journal article·2022-01

Synthesis, Corrosion, and Bioactivity Evaluation of the Hybrid Anodized Polycaprolactone Fumarate/Silicon- and Magnesium-Codoped Fluorapatite Nanocomposite Coating on AZ31 Magnesium Alloy

K. Mohemi, T. Ahmadi, A. Jafarzadeh, H. R. Bakhsheshi-Rad, M. Taghian Dehaghani, F. Berto

Physical Mesomechanics· Volume 25· Issue 1
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Abstract

In the present study, a dual composite coating consisting of an anodized layer as the inner layer and PCLF (polycaprolactone fumarate)/silicon- and magnesium-codoped fluorapatite (Si-Mg-FA) nanocomposite as the outer layer was fabricated on AZ31 Mg alloy. The thickness of the PCLF/(Si-Mg-FA) nanocomposite coating is 9.72 μm, with the Si-Mg-FA nanoparticles being well distributed in the PCLF matrix. Electrochemical measurements showed that AZ31 Mg alloy with the anodized PCLF/Si-Mg-FA coating has a low corrosion current density (5.137 × 10–6 A/cm2), providing a sufficient protection (Rp = 5888.72 Ω cm2) for Mg alloys. Immersion tests in a simulated body fluid showed that cauliflower-like/cloudy apatite forms on AZ31 Mg alloy with the anodized PCLF/Si-Mg-FA coating and governs good bioactivity. Osteosarcoma cells adhere well to the surface of the coating. Surface modification by the anodized PCLF/Si-Mg-FA coating can be a suitable method for controlling the corrosion degradation and increasing the bioactivity and cell attachment of AZ31 Mg alloy for implant applications.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Corrosion Behavior and Inhibition

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