A matching design between strain tolerance and cracking resistance for a long lifespan in thick thermal barrier coatings
Source abstract
Abstract
Abstract Failure is a main disadvantage of thermal barrier coatings (TBCs). Typically, whether failure occurs depends on competition between the cracking driving force (negatively related to strain tolerance) and cracking resistance. However, it is difficult to simultaneously enhance these two properties in conventional monostructures since they often need totally opposite structures. In this work, a novel structure was designed to co-enhance strain tolerance and cracking resistance in thick TBCs. The novel structure appears to have trimodal features. The macro-columnar structure was tailored to enhance the strain tolerance, the mesogradient structure in individual columns was porosity-distributed from bottom to top to enhance the cracking resistance, and the microlamellar structure was deposited to further tolerate strain and to prevent heat flux. First, the trimodal-featured structure was tailored in 2000-μm-thick TBCs. Thermal cyclic tests showed that the lifespan was nearly 4 and 9 times that of the conventional one-way designs of columnar and gradient TBCs, respectively. Second, a finite element model was developed to investigate the mechanism responsible for the long lifespan. Cooperation in lowering the driving force and increasing the cracking resistance significantly retards the cracking behavior in thick coatings. Finally, dominant factors of trimodal-featured structures were discussed and optimized to further extend the lifespan of thick TBCs. Overall, the matching design between strain tolerance and cracking resistance provides a fundamental method for durable protection in thick TBCs.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: High-Temperature Coating Behaviors · Advanced ceramic materials synthesis · High Entropy Alloys Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (72)
Show source-provided references
1. NP Padture. Thermal barrier coatings for gas-turbine engine applications. 2002, 296: 280-284.10.1126/science.1068609 ↗
2. ZJ Zhang. High toughness and CMAS resistance of REAlO 3 /RE 2 Zr 2 O 7 (RE = La, Nd, Sm, Eu, Gd, and Dy) composites with eutectic composition for thermal barrier coatings. 2024, 13: 800-809.10.26599/JAC.2024.9220899 ↗
3. NP Padture. Advanced structural ceramics in aerospace propulsion. 2016, 15: 804-809.10.1038/nmat4687 ↗
4. MD Gan. Suppressing the oxygen-ionic conductivity and promoting the phase stability of the high-entropy rare earth niobates via Ta substitution. 2025, 209: 79-94.10.1016/j.jmst.2024.05.015 ↗
5. DR Clarke. Thermal-barrier coatings for more efficient gas-turbine engines. 2012, 37: 891-898.10.1557/mrs.2012.232 ↗
6. MD Gan. Capturing and visualizing the phase transition mediated thermal stress of thermal barrier coating materials via a cross-scale integrated computational approach. 2024, 13: 413-428.10.26599/JAC.2024.9220864 ↗
7. YQ Guo. Mechanical properties and simulated thermal conductivity of biomimetic structured PS-PVD (Gd 0.9 Yb 0.1 ) 2 Zr 2 O 7 thermal barrier coatings. 2024, 182: 33-40.10.1016/j.jmst.2023.09.034 ↗
8. ZS Yang. Abnormal thermal expansion coefficients in (Nd 1– x Dy x ) 2 Zr 2 O 7 pyrochlore: The effect of low-lying optical phonons. 2023, 12: 1001-1014.10.26599/JAC.2023.9220734 ↗
9. L Chen. Rare-earth tantalates for next-generation thermal barrier coatings. 2024, 144: 101265.10.1016/j.pmatsci.2024.101265 ↗
10. GR Li. Tailoring sintering-resistant thermal barrier coatings by considering critical healing width of two-dimensional interlamellar pores. 2023, 12: 1317-1330.10.26599/JAC.2023.9220750 ↗
