journal article·2007Open access

Nano-structural Changes of C-S-H in Hardened Cement Paste during Drying at 50°C

Yoshimichi Aono, Fumiaki Matsushita, Sumio Shibata, Yukio Hama

Abstract

Pore structural changes in hardened cement pastes, subjected to drying and wetting/drying cycles, were studied at micrometer and nanometer levels. Characterization techniques included Nuclear Magnetic Resonance (NMR), nitrogen and water vapor adsorption, mercury intrusion porosimetry (MIP) and under-water weighing. Coarsening of pore structure was observed with MIP and increase in the true density of C-S-H was suggested by the result of under-water weighing. Decrease in specific surface area due to drying was observed with nitrogen adsorption, and water vapor adsorption associated with Excess Surface Work (ESW) analysis suggested a development of cohesive structure in C-S-H. NMR confirmed polymerization of silicate anion chains. The drying-induced coarsening of pore structure is probably attributed to polymerization of silicate anion chains and development of cohesive structure in C-S-H.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Concrete Properties and Behavior · Advanced ceramic materials synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Sumitomo Metal Mining Siporex, Co. Ltd., Tokyo, Japan.

Muroran Institute of Technology, Muroran, Japan.

References (31)

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