journal article·2024-06

Effect of Structural-Phase State on the Deformation Behavior and Mechanical Properties of Near β Titanium Alloy VT22 in the Temperature Range 293–823 K

G. P. Grabovetskaya, I. P. Mishin, E. V. Naydenkin, I. V. Ratochka, E. N. Stepanova, O. V. Zabudchenko, O. N. Lykova

Physical Mesomechanics· Volume 27· Issue 3
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Abstract

Abstract This paper investigates the effect of thermomechanical treatments, including deformation by radial shear rolling or severe plastic deformation by abc pressing with subsequent aging at 773 K, on the structural-phase state, deformation behavior, and mechanical properties of commercial near β titanium alloy VT22 (Ti–5Al–5Mo–5V–1Cr–1Fe). The structure of the alloy after radial shear rolling and subsequent aging consists of transformed β grains with a lamellar α + β structure and primary α-phase particles. Severe plastic deformation of the alloy followed by aging causes the formation of a grain-subgrain α + β structure with an average characteristic size of 0.23 µm. It is found that, after the thermomechanical treatments, the strength characteristics of the alloy at room temperature increase by ~40% compared to the as-received alloy. The alloy after radial shear rolling and aging retains a 40–20% higher strength in the temperature range of 293–823 K. The strength of the alloy after severe plastic deformation and aging becomes lower than that of the as-received alloy already at a temperature of 773 K. Analysis of creep parameters at 743 K shows that the creep deformation of the alloy in the state after radial shear rolling and aging occurs by the motion of dislocations (glide + climb). The creep deformation of the alloy in the state after severe plastic deformation and subsequent aging is largely contributed by grain boundary sliding.
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OpenAlex topics: Titanium Alloys Microstructure and Properties · Metal and Thin Film Mechanics · Advanced materials and composites

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References (43)

Show source-provided references
1. Putyrskiy, S.V., Yakovlev, A.L., Nochovnaya, N.A., and Krokhina, V.A., Research of Different Heat Treatment Modes Influence on Properties of Semi-Finished Products and Welded Joints from Titanium Alloy VT22M, Aviats. Mat. Tekhn., 2019, no. 1(54), pp. 3–10. https://doi.org/10.18577/2071-9140-2019-0-1-3-1010.18577/2071-9140-2019-0-1-3-10 ↗
2. Li, C., Zhang, X.Y., Zhou, K.C., and Peng, C.Q., Relationship between Lamellar α Evolution and Flow Behavior during Isothermal Deformation of Ti-5Al-5Mo-5V-1Cr-1Fe near β Titanium Alloy, Mater. Sci. Eng. A, 2012, vol. 558, pp. 668–674. https://doi.org/10.1016/j.msea.2012.08.07410.1016/j.msea.2012.08.074 ↗
3. Demakov, S.L., Gadeev, D.V., Illarionov, A.G., and Ivasishin, O.M., Effect of Heat Treatment on the Structure and Fracture Behavior of Titanium Alloy VST5553, Met. Sci. Heat Treat., 2015, vol. 57, no. 7–8, pp. 473–479.10.1007/s11041-015-9907-1 ↗
4. Polyanskiy, V.M., Puchkov, Yu.A., Orlov, M.R., Naprienko, S.A., and Lavrov, A.V., Influence of Tensile Stresses on the Corrosion Resistance of Titanium Alloy VT22 in Aqueous Solution of NaCl, Inorg. Mat. Appl. Res., 2017, vol. 8, no. 1, pp. 94–99.10.1134/S2075113317010294 ↗
5. Huang, J., Wang, Z., and Zhou, J., Cyclic Deformation Response of β-Annealed Ti-5Al-5V-5Mo-3Cr Alloy under Compressive Loading Conditions, Metall. Mater. Trans. A, 2011, vol. 42, pp. 2868–2880. https://doi.org/10.1007/s11661-011-0705-010.1007/s11661-011-0705-0 ↗
6. Naydenkin, E.V., Mishin, I.P., Ratochka, I.V., Oborin, V.A., Bannikov, M.V., Bilalov, D.A., and Naydenkin, K.E., Fatigue and Fracture Behavior of Ultrafine-Grained near β Titanium Alloy Produced by Radial Shear Rolling and Subsequent Aging, Mater. Sci. Eng. A, 2021, vol. 810, p. 140968. https://doi.org/10.1016/j.msea.2021.14096810.1016/j.msea.2021.140968 ↗
7. Lütjering, G. and Williams, J.C., Titanium, Berlin: Springer, 2007, pp. 283–336. https://doi.org/10.1007/978-3-540-73036-110.1007/978-3-540-73036-1 ↗
8. Moiseev, V.N., Gribkov, Yu.A., and Zakharov, Yu.I., High-Strength Titanium Alloys in Aircraft Structures, Aviats. Mat. Tekhn., 2007, no. 1, pp. 46–51.
