journal article·2026-02

Formation of Zigzag Deformation Twins in Aluminum Nanowires

M. Yu. Gutkin, N. V. Skiba

Physical Mesomechanics· Volume 29· Issue 1
Publisher page

Abstract

Abstract A theoretical model is proposed that describes the formation micromechanism of a zigzag-shaped deformation twinning structure in aluminum nanowires covered with an amorphous aluminum oxide layer. Within the framework of a two-dimensional model, this structure is formed by successive nucleation of twins in the aluminum nanolayer between the interfaces with the amorphous oxide films. In this case, the primary twin is formed at a stress concentrator near one of these interfaces, secondary twins nucleate in the stress concentration sites at the ends of the primary twin, and then this process repeats cyclically, i.e., new twins nucleate at the ends of the previous ones. Contour plots of von Mises shear stresses and elastic energy density of the primary twin are generated. Using these plots, the nucleation sites and growth directions of secondary twins are determined. According to the results of the model, the successive nucleation of deformation twins should lead to the formation of a zigzag twinning structure. It is concluded that the main reason for the formation of such a structure in aluminum nanowire is the presence of an oxide amorphous layer on its surface, which prevents the escape of the twins to the free surface of the nanowire, and as a result new stress concentration sites emerge in their locking points.
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Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Microstructure and mechanical properties · Nanowire Synthesis and Applications

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References (40)

