journal article·2020-05

Visible light active ZnO nanostructures prepared by simple co-precipitation method

Puneetha J, Nagaraju Kottam, Nagaraju G, Rathna A

Publisher page

Abstract

Abstract Visible light active photocatalytic processes have gained much interest in removing the organic pollutants from wastewater. In this article, we report the ZnO prepared by a simple co-precipitation method and characterized by PXRD, FE-SEM, TEM, DRS, and FTIR. The photocatalytic activity of ZnO assisted by H2O2 was examined for the degradation of the aqueous solution of Crystal violet (CV) under visible light. The combination of ZnO and H2O2 has enhanced the activity compared to bare ZnO or H2O2 alone under visible light. The influence of H2O2, Catalyst amount, CV concentration and pH were studied. The ZnO nanostructures in the presence of H2O2 exhibited highest photodegradation rate of CV solution under alkaline pH. The observed photodegradation efficiency by the ZnO photocatalyst under visible light is due to the deep level defects within the band gap, which induced in the course of the preparation method of the ZnO nanostructures, which shifts the absorption wavelength band to the visible light region. The ZnO assisted by H2O2 maintained good photostability and repeatability after 4 cycles of degradation under visible light.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · ZnO doping and properties · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (60)

Show source-provided references
1. A review of ZnO nanoparticles as solar photocatalysts: synthesis, mechanisms and applications10.1016/j.rser.2017.08.020 ↗
2. A combustion synthesis route for magnetically separable GrapheneOxide-CuFe2O4-ZnO nanocomposite with enhanced solar light-mediated PhotocatalyticActivity10.1039/C7NJ02070H ↗
3. Recent developments in heterogeneous photocatalyticwater treatment using visibleLight responsive photocatalysts: a review10.1039/C4RA13734E ↗
4. Review on various strategies for enhancingphotocatalytic activity of graphene basednanocomposites for water purification
5. Photoreactivityof ZnO nanoparticles in visible light: Effect of surface states on electrontransfer reaction
6. Hooshyar Hossini & Ghulam Md Ashraf, Photocatalytic degradation of Aniline from aqueous solutions under sunlightillumination using immobilized Cr:ZnO nanoparticles
7. Synthesis of zinc oxide nanotubes within ultrathin anodic aluminum oxide membrane by sol–gel method10.1016/j.matlet.2013.02.037 ↗
8. Facile template-freehydrothermal synthesis and microstrain measurement of ZnO nanorods10.1007/s12034-014-0676-z ↗
9. Controllable synthesis ofZnO nanoparticles with high intensity visible photoemission andinvestigation of itsmechanism, IOP Publishing
10. Visible light photocatalysis as a greener approach tophotochemical synthesis10.1038/nchem.687 ↗
11. Controlled defects of zinc oxide nanorods for efficient visible light photocatalytic degradationof phenol10.3390/ma9040238 ↗
12. Enhanced Photocatalytic Activityof NaBH4 Reduced BiFeO3Nanoparticles for Rhodamine B Decolorization
13. Defects in ZnO10.1063/1.3216464 ↗
14. Band gap engineering of CeO2 Nanostructure by electrochemically active biofilm for visible light applications10.1039/C4RA00861H ↗
15. Synthesis, structural and optical properties of pure ZnO and Co doped ZnO nanoparticle prepared by the co-precipitation method10.1007/s40094-016-0221-0 ↗
16. Rapid photocatalyticdegradation of crystal violet dye over ZnO flower nanomaterials10.1016/j.matlet.2013.01.034 ↗
17. ZnO nanonails for photocatalytic degradation of crystal violet dye under UVirradiation10.3934/matersci.2017.1.267 ↗
18. Synthesis of ZnOnanoparticles by co-precipitation method for solar drivenphotodegradation of Congoreddye at different pH10.1016/j.photonics.2018.08.005 ↗
19. Visible light assisted improved photocatalytic activity of combustion synthesized spongy-ZnO towards dye degradation and bacterial inactivation10.1039/C6RA10472J ↗
20. Photocatalyticdegradation of Rhodamine B dye under UV/solar light using ZnO nanopowdersynthesized by solution combustion route10.1016/j.powtec.2011.09.014 ↗
21. An excellent photocatalytic efficiency of ZnO under visible light for fast removal of photocatalytic efficiency of ZnO under visible light for fast/removal of organic pollutant from aqueous solution10.1016/j.matpr.2018.06.471 ↗
22. Photocatalytic decolourization of crystal violet in aqueous nano-ZnO suspension undervisible light irradiation
23. Two-channelphotocatalytic production of H2O2 over g-C3N4 nanosheets modified with peryleneimides10.1016/j.jcat.2017.05.010 ↗
24. Enhanced Photocatalyticdegradation of methylene blue dye using CuS-CdS nanocomposite under visible light irradiation10.1016/j.apsusc.2018.12.178 ↗