9. Kolachev, B.A., Eliseev, Yu.S., Bratukhin, A.G., and Talalaev, V.D., Titanium Alloys in Structures and Production of Aircraft Engines and Aerospace Equipment, Bratukhin, A.G., Ed., Moscow: MAI Publ. House, 2001.
10. Yakovlev, A.L., Nochovnaya, N.A., Putyrskiy, S.V., and Krokhina, V.A., Prospecive Usage of High-Strength Titanium Alloy VT22 and Its Modifications, Titan, 2018, no. 2(60), pp. 42–47.
11. Ilyin, A.A., Kolachev, B.A., and Polkin, I.S., Titanium Alloys. Composition, Structure, Properties: Handbook, Moscow: VILS-MATI, 2009.
12. Moiseev, V.N., Sysoeva, N.V., and Ermolova, M.I., Heat Treatment of Granular Alloy Type VT22, Met. Sci. Heat Treatment, 1996, vol. 38, no. 1, pp. 42–45.10.1007/BF01153872 ↗
13. Kozlova, I.R., Chudakov, E.V., Tretyakova, N.V., Markova, Y.M., and Vasilieva, E.A., The Influence of Heat Treatment on the Formation of the Structure and the Level of Mechanical Properties of High-Alloy Titanium Alloy, Inorg. Mat. Appl. Res., 2020, vol. 11, no. 6, pp. 1307–130610.1134/S2075113320060118 ↗
14. Yilmazer, H., Niinomi, M., Nakai, M., Cho, K., Hieda, J., Todaka, Y., and Miyazaki, T., Mechanical Properties of a Medical -Type Titanium Alloy with Specific Microstructural Evolution through High-Pressure Torsion, Mater. Sci. Eng. C, 2013, vol. 33(5), pp. 2499–2507. https://doi.org/10.1016/j.msec.2013.01.05610.1016/j.msec.2013.01.056 ↗
15. Valiev, R.Z., Estrin, Y., Horita, Z., Langdon, T.G., Zehetbauer, M.J., and Zhu, Y.T., Fundamentals of Superior Properties in Bulk NanoSPD Materials, Mater. Res. Lett., 2016, vol. 4, no. 1, pp. 1–21. https://doi.org/10.1080/21663831.2015.106054310.1080/21663831.2015.1060543 ↗
16. Grabovetskaya, G.P., Mishin, I.P., Stepanova, E.N., Zabudchenko, O.V., and Ratochka, I.V., Effect of the Structural and Phase State on the Deformation Behavior and Mechanical Properties of the Ultrafine-Grained Titanium Alloy (Ti–Al–V–Мо) at Temperatures in the Range of 293–973 K, Mater. Sci. Eng. A, 2021, vol. 800, p. 140334. https://doi.org/10.1016/j.msea.2020.14033410.1016/j.msea.2020.140334 ↗
17. Ratochka, I.V., Naydenkin, E.V., Lykova, O.N., and Mishin, I.P., Influence of Annealing on the Structure and Mechanical Properties of Ultrafine-Grained VT22 Titanium Alloy, Russ. Phys. J., 2019, vol. 62, pp. 1322–1329. https://doi.org/10.1007/s11182-019-01850-510.1007/s11182-019-01850-5 ↗
18. Polkin, I.S., Kasparova, O.V., and Zabolotnov, M.E., Method of Thermomechanical Processing of α + β Titanium Alloys, Patent SU396427A1, Byul. Izobr., 1973, no. 36.