Show source-provided references
1. Polukhin, P.I., Gorelik, S.S., and Vorontsov, V.K., Physical Foundations of Plastic Deformation. Textbook for Universities, Moscow: Metallurgy, 1982.
2. Mahajan, S. and Chin, G.Y., Formation of deformation twins in f.c.c. crystals, Acta Metallurgica, 1973, vol. 21, pp. 1353–1363. https://doi.org/10.1016/0001-6160(73)90085-010.1016/0001-6160(73)90085-0 ↗
3. Christian, J.W. and Mahajan, S., Deformation twinning. Progress in Materials Science, 1995, vol. 39, pp. 1–157. https://doi.org/10.1016/0079-6425(94)00007-710.1016/0079-6425(94)00007-7 ↗
4. Meyers, M.A., Vöhringer, O., and Lubarda, V.A., The onset of twinning in metals: a constitutive description, Acta Mater., 2001, vol. 49, pp. 4025–4039. https://doi.org/10.1016/S1359-6454(01)00300-710.1016/S1359-6454(01)00300-7 ↗
5. Zhu, Y.T., Liao, X.Z., and Wu, X.L., Deformation twinning in nanocrystalline materials, Progress in Materials Science, 2012, vol. 57, pp. 1–62. https://doi.org/10.1016/j.pmatsci.2011.05.00110.1016/j.pmatsci.2011.05.001 ↗
6. Ma, X., Zhu, Y., and Ramadan, M., Deformation twinning in nanocrystalline metals, Encyclopedia of Smart Materials, 2022, vol. 3, pp. 412–431. https://doi.org/10.1016/B978-0-12-815732-9.00144-310.1016/B978-0-12-815732-9.00144-3 ↗
7. Weinberger, C.R. and Cai, W., Plasticity of metal nanowires, Journal of Materials Chemistry, 2012, vol. 22, pp. 3277-3292. https://doi.org/10.1039/C2JM13682A10.1039/C2JM13682A ↗
8. Yue, Y., Gong, Q., and Zhang, Q., In situ atomistic deformation mechanisms study of nanowires, Journal of Nanomaterials, 2016, vol. 2016, art. no. 8497242. https://doi.org/10.1155/2016/849724210.1155/2016/8497242 ↗
9. Mordehai, D., David, O., and Kositski, R., Nucleation-controlled plasticity of metallic nanowires and nanoparticles, Advanced Materials, 2018, vol. 30, art. no. 1706710. https://doi.org/10.1002/adma.20170671010.1002/adma.201706710 ↗
10. Yin, S., Cheng, G., Richter, G., Gao, H., and Zhu, Y., Transition of deformation mechanisms in single-crystalline metallic nanowire, ACS Nano, 2019, vol. 13, pp. 9082-9090. https://doi.org/10.1021/acsnano.9b0331110.1021/acsnano.9b03311 ↗
11. Seo, J.-H., Yoo, Y., Park, N.-Y., Yoon, S.-W., Lee, H., Han, S., Lee, S.-W., Seong, T.-Y., Lee, S.-C., and Lee, K.-B., Superplastic deformation of defect-free Au nanowires via coherent twin propagation, Nano Lett., 2011, vol. 11, pp. 3499-3502. https://doi.org/10.1021/nl202230610.1021/nl2022306 ↗
12. Sedlmayr, A., Bitzek, E., Gianola, D.S., Richter, G., Mönig, R., and Kraft, O., Existence of two twinning-mediated plastic deformation modes in Au nanowhiskers, Acta Mater., 2012, vol. 60, pp. 3985-3993. https://doi.org/10.1016/j.actamat.2012.03.01810.1016/j.actamat.2012.03.018 ↗
13. Roos, B., Kapelle, B., Richter, G., and Volkert, C.A., Surface dislocation nucleation controlled deformation of Au nanowires, Appl. Phys. Lett., 2014, vol. 105, art. no. 201908. https://doi.org/10.1063/1.490231310.1063/1.4902313 ↗
14. Leach, A.M., McDowell, M., and Gall, K., Deformation of top-down and bottom-up silver nanowires, Adv. Funct. Mater., 2007, vol. 17, pp. 43-53. https://doi.org/10.1002/adfm.20060073510.1002/adfm.200600735 ↗
15. Liang, W., Zhou, M., and Ke, F., Shape memory effect in Cu nanowires, Nano Lett., 2005, vol. 5, pp. 2039-2043. https://doi.org/10.1021/nl051591010.1021/nl0515910 ↗
16. Oh, S.H., Legros, M., Kiener, D., and Dehm, G., In situ observation of dislocation nucleation and escape in a submicrometre aluminium single crystal, Nature Materials, 2009, vol. 8, pp. 95-100. https://doi.org/10.1038/nmat237010.1038/nmat2370 ↗
17. Han, X., Wang, L., Liu, P., Yue, Y., Yang, M., Sun, J., and Zhang, Z., Dynamic atomic mechanisms of plasticity of Ni nanowires and nano crystalline ultra-thin films, Materials Science Forum, 2010, vol. 654-656, pp. 2293-2296. https://doi.org/10.4028/www.scientific.net/MSF.654-656.229310.4028/www.scientific.net/MSF.654-656.2293 ↗
18. Mompiou, F., Legros, M., Sedlmayr, A., Gianola, D.S., Caillard, D., and Kraft, O., Source-based strengthening of sub-micrometer Al fibers, Acta Mater., 2012, vol. 60, pp. 977-983. https://doi.org/10.1016/j.actamat.2011.11.00510.1016/j.actamat.2011.11.005 ↗
19. Wang, L., Teng, J., Sha, X., Zou, J., Zhang, Z., and Han, X., Plastic deformation through dislocation saturation in ultrasmall Pt nanocrystals and its in situ atomistic mechanisms, Nano Letters, 2017, vol. 17, pp. 4733-4739. https://doi.org/10.1021/acs.nanolett.7b0141610.1021/acs.nanolett.7b01416 ↗
20. Kim, S.H., Kim, H.K., Seo, J.H., Whang, D.M., Ahn, J.P., and Lee, J.C., Deformation twinning of ultrahigh strength aluminum nanowire, Acta Mater., 2018, vol. 160, pp. 14-21. https://doi.org/10.1016/j.actamat.2018.08.04710.1016/j.actamat.2018.08.047 ↗
