journal article·2022-10

The Nature and Features of the Fracture Surface in the Hydrogen-Embrittled Low Alloy Steel with Ultrafine-Grained Microstructure

E. D. Merson, V. A. Poluyanov, P. N. Myagkikh, D. L. Merson, A. Yu. Vinogradov

Physical Mesomechanics· Volume 25· Issue 5
Publisher page

Abstract

It has been shown recently that hydrogen embrittlement in severely deformed low alloy steel results in the formation of specific tearing morphology on the fracture surface. The origin of such a fracture surface has not yet been fully understood. This paper reports the results of fractographic examination combined with electron backscatter diffraction study of the microstructure underlying the fracture surface in ultrafine-grained low alloy steel 09G2S produced by equal channel angular pressing. Tensile tests are carried out on hydrogen-free and cathodically hydrogen-charged specimens. It is found that all hydrogen-charged specimens exhibit tearing fracture morphology and numerous secondary cracks. The metallographic images obtained by scanning electron microscopy and electron backscatter diffraction clearly show that both hydrogen-induced cracking and hydrogen-assisted cracking in the ultrafine-grained steel occur primarily along hydrogen-embrittled high- and low-angle ultrafine grain boundaries and dislocation cell walls, resulting in the formation of tearing morphology on the fracture surface. The mechanism governing the formation of specific morphological elements on the fracture surface is proposed and discussed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Microstructure and Mechanical Properties of Steels · Material Properties and Failure Mechanisms

