Layer-dependent Raman spectroscopy of ultrathin Ta2Pd3Te5

Two-dimensional topological insulators (2DTIs) or quantum spin Hall insulators are attracting increasing attention due to their potential applications in next-generation spintronic devices. Despite their promising prospects, realizable 2DTIs are still limited. Recently, ${\mathrm{Ta}}₂{\mathrm{Pd}}₃{\mathrm{Te}}₅$, a semiconducting van der Waals material, has shown spectroscopic evidence of quantum spin Hall states. However, achieving controlled preparation of few to monolayer samples, a crucial step in realizing quantum spin Hall devices, has not yet been achieved. In this work, we fabricated few to monolayer ${\mathrm{Ta}}₂{\mathrm{Pd}}₃{\mathrm{Te}}₅$ and performed systematic thickness- and temperature-dependent Raman spectroscopy measurements. Our results demonstrate that Raman spectra can provide valuable information to determine the thickness of ${\mathrm{Ta}}₂{\mathrm{Pd}}₃{\mathrm{Te}}₅$ thin flakes. Moreover, our angle-resolved polarized Raman (ARPR) spectroscopy measurements show that the intensities of the Raman peaks are strongly anisotropic due to the quasi-one-dimensional atomic structure, providing a straightforward method to determine its crystalline orientation. Our findings may stimulate further efforts to realize quantum devices based on few or monolayer ${\mathrm{Ta}}₂{\mathrm{Pd}}₃{\mathrm{Te}}₅$.