19. Wang, H., Ge, J., Zhang, X., Chen, C., and Zhou, K., Investigation of the Dynamic Recovery and Recrystallization of Near-β Titanium Alloy Ti-55511 during Two-Pass Hot Xompression, Metals, 2021, vol. 11(2), p. 359. https://doi.org/10.3390/met1102035910.3390/met11020359 ↗
20. Illarionov, A.G., Korelin, A.V., Popov, A.A., Illarionova, S.M., and Elkina, O.A., Formation of the Structure, Phase Composition, and Properties in High-Strength Titanium Alloy upon Isothermal and Thermomechanical Treatment, PMM, 2018, vol. 119, no. 8, pp. 780–788.
21. Sheremetyev, V., Kudryashova, A., Cheverikin, V., Korotitskiy, A., Galkin, S., Prokoshkin, S., and Brailovski, V., Hot Radial Shear Rolling and Rotary Forging of Metastable beta Ti-18Zr14Nb (at %) Alloy for Bone Implants: Microstructure, Texture and Functional Properties, J. Alloy. Compd, 2019, vol. 800, pp. 320–326. https://doi.org/10.1016/j.jallcom.2019.06.04110.1016/j.jallcom.2019.06.041 ↗
22. Ahmed, M., Savvakin, D.G., Ivasishin, O.M., and Pereloma, E.V., The Effect of Ageing on Microstructure and Mechanical Properties of Powder Ti–5Al–5Mo–5V–1Cr–1Fe Alloy, Mater. Sci. Eng. A, 2014, vol. 605, pp. 89–97. https://doi.org/10.1016/j.msea.2014.03.03010.1016/j.msea.2014.03.030 ↗
23. Naydenkin, E.V., Mishin, I.P., Ratochka, I.V., Lykova, O.N., and Manisheva, A.I., Influence of Radial Shear Rolling Regimes on the Homogeneity of Structural-Phase State, Mechanical Properties and Fatigue of Near β Titanium Alloy, Mater. Sci. Forum, 2021, vol. 1016, pp. 1024–1030. https://doi.org/10.4028/www.scientific.net/msf.1016.102410.4028/www.scientific.net/msf.1016.1024 ↗
24. Langdon, T.G., Grain Boundary Sliding Revisited: Developments in Sliding over Four Decades, J. Mater. Sci., 2006, vol. 41, pp. 597–609. https://doi.org/10.1007/s10853-006-6476-010.1007/s10853-006-6476-0 ↗
25. Gifkins, R.C., Grain-Boundary Sliding and Its Accommodation during Creep and Superplasticity, Metall. Trans. A, 1976, vol. 7, pp. 1225–1232. https://doi.org/10.1007/BF0265660710.1007/BF02656607 ↗
26. Mukherjee, A.K., The Rate Controlling Mechanism in Superplasticity, Mater. Sci. Eng. A, 1971, vol. 8(2), pp. 83–89. https://doi.org/10.1016/0025-5416(71)90085-110.1016/0025-5416(71)90085-1 ↗
27. Motyka, M., Sieniawski, J., and Ziaja, W., Microstructural Aspects of Superplasticity in Ti-6Al-4V Alloy, Mater. Sci. Eng. A, 2014, vol. 599, pp. 57–63. https://doi.org/10.1016/j.msea.2014.01.06710.1016/j.msea.2014.01.067 ↗
28. Meier, M.L., Lesuer, D.R., and Mukherjee, A.K., α Grain Size and β Volume Fraction Aspects of the Superplasticity of Ti-6Al-4V, Mater. Sci. Eng. A, 1991, vol. 136, pp. 71–78. https://doi.org/10.1016/0921-5093(91)90442-P10.1016/0921-5093(91)90442-P ↗
29. Kaibyshev, O.A. and Valiev, R.Z., Grain Boundaries and Properties of Metals, Moscow: Metallurgiya, 1987.
30. Watanabe, Т., Yamada, М., Karashima, S., and Shima, S., Misorientation Dependence of Grain Boundary Sliding in <1010> Tilt Zinc Bicrystals, Philos. Mag. A, 1979, vol. 40, no. 5, pp. 667–683. https://doi.org/10.1080/0141861790823486710.1080/01418617908234867 ↗
31. Shalimova, A.V. and Rogalina, N.A., Influence of Misorientation of Neighboring Grains on Grain Boundary Sliding, FMM, 1981, vol. 51, no. 5, pp. 1084–1086.
