ↗
43. Ultrafast synthesis of flower-like ordered Pd3Pb nanocrystals with superior electrocatalytic activities towards oxidation of formic acid and ethanol10.1016/j.jpowsour.2015.09.114 ↗
44. Facile Cu3P-C hybrid supported strategy to improve Pt nanoparticle electrocatalytic performance toward methanol, ethanol, glycol and formic acid electro-oxidation10.1016/j.electacta.2016.10.105 ↗
45. Formic acid electro-oxidation at PtAu alloyed nanoparticles synthesized by pulsed laser ablation in liquids10.1016/j.jpowsour.2013.09.045 ↗
46. A simple synthesis of urchin-like Pt-Ni bimetallic nanostructures as enhanced electrocatalysts for the oxygen reduction reaction10.1039/C5CC08088F ↗
47. Facile synthesis of 3D Pd-P nanoparticle networks with enhanced electrocatalytic performance towards formic acid electrooxidation10.1039/C4CC03282A ↗
48. Composition-tunable Pt–Co alloy nanoparticle networks: simple room-temperature synthesis and supportless electrocatalytic applications10.1002/cphc.201100989 ↗
49. Electrochemical activated PtAuCu alloy nanoparticle catalysts for formic acid, methanol and ethanol electro-oxidation10.1016/j.electacta.2015.07.157 ↗
50. Synthesis of hollow and nanoporous gold/platinum alloy nanoparticles and their electrocatalytic activity for formic acid oxidation10.1016/j.jcis.2012.08.011 ↗
51. High efficiency photoelectrocatalytic methanol oxidation on CdS quantum dots sensitized Pt electrode10.1021/acsami.5b10234 ↗