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Louthan, M.R., Hydrogen Embrittlement of Metals: A Primer for the Failure Analyst, J. Fail. Anal. Prev., 2008, vol. 8, pp. 289–307. https://doi.org/10.1007/s11668-008-9133-x10.1007/s11668-008-9133-x ↗
2. Claeys, L., De Graeve, I., Depover, T., and Verbeken, K., Hydrogen-Assisted Cracking in 2205 Duplex Stainless Steel: Initiation, Propagation and Interaction with Deformation-Induced Martensite, Mater. Sci. Eng. A, 2020, vol. 797. https://doi.org/10.1016/j.msea.2020.14007910.1016/j.msea.2020.140079 ↗
3. Kyriakopoulou, H.P., Karmiris-Obratański, P., Tazedakis, A.S., Daniolos, N.M., Dourdounis, E.C., Manolakos, D.E., and Pantelis, D., Investigation of Hydrogen Embrittlement Susceptibility and Fracture Toughness Drop after In Situ Hydrogen Cathodic Charging for an X65 Pipeline Steel, Micromachines, 2020, vol. 11, pp. 1–21. https://doi.org/10.3390/MI1104043010.3390/MI11040430 ↗
4. Dwivedi, S.K. and Vishwakarma, M., Effect of Hydrogen in Advanced High Strength Steel Materials, Int. J. Hydrogen Energy, 2019, vol. 44, pp. 28007–28030. https://doi.org/10.1016/j.ijhydene.2019.08.14910.1016/j.ijhydene.2019.08.149 ↗
5. Arora, A., Singh, H., and Mahajan, D.K., Towards the Prediction of Intergranular Fatigue Crack Initiation in Metals due to Hydrogen, Mater. Sci. Eng. A, 2020, vol. 787. https://doi.org/10.1016/j.msea.2020.13948810.1016/j.msea.2020.139488 ↗
6. Wang, S., Martin, M.L., Sofronis, P., Ohnuki, S., Hashimoto, N., and Robertson, I.M., Hydrogen-Induced Intergranular Failure of Iron, Acta Mater., 2014, vol. 69, pp. 275–282. https://doi.org/10.1016/j.actamat.2014.01.06010.1016/j.actamat.2014.01.060 ↗
7. McMahon, C.J., Hydrogen-Induced Intergranular Fracture of Steels, Eng. Fract. Mech., 2001, vol. 68, pp. 773–788. https://doi.org/10.1016/S0013-7944(00)00124-710.1016/S0013-7944(00)00124-7 ↗
8. Gong, P., Nutter, J., Rivera-Diaz-Del-Castillo, P.E.J., and Rainforth, W.M., Hydrogen Embrittlement through the Formation of Low-Energy Dislocation Nanostructures in Nanoprecipitation-Strengthened Steels, Sci. Adv., 2020, vol. 6. https://doi.org/10.1126/sciadv.abb615210.1126/sciadv.abb6152 ↗
9. Nakasato, F. and Bernstein, I., Crystallographic and Fractographic Studies of Hydrogen-Induced Cracking in Purified Iron and Iron–Silicon Alloys, Metall. Mater. Trans. A, 1978, vol. 9, pp. 1317–1326. https://doi.org/10.1007/bf0265225610.1007/bf02652256 ↗
10. Tetelman, A. and Robertson, W., Direct Observation and Analysis of Crack Propagation in Iron–3% Silicon Single Crystals, Acta Metall., 1963, vol. 11, pp. 415–426. https://doi.org/10.1016/0001-6160(63)90166-410.1016/0001-6160(63)90166-4 ↗
11. Botvina, L., Tetyueva, T., and Ioffe, A., Stages of Multiple Fracture of Low-Alloy Steels in a Hydrogen Sulfide Medium, Met. Sci. Heat Treat., 1998, vol. 40, pp. 61–70. https://doi.org/10.1007/bf0246826010.1007/bf02468260 ↗
12. Martin, M.L., Fenske, J.A., Liu, G.S., Sofronis, P., and Robertson, I.M., On the Formation and Nature of Quasi-Cleavage Fracture Surfaces in Hydrogen-Embrittled Steels, Acta Mater., 2011, vol. 59, pp. 1601–1606. https://doi.org/10.1016/j.actamat.2010.11.02410.1016/j.actamat.2010.11.024 ↗
13. Merson, E., Myagkikh, P., Poluyanov, V., Dorogov, M., Merson, D., and Vinogradov, A., The Fundamental Difference between Cleavage and Hydrogen-Assisted Quasi-Cleavage in Ferritic Materials Revealed by Multiscale Quantitative Fractographic and Side Surface Characterization, Mater. Sci. Eng. A, 2021, vol. 824, p. 141826. https://doi.org/10.1016/j.msea.2021.14182610.1016/j.msea.2021.141826 ↗
14. Merson, E., Poluyanov, V., Myagkikh, P., Merson, D., and Vinogradov, A., Quantitative Comparison of Cleavage and Quasi-Cleavage Fracture Surfaces in Hydrogen-Embrittled Low-Carbon Steel, Lett. Mater., 2020, vol. 10, pp. 303–308. https://doi.org/10.22226/2410-3535-2020-3-303-30810.22226/2410-3535-2020-3-303-308 ↗
15. Merson, E.D., Myagkikh, P.N., Poluyanov, V.A., Merson, D.L., and Vinogradov, A., Quasi-Cleavage Hydrogen-Assisted Cracking Path Investigation by Fractographic and Side Surface Observations, Eng. Fract. Mech., 2019, vol. 214, pp. 177–193. https://doi.org/10.1016/j.engfracmech.2019.04.04210.1016/j.engfracmech.2019.04.042 ↗
16. Merson, E.D., Myagkikh, P.N., Klevtsov, G.V., Merson, D.L., and Vinogradov, A., Effect of Fracture Mode on Acoustic Emission Behavior in the Hydrogen-Embrittled Low-Alloy Steel, Eng. Fract. Mech., 2019, vol. 210, pp. 342–357. https://doi.org/10.1016/j.engfracmech.2018.05.02610.1016/j.engfracmech.2018.05.026 ↗