25. Exposure to crystal violet, its toxic, genotoxic andcarcinogenic effects on environment and its degradation and detoxification for environmental safety
26. Photocatalyticdegradation of crystal violet over semiconductor zinc oxide powder suspended inaqueous solution10.1080/02772249709358460 ↗
27. Highly efficient WO3–ZnO mixed oxides for photocatalysis10.1039/C4RA13210F ↗
28. Modified scherrer equation to estimatemore accurately nano crystallite size using XRD10.4236/wjnse.2012.23020 ↗
29. Synthesis and opticalcharacterization of porous ZnO, K. Sowri Babu, A. Ramachandra reddy
30. Synthesis of nano-sized ZnOparticles by co-precipitation method with variation of heating time
31. Analysis of structural, optical and magnetic properties of Fe/Co co-doped ZnO nanocrystals10.1016/j.ceramint.2017.03.201 ↗
32. Transition metal (Co, Mn) co-doped ZnO nanoparticles: effect on structural and optical properties10.1016/j.jallcom.2016.12.227 ↗
33. Annealing effects on the structural and optical propertiesof ZnO nanostructures
34. Disinfection of multidrug resistant Escherichia coli by SolarPhotocatalysis using Fe-doped ZnO nanoparticles
35. Estimation of lattice strain in ZnO nanoparticles: X-ray peakprofile analysis10.1007/s40094-014-0141-9 ↗
36. Green mediated synthesisand characterization of ZnO nanoparticles using Euphorbia jatropa latex as reducingagent10.1016/j.jsamd.2016.06.015 ↗
37. Structural and magnetic properties and DFT analysis ofZnO:(Al,Er) nanoparticles10.1039/C7RA01015J ↗
38. Catalytically Engineered reduced graphene oxide/ZnO hybrid nanocomposites for the adsorption, photoactivity and selective oil pick-up from aqueous media10.1039/C5RA04850H ↗
39. Bovine serum albumin modified ZnO to degrade organicdyes under ultraviolet light irradiation10.1039/C5NJ03061G ↗
40. Hydrothermalsynthesis of Zinc oxide nanopartilces using rice as soft biotemplate10.1186/1752-153X-7-136 ↗
41. Facile synthesis of quasi spherical ZnO nanoparticles with excellent photocatalytic activity10.1007/s10876-014-0806-1 ↗
42. Novelinsights into the properties of AgBiO3 photocatalyst and its application in immobilizedstate for 4-nitrophenol degradation and bacteria inactivation10.1016/j.jphotochem.2018.11.001 ↗
43. High throughput light absorber discovery, part 1: an algorithm for automated Tauc analysis10.1021/acscombsci.6b00053 ↗
44. Influence of hydrogenperoxide in enhancing photocatalytic activity of carbon nitride under visible light: an insight into reaction intermediates10.1016/j.jece.2018.07.030 ↗
45. Hollow microspheres Mg-doped ZrO2 nanoparticles: green assisted synthesis and applications in photocatalysis and photoluminescence10.1016/j.jallcom.2016.02.124 ↗
46. Hydrogen peroxide-assisted photocatalysis under solar light irradiation: interpretation of interaction effects between an active photocatalyst and H2O210.1002/cjce.23455 ↗
47. Enhanced visible light photocatalyticactivity of g-C3N4 assisted by hydrogen peroxide
48. Enhancement of decolorization rate and COD removal from dyes containing wastewaterby the addition of hydrogen peroxide under solar photocatalytic oxidation10.1016/j.desal.2007.01.013 ↗
49. Photocatalytic degradation of Bisphenol-A using N, Co codoped TiO2 catalyst under solar light
50. Influencing parameters in the photocatalytic degradation of organic effluent via nanometal oxide catalyst: a review
51. Changlin Yuaand Min Wub, Photocatalytic degradation of two different types of dyes by synthesizedLa/Bi2WO6
52. Characterization of zinc oxide nanorods loaded on activated carbon as cheap and efficient adsorbent for removal of methylene blue10.1016/j.jiec.2014.05.006 ↗
53. Removal of malachite greenfrom aqueous solution by zinc oxide nanoparticle loaded on activated carbon: kineticsand isotherm study10.1016/j.jiec.2013.04.031 ↗
54. Influence of pH on the photocatalytic activityof ZnO nanoparticles10.1007/s10854-016-4284-0 ↗
55. Enhancing photocatalytic activity of zinc oxide by coating with some natural pigments10.1016/j.arabjc.2010.06.038 ↗
56. Insights into the energy levels of semiconductor nanocrystals by a dopant approach, angewandte chemie international edition
57. Kinetic modeling of photocatalytic degradation of acid red 27 in UV/TiO2 process10.1016/j.jphotochem.2004.05.011 ↗
58. Modeling the degradation and disinfection of water pollutants by photocatalysts and composites: a critical review10.1016/j.scitotenv.2019.134197 ↗
59. Mechanism and Kinetics study for photocatalytic oxidation degradation: a case study for phenoxyacetic acid organic pollutant, Hindawi publishing corporation
60. Amagnetically recyclable photocatalyst with commendable dye degradation activity atambient conditions