journal article·2013-08

The high temperature oxidation and ignition behavior of Mg–Nd alloys part I: The oxidation of dilute alloys

D.S. Aydin, Z. Bayindir, M. Hoseini, M.O. Pekguleryuz

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Abstract

Abstract The high temperature oxidation behavior of magnesium (Mg) alloys containing neodymium (Nd) was investigated at low level concentrations (0.3 and 0.5 wt.%). Continuous heating experiments carried out in dry air-flow revealed, interestingly, that the ignition temperature ( T i ) is raised from 640 °C (of pure Mg) to up to 770 °C at 0.5 wt.% Nd addition. No significant improvement was detected with 0.3 wt.% Nd. The analyses of the surface indicate that the two alloys form different oxide morphologies when oxidized at 500 °C for 12 h in air. Although a more dense oxide scale forms with 0.3 wt.% Nd addition compared to pure Mg, the ignition results showed that the Nd addition below 0.5 wt.% is not effective on the oxidation resistance. The presence of Nd 2 O 3 plays an indirect protective role delaying Mg evaporation and ignition.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · High-Temperature Coating Behaviors · Hydrogen Storage and Materials

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References (51)

Show source-provided references
1. You · Scripta Mater. · 2000 · 42 · 108910.1016/S1359-6462(00)00344-4 ↗
2. Song · Adv. Eng. Mater. · 2005 · 7 · 56310.1002/adem.200500013 ↗
3. Fournier · Surf. Int. Anal. · 2002 · 34 · 49410.1002/sia.1346 ↗
4. Liu · Corros. Sci. · 2009 · 51 · 12910.1016/j.corsci.2008.10.011 ↗
5. Czerwinski · Corros. Sci. · 2004 · 46 · 37710.1016/S0010-938X(03)00151-3 ↗
6. Ha · J. Alloys Comp. · 2006 · 422 · 20810.1016/j.jallcom.2005.12.003 ↗
7. M. Tim, FAA overview on testing of magnesium alloys for use in an aircraft cabin, FAA 6th Triennial Cabin and Fire Safety Conference, October 27, 2010, Atlantic City.
8. S. Alfons, Potential for magnesium in aircraft seats, FAA 6th Triennial Cabin and Fire Safety Conference, October 27, 2010, Atlantic City.
9. G. Bruce, Magnesium alloys in aerospace applications – flammability testing and results, in: S.R. Agnew, N.R. Neelameggham, E.A. Nyberg, W.H. Sillekens (Eds.), Magnesium Technology, 2010, p. 13.
10. Gulbransen · Trans. Electrochem. Soc. · 1945 · 87 · 58910.1149/1.3071667 ↗
11. Leontis · Trans. Am. Inst. Mining Met. Eng. · 1946 · 166 · 265
12. Gregg · J. Inst. Met. · 1958 · 87 · 187
13. J.J. Blandin, E. Grosjean, M. Suéry, N.V. Ravi Kumar, N. Mebarki, Ignition resistance of various magnesium alloys, in: A.A. Luo (Ed.), Magnesium Technology, 2004, pp. 235–240.
14. Edward · 2010
15. Kubaschewski · 1967
16. Tadao · Combust. Sci. Technol. · 1980 · 213 · 109
17. Ravi Kumar · Scripta Mater. · 2003 · 49 · 22510.1016/S1359-6462(03)00263-X ↗
18. Laurendeau · Combust. Sci. Technol. · 1971 · 3 · 7710.1080/00102207108952274 ↗
19. Birbilis · Corros. Sci. · 2009 · 51 · 68310.1016/j.corsci.2008.12.012 ↗
20. Arrabal · Oxid. Met. · 2011 · 76 · 43310.1007/s11085-011-9265-3 ↗
21. Fan · J. Alloys Comp. · 2011 · 509 · 213710.1016/j.jallcom.2010.10.168 ↗
22. Zhao · Adv. Mater. Res. · 2011 · 214 · 11810.4028/www.scientific.net/AMR.214.118 ↗
23. Wang · Appl. Surf. Sci. · 2007 · 253 · 901710.1016/j.apsusc.2007.05.023 ↗
24. Lin · Corros. Sci. · 2008 · 50 · 266910.1016/j.corsci.2008.06.025 ↗
25. Li · Mater. Lett. · 2007 · 61 · 277210.1016/j.matlet.2006.10.028 ↗
26. Fan · Metall. Mater. Trans. A · 2005 · 36A · 23510.1007/s11661-005-0155-7 ↗
27. Lin · Corros. Sci. · 2009 · 51 · 30110.1016/j.corsci.2008.10.033 ↗
28. Xuemin · J. Alloys Comp. · 2009 · 474 · 49910.1016/j.jallcom.2008.06.122 ↗
29. Rokhlin · 2003
30. Delfino · Metall. Trans. A · 1990 · 21A · 210910.1007/BF02647869 ↗
31. Kopp · J. Phase Equilib. Diffus. · 2011 · 32 · 29810.1007/s11669-011-9882-1 ↗
32. Wang · J. Alloys Comp. · 2008 · 460 · 36810.1016/j.jallcom.2007.06.065 ↗
33. Shih · Mater. Chem. Phys. · 2007 · 104 · 49710.1016/j.matchemphys.2007.04.010 ↗
34. Pieraggi · Oxid. Metal. · 1987 · 27 · 17710.1007/BF00667057 ↗
35. de Noirfontaine · Oxid. Metal. · 2010 · 73 · 21910.1007/s11085-009-9176-8 ↗
36. Yao · Electrochim. Acta · 2003 · 48 · 419710.1016/S0013-4686(03)00605-4 ↗
37. Wang · J. Alloys Comp. · 2008 · 456 · 38410.1016/j.jallcom.2007.02.048 ↗
38. Splinter · Surf. Sci. · 1993 · 292 · 13010.1016/0039-6028(93)90396-2 ↗
39. Peng · Surf. Sci. · 1990 · 233 · 28310.1016/0039-6028(90)90641-K ↗
40. Uwamino · J. Electron. Spectrosc. Relat. Phenom. · 1984 · 34 · 6710.1016/0368-2048(84)80060-2 ↗
41. Moulder · 1995
42. Yao · Electrochim. Acta · 2003 · 48 · 264110.1016/S0013-4686(03)00310-4 ↗
43. Kang · Calphad · 2012 · 38 · 10010.1016/j.calphad.2012.05.005 ↗
44. Bale · Calphad · 2009 · 33 · 29510.1016/j.calphad.2008.09.009 ↗
45. Barin · 1993
46. Rahmel · Oxid. Metal. · 1991 · 35 · 5310.1007/BF00666500 ↗
47. James · Rev. Min. Geochem. · 2010 · 72 · 75710.2138/rmg.2010.72.17 ↗
48. Lea · J. Mater. Sci. · 1984 · 19 · 233610.1007/BF01058110 ↗
49. G.D. Stone, G.R. Weber, L. Eyring, Self diffusion of oxygen in neodymium and Samarium Sesquioxide, in: J.B. Wachman, Jr., A.D. Franklin (Eds.), Proceedings of a Conference on Mass Transport in Oxides, Marylan, October 22–25, 1967, pp. 179–186.
50. P. Kofstad, Reactions at surfaces and interfaces – Gas–metal interactions at high temperatures, in: 8th International Symposium on the Reactivity of Solids, Chalmers University of Technology, Goteborg, Sweden, 1976, pp. 15–42.10.1007/978-1-4684-2340-2_2 ↗
51. Yufeng · Adv. Mater. Res. · 2011 · 146–147 · 1702