journal article·2017-09

The phase stability of equiatomic CoCrFeMnNi high-entropy alloy: Comparison between experiment and calculation results

Nokeun Park, Byeong-Joo Lee, Nobuhiro Tsuji

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Abstract

Abstract A comparative study about the phase stability of equiatomic CoCrFeMnNi alloy of thermodynamic calculation (Thermo-Calc) and experimental result is shown. The alloy was processed by through a high-pressure torsion (HPT) process and annealing treatment at temperatures ranging from 900 to 600 °C. Phase identification using X-ray diffraction and energy dispersive X-ray spectroscopy indicated that the Cr-rich sigma phase formed during annealing at temperatures lower than 800 °C after the HPT process, and fraction of sigma phase increased as decreasing annealing temperature as predicted by Thermo-Calc. The thermodynamic calculation based on the TCFE database was found to be suitable for predicting the possible phases in the CoCrFeMnNi alloy.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Additive Manufacturing Materials and Processes

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References (22)

Show source-provided references
1. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes10.1002/adem.200300567 ↗
2. Microstructural development in equiatomic multicomponent alloys10.1016/j.msea.2003.10.257 ↗
3. Alloy design strategies and future trends in high-entropy alloys10.1007/s11837-013-0761-6 ↗
4. Grain growth and the Hall–Petch relationship in a high-entropy FeCrNiCoMn alloy10.1016/j.scriptamat.2012.12.002 ↗
5. The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy10.1016/j.actamat.2013.06.018 ↗
6. Microstructure and texture evolution during annealing of equiatomic CoCrFeMnNi high-entropy alloy10.1016/j.jallcom.2013.10.237 ↗
7. Temperature dependencies of the elastic moduli and thermal expansion coefficient of an equiatomic, single-phase CoCrFeMnNi high-entropy alloy10.1016/j.jallcom.2014.11.061 ↗
8. Otto · Acta Mater. · 2016 · 112 · 4010.1016/j.actamat.2016.04.005 ↗
9. Mechanical properties, microstructure and thermal stability of a nanocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation10.1016/j.actamat.2015.06.025 ↗
10. Pseudo float melting state in ladle arc-melt-type furnace for preparing crystalline inclusion-free bulk amorphous alloy10.2320/matertrans.43.2316 ↗
11. Microstructure and mechanical properties of Co21Cr22Cu22Fe21Ni14 processed by high pressure torsion and annealing10.1007/s11837-015-1586-2 ↗
12. The Thermo-Calc databank system10.1016/0364-5916(85)90021-5 ↗
13. 1999
14. Thermodynamic calculation on the stability of (Fe,Mn)3AlC carbide in high aluminum steels10.1016/j.jallcom.2010.06.032 ↗
15. Insights into the phase diagram of the CrMnFeCoNi high entropy alloy10.1016/j.actamat.2015.01.068 ↗
16. An understanding of high entropy alloys from phase diagram calculations10.1016/j.calphad.2013.10.006 ↗
17. Orientation relationships between gamma (f.c.c.) and sigma phases in an iron-chromium-nickel alloy10.2320/matertrans1960.3.82 ↗
18. Precipitation of (Fe, Cr) sigma phase from austenite10.1016/0001-6160(66)90162-3 ↗
19. Solid state phase equilibrium in the ternary Fe–Co–Cr system: experimental determination of isothermal sections in the temperature range 800 – 1300 °C10.1016/0022-5088(79)90189-9 ↗
20. Overview of intermetallic sigma phase precipitation in stainless steels10.5402/2012/732471 ↗
21. Sigma phase in iron-chromium alloys and steels10.1007/s11041-012-9426-2 ↗
22. Significant hardening due to the formation of a sigma phase matrix in a high entropy alloy10.1016/j.intermet.2012.09.022 ↗