32. Vinokurov, V.A., Ratochka, I.V., Naidenkin, E.V., Mishin, I.P., and Rozhentseva, N.V., Method to Produce Titanium Alloys with Submicrocrystalline Strain Structure Allowing Intensive Plastic Strain, RF Patent No. 2388566, Byul. Izobr., 2010, no. 13.
33. Gorelik, S.S., Skakov, Yu.A., and Rastorguev, L.N., X-Ray and Electron-Optical Analysis, Moscow: MISIS, 2002.
34. Frost, H.J. and Ashby, M.F., Deformation-Mechanism Maps, Oxford: Pergamon Press, 1982.
35. Malykhin, D.G. and Korneeva, V.V., Determination of Dislocation Density by X-Ray Analysis of Microdistortions in Polycrystalline Materials, Vest. Kharkov. Univer., 2010, vol. 887, no. 1, pp. 115–117.
36. Garofalo, F., Fundamentals of Creep and Creep-Rupture in Metals, New York: Macmillan, 1965.
37. Ratochka, I.V., Naydenkin, E.V., Mishin, I.P., Lykova, O.N., and Zabudchenko, O.V., Low-Temperature Superplasticity of Ultrafine-Grained Near β Titanium Alloy, J. Alloy. Compd, 2022, vol. 891, p. 161981. https://doi.org/10.1016/j.jallcom.2021.16198110.1016/j.jallcom.2021.161981 ↗
38. Grabovetskaya, G.P., Mishin, I.P., Naydenkin, E.V., Zabudchenko, O.V., and Stepanova, E.N., Mechanical Properties and Creep of Alloy VT22 after Radial-Shear Rolling and Subsequent Aging, AIP Conf. Proc., 2022, vol. 2509, p. 020078. https://doi.org/10.1063/5.008490210.1063/5.0084902 ↗
39. Kral, P., Dvorak, J., Zherebtsov, S., Salishchev, G., Kvapilova, M., and Sklenicka, V., Effect of Severe Plastic Deformation on Creep Behavior of a Ti–6Al–4V Alloy, J. Mater. Sci., 2013, vol. 48, pp. 4789–4795. https://doi.org/10.1007/s10853-013-7160-910.1007/s10853-013-7160-9 ↗
40. Guo, Y., Tian, J., Xiao, S., Xu, L., and Chen, Y., Elevated Temperature Performance and Creep Behavior of Y2O3 Reinforced Ti-48Al-6Nb Alloy at the Brittle-Ductile Transition Temperature, J. Alloy. Compd, 2021, vol. 871, p. 159497. https://doi.org/10.1016/j.jallcom.2021.15949710.1016/j.jallcom.2021.159497 ↗
41. Grabovetskaya, G.P., Mishin, I.P., Stepanova, E.N., and Zabudchenko, O.V., Effect of Structure and Hydrogen on the Short-Term Creep of Titanium Ti-2.9Al-4.5V-4.8Mо Alloy, Materials, 2022, vol. 15(11), p. 3905. https://doi.org/10.3390/ma1511390510.3390/ma15113905 ↗
42. Herzig, C., Wilger, T., Przeorski, T., Hisker, F., and Divinski, S.V., Titanium Tracer Diffusion in Grain Boundaries of α-Ti, α2-Ti3Al, and γ-TiAl and in α2/γ Interphase Boundaries, Intermetallics, 2001, vol. 9(5), pp. 431–442. https://doi.org/10.1016/S0966-9795(01)00022-X10.1016/S0966-9795(01)00022-X ↗
43. Novikov, I.I. and Portnoi, V.K., Superplasticity of Alloys with Ultrafine Grains, Moscow: Metallurgiya, 1981.