Enhanced photocatalytic oxidation of toluene with a coral-like direct Z-scheme BiVO 4 /g-C 3 N 4 photocatalyst

Abstract A coral-like direct Z-scheme BiVO4/g-C3N4 photocatalyst was synthesized by a calcination method for the photocatalytic oxidation of toluene. The structures and optical properties of the photocatalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), the Brunauer–Emmett–Teller (BET) method and UV–Vis diffuse reflectance spectroscopy (DRS). BiVO4/g-C3N4 composites exhibited coral-like structures, with well-defined boundaries and high specific surface area (33.97 m2 g−1) compared to a g-C3N4 sample (5.627 m2 g−1). The introduction of BiVO4 to g-C3N4 greatly enhanced the photocatalytic efficiency. For the optimum BiVO4/g-C3N4 photocatalyst, the degradation rate constant and mineralization rate of toluene were 3.2 and 4.5 times greater, respectively, than those of pure g-C3N4 under visible light (λ > 400 nm). A direct Z-scheme mechanism is proposed for the enhanced photocatalytic activity and was further confirmed by electron spin-resonance spectroscopy (ESR) and terephthalic acid photoluminescence (TA-PL) experiments. This study demonstrated a coral-like BiVO4/g-C3N4 photocatalyst for the efficient photocatalytic oxidation of toluene and provided some understanding for designing direct Z-scheme photocatalysts.