Kinetic fragility directly correlates with the many-body static amorphous order in glass-forming liquids
Source abstract
Abstract
The term ``fragility'' describes the rate at which viscosity grows when a supercooled liquid approaches its putative glass transition temperature. The field of glassy materials is actively searching for a structural origin that governs this dynamical slowing down in the supercooled liquid, which occurs without any discernible change in structure. Our work shows clear evidence that growing many-body static amorphous order is intimately correlated with the kinetic fragility of glass-forming liquids. It confirms that the system's dynamical response to temperature is concealed in its microstructures. This finding may pave the way for a deeper understanding of the different temperature dependence of the relaxation time or viscosity in a wide variety of glass-forming liquids.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Material Dynamics and Properties · Glass properties and applications · Liquid Crystal Research Advancements
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Physics and Astronomy, University of Pennsylvania, 209 South 33rd Street, Philadelphia, Pennsylvania 19104, USA
Tata Institute of Fundamental Research, 36/P Gopanpally Village, Serilingampally Mandal, Ranga Reddy District, Hyderabad 500107, India
Funding
National Science Foundation · Tata Institute of Fundamental Research · Department of Atomic Energy, Government of India · Swarna Jayanti Fellowship
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