21. Kim, S.H., Park, J.H., Kim, H.K., Ahn, J.P., Whang, D.M., and Lee, J.C., Twin boundary sliding in single crystalline Cu and Al nanowires, Acta Mater., 2020, vol. 196, pp. 69-77. https://doi.org/10.1016/j.actamat.2020.06.02810.1016/j.actamat.2020.06.028 ↗
22. Seo, J.-H., Park, H.-S., Yoo, Y., Seong, T.-Y., Li, J., Ahn, J.-P., Kim, B., and Choi, I.-S., Origin of size dependency in coherent-twin-propagation-mediated tensile deformation of noble metal nanowires, Nano Lett., 2013, vol. 13, pp. 5112-5116. https://doi.org/10.1021/nl402282n10.1021/nl402282n ↗
23. Chen, L.Y., Richter, G., Sullivan, J.P., and Gianola, D.S., Lattice anharmonicity in defect-free Pd nanowhiskers, Phys. Rev. Lett., 2012, vol. 109, art. no. 125503. https://doi.org/10.1103/PhysRevLett.109.12550310.1103/PhysRevLett.109.125503 ↗
24. Bobylev, S.V., Gutkin, M.Yu., and Ovid'ko. I.A., Partial and split dislocation configurations in nanocrystalline metals, Phys. Rev. B, 2006, vol. 73, art. no. 064102. https://doi.org/10.1103/PhysRevB.73.06410210.1103/PhysRevB.73.064102 ↗
25. Gutkin, M.Yu. and Ovid’ko, I.A., Generation of dislocation loops in deformed nanocrystalline materials, Phil. Mag., 2006, vol. 86, pp. 1483-1511. https://doi.org/10.1080/1478643050019930210.1080/14786430500199302 ↗
26. Bobylev, S.V., Gutkin, M.Yu., and Ovid'ko, I.A., Generation of glide split-dislocation half-loops by grain boundaries in nanocrystalline, Physics of Solid State, 2006, vol. 48, no. 8, pp. 1495-1505. https://doi.org/10.1134/S106378340608013010.1134/S1063783406080130 ↗
27. Gutkin, M.Yu., Ovid’ko, I.A., and Skiba, N.V., Generation of deformation twins in nanocrystalline metals: theoretical model, Phys. Rev. B, 2006, vol. 74, art. no. 172107. https://doi.org/10.1103/PhysRevB.74.17210710.1103/PhysRevB.74.172107 ↗
28. Gutkin, M.Yu., Ovid'ko, I.A., and Skiba, N.V., Mechanism of deformation-twin formation in nanocrystalline metals, Physics of Solid State, 2007, vol. 49, No. 5, pp. 874-882. https://doi.org/10.1134/S106378340705012510.1134/S1063783407050125 ↗
29. Gutkin, M.Yu., Ovid’ko, I.A., and Skiba, N.V., Crack-stimulated generation of deformation twins in nanocrystalline metals and ceramics, Philos. Mag., 2008, vol. 88, pp. 1137-1151. https://doi.org/10.1080/1478643080207081310.1080/14786430802070813 ↗
30. Hirth, J.P. and Lothe, J., Theory of Dislocations. New York: Wiley, 1982.
31. Gutkin, M.Yu. and Romanov, A.E., Straight edge dislocations in a thin two-phase plate. I. Elastic stress fields, Phys. stat. sol. (a), 1991, vol. 125, pp. 107-125. https://doi.org/10.1002/pssa.221125010810.1002/pssa.2211250108 ↗
32. Gutkin, M.Yu. and Ovidko, I.A., Physical Mechanics of Deformable Nanostructures. Volume II. Nanolayer Structures. St. Petersburg: Janus, 2005.
33. Mura, T., The continuum theory of dislocations, in Advances in Material Research, Herman, H., Ed., New York: Interscience, 1968, vol. 3, pp. 1-108.
34. Rabotnov, Yu.N., Mechanics of Deformable Solids. Moscow: Nauka, 1988.
35. Liao, X.Z., Zhou, F., Lavernia, E.J., Srinivasan, S.G., Baskes, M.I., He, D.W., and Zhu, Y.T., Deformation mechanism in nanocrystalline Al: Partial dislocation slip, Applied Physics Letters, 2003, vol. 83, p.p. 632-634. https://doi.org/10.1063/1.159483610.1063/1.1594836 ↗
36. Liao, X.Z., Zhou, F., Lavernia, E.J., He, D.W., and Zhu, Y.T., Deformation twins in nanocrystalline Al, Applied Physics Letters, 2003, vol. 83, pp. 5062-5064. https://doi.org/10.1063/1.163397510.1063/1.1633975 ↗
37. Chen, M., Ma, E., Hemker, K.J., Sheng, H., Wang, Y., and Cheng, X., Deformation twinning in nanocrystalline aluminum, Science, 2003, vol. 300, pp. 1275-1277. https://doi.org/10.1126/science.108372710.1126/science.1083727 ↗
38. Han, W.Z., Cheng, G.M., Li, S.X., Wu, S.D., and Zhang, Z.F., Deformation induced microtwins and stacking faults in aluminum single crystal, Physical Review Letters, 2008, vol. 101, art. no. 115505. https://doi.org/10.1103/PhysRevLett.101.11550510.1103/PhysRevLett.101.115505 ↗
39. Yamakov, V., Wolf, D., Phillpot, S.R., and Gleiter, H., Deformation twinning in nanocrystalline Al by molecular dynamics simulation, Acta Mater., 2002, vol. 50, pp. 5005–5020. https://doi.org/10.1016/S1359-6454(02)00318-X10.1016/S1359-6454(02)00318-X ↗
40. Shimokawa, T., Nakatani, A., and Kitagawa, H., Grain-size dependence of the relationship between intergranular and intragranular deformation of nanocrystalline Al by molecular dynamics simulations, Physical Review B, 2005, vol. 71, art. no. 224110. https://doi.org/10.1103/PhysRevB.71.22411010.1103/PhysRevB.71.224110 ↗