17. Merson, E.D., Myagkikh, P.N., Klevtsov, G.V., Merson, D.L., and Vinogradov, A., Effect of Hydrogen Concentration and Strain Rate on Hydrogen Embrittlement of Ultrafine-Grained Low-Carbon Steel, Springer Int. Publ., 2021. https://doi.org/10.1007/978-3-030-66948-5_1010.1007/978-3-030-66948-5_10 ↗
18. Merson, E., Vinogradov, A., and Merson, D.L., Application of Acoustic Emission Method for Investigation of Hydrogen Embrittlement Mechanism in the Low-Carbon Steel, J. Alloys Compnd, 2015, vol. 645, pp. S460–S463. https://doi.org/10.1016/j.jallcom.2014.12.08310.1016/j.jallcom.2014.12.083 ↗
19. Merson, E., Kudrya, A.V., Trachenko, V.A., Merson, D., Danilov, V., and Vinogradov, A., Quantitative Characterization of Cleavage and Hydrogen-Assisted Quasi-Cleavage Fracture Surfaces with the Use of Confocal Laser Scanning Microscopy, Mater. Sci. Eng. A, 2016, vol. 665, pp. 35–46. https://doi.org/10.1016/j.msea.2016.04.02310.1016/j.msea.2016.04.023 ↗
20. Okada, K., Shibata, A., Takeda, Y., and Tsuji, N., Crystallographic Feature of Hydrogen-Related Fracture in 2Mn-0.1C Ferritic Steel, Int. J. Hydrogen Energy, 2018, vol. 43, pp. 11298–11306. https://doi.org/10.1016/j.ijhydene.2018.05.01110.1016/j.ijhydene.2018.05.011 ↗
21. Mine, Y., Matsumoto, S., and Horita, Z., Strengthening and Hydrogen Embrittlement of Ultrafine-Grained Fe–0.01 mass % C Alloy Processed by High-Pressure Torsion, Corrosion Sci., 2011, vol. 53, pp. 2969–2977. https://doi.org/10.1016/j.corsci.2011.05.05210.1016/j.corsci.2011.05.052 ↗
22. Merson, E., Myagkikh, P., Klevtsov, G., Merson, D., and Vinogradov, A., Effect of Equal-Channel Angular Pressing (ECAP) and Current Density of Cathodic Hydrogen Charging on Hydrogen Trapping in the Low-Alloy Steel, Lett. Mater., 2020, vol. 10, pp. 152–157. https://doi.org/10.22226/2410-3535-2020-2-152-15710.22226/2410-3535-2020-2-152-157 ↗
23. Hadam, U. and Zakroczymski, T., Absorption of Hydrogen in Tensile Strained Iron and High-Carbon Steel Studied by Electrochemical Permeation and Desorption Techniques, Int. J. Hydrogen Energy, 2009, vol. 34, pp. 2449–2459. https://doi.org/10.1016/j.ijhydene.2008.12.08810.1016/j.ijhydene.2008.12.088 ↗
24. Nagumo, M., Takai, K., and Okuda, N., Nature of Hydrogen Trapping Sites in Steels Induced by Plastic Deformation, J. Alloys Compnd, 1999, vol. 293, pp. 310–316. https://doi.org/10.1016/S0925-8388(99)00322-910.1016/S0925-8388(99)00322-9 ↗
25. Lee, J.Y. and Lee, J.L., A Trapping Theory of Hydrogen in Pure Iron, Philos. Mag. A, 1987, vol. 56, pp. 293–309. https://doi.org/10.1080/0141861870821438710.1080/01418618708214387 ↗
26. Pressouyre, G.M., A Classification of Hydrogen Traps in Steel, Metall. Trans. A, 1979, vol. 10, pp. 1571–1573. https://doi.org/10.1007/BF0281202310.1007/BF02812023 ↗
27. Mine, Y., Tsumagari, T., and Horita, Z., Hydrogen Trapping on Lattice Defects Produced by High-Pressure Torsion in Fe–0.01 mass % C Alloy, Scripta Mater., 2010, vol. 63, pp. 552–555. https://doi.org/10.1016/j.scriptamat.2010.05.02710.1016/j.scriptamat.2010.05.027 ↗
28. Mine, Y., Tachibana, K., and Horita, Z., Effect of Hydrogen on Tensile Properties of Ultrafine-Grained Type 310S Austenitic Stainless Steel Processed by High-Pressure Torsion, Metall. Mater. Trans. A, 2011, vol. 42, pp. 1619–1629. https://doi.org/10.1007/s11661-010-0558-y10.1007/s11661-010-0558-y ↗
29. Kimura, Y., Sakai, Y., Hara, T., Belyakov, A., and Tsuzaki, K., Hydrogen Induced Delayed Fracture of Ultrafine Grained 0.6% O Steel with Dispersed Oxide Particles, Scripta Mater., 2003, vol. 49, pp. 1111–1116. https://doi.org/10.1016/j.scriptamat.2003.08.00610.1016/j.scriptamat.2003.08.006 ↗
30. Choo, W.Y. and Lee, J., Hydrogen Trapping Phenomena in Carbon Steel, J. Mater. Sci., 1982, vol. 17, pp. 1930–1938. https://doi.org/10.1007/BF0054040910.1007/BF00540409 ↗
31. Lynch, S.P., Hydrogen Embrittlement Phenomena and Mechanisms, Corros. Rev., 2012, vol. 30, pp. 63–133. https://doi.org/10.1515/corrrev-2012-050210.1515/corrrev-2012-0502 ↗
32. Robertson, I.M., Sofronis, P., Nagao, A., Martin, M.L., Wang, S., Gross, D.W., et al., Hydrogen Embrittlement Understood, Metall. Mater. Trans. A, 2015, vol. 46, pp. 2323–2341. https://doi.org/10.1007/s11661-015-2836-110.1007/s11661-015-2836-1 ↗
33. Wert, C.A. and Frank, R.C., Trapping of Interstitials in Metals, Annu. Rev. Mater. Sci., 1983, vol. 13, pp. 139–172. https://doi.org/10.1146/annurev.ms.13.080183.00103510.1146/annurev.ms.13.080183.001035 ↗
34. Krom, A. and Bakker, A., Hydrogen Trapping Models in Steel, Metall. Mater. Trans. B, 2000, vol. 31, pp. 1475–1482. https://doi.org/10.1007/s11663-000-0032-010.1007/s11663-000-0032-0 ↗