11. R Vaßen. Overview on advanced thermal barrier coatings. 2010, 205: 938-942.10.1016/j.surfcoat.2010.08.151 ↗
12. JK Wang. Evolutions of mechanical and thermal properties of TmNbO 4 /Tm 3 NbO 7 composites as protective coating materials. 2024, 13: 1771-1785.10.26599/JAC.2024.9220973 ↗
13. XF Wang. Mechanical properties and damage tolerance of bulk Yb 3 Al 5 O 12 ceramic. 2015, 31: 369-374.10.1016/j.jmst.2015.01.002 ↗
14. CJ Li. The correlation of the TBC lifetimes in burner cycling test with thermal gradient and furnace isothermal cycling test by TGO effects. 2017, 26: 378-387.10.1007/s11666-017-0530-0 ↗
15. ZY Wei. Progress in ceramic materials and structure design toward advanced thermal barrier coatings. 2022, 11: 985-1068.10.1007/s40145-022-0581-7 ↗
16. Z Lu. Thermal stability and mechanical properties of thick thermal barrier coatings with vertical type cracks. 2014, 24: s29-s35.10.1016/S1003-6326(14)63284-2 ↗
17. A Scrivani. Enhanced thick thermal barrier coatings that exhibit varying porosity. 2008, 476: 1-7.10.1016/j.msea.2007.04.035 ↗
18. HB Guo. Thermophysical properties and thermal cycling behavior of plasma sprayed thick thermal barrier coatings. 2005, 192: 48-56.10.1016/j.surfcoat.2004.02.004 ↗
19. HB Guo. Atmospheric plasma sprayed thick thermal barrier coatings with high segmentation crack density. 2004, 186: 353-363.10.1016/j.surfcoat.2004.01.002 ↗
20. M Izadinia. Effect of segmented cracks on TGO growth and life of thick thermal barrier coating under isothermal oxidation conditions. 2020, 46: 7475-7481.10.1016/j.ceramint.2019.11.245 ↗
21. G Mehboob. Strain-induced cracking behavior of coating/substrate systems and strain tolerant design for thick coatings. 2020, 10: 1066.10.3390/coatings10111066 ↗
22. SV Shinde. Segmentation crack formation dynamics during air plasma spraying of zirconia. 2020, 183: 196-206.10.1016/j.actamat.2019.10.052 ↗
23. P Jiang. Oxide growth in high-strain tolerance thermal barrier coating with segmented vertical cracks. 2024, 50: 25025-25033.10.1016/j.ceramint.2024.04.228 ↗
24. P Li. Comparative study on microstructure evolution and failure mechanisms of ordinary and refurbished EB-PVD TBC under cyclic oxidation. 2023, 12: 1805-1820.10.26599/JAC.2023.9220789 ↗
25. DY Hu. Characterization and mechanical modeling of interfacial damage in EB-PVD thermal barrier coatings considering multiple failure factors. 2024, 190: 42-55.10.1016/j.jmst.2023.12.018 ↗
26. M Karger. Atmospheric plasma sprayed thermal barrier coatings with high segmentation crack densities: Spraying process, microstructure and thermal cycling behavior. 2011, 206: 16-23.10.1016/j.surfcoat.2011.06.032 ↗
27. B Cheng. Sintering induced the failure behavior of dense vertically crack and lamellar structured TBCs with equivalent thermal insulation performance. 2017, 43: 15459-15465.10.1016/j.ceramint.2017.08.092 ↗
28. JX Wei. A bimodal-structured coating with columnar/lamellar trans-scale features for strain-tolerant and thermal insulative performances. 2026, 247: 29-43.10.1016/j.jmst.2025.04.062 ↗
29. R Kumar. Influence of microstructure on the durability of gadolinium zirconate thermal barrier coatings using APS & SPPS processes. 2018, 337: 117-125.10.1016/j.surfcoat.2018.01.004 ↗
30. A Rabiei. Failure mechanisms associated with the thermally grown oxide in plasma-sprayed thermal barrier coatings. 2000, 48: 3963-3976.10.1016/S1359-6454(00)00171-3 ↗
31. S Ahmadian. Explanation of the effect of rapid cycling on oxidation, rumpling, microcracking and lifetime of air plasma sprayed thermal barrier coatings. 2014, 244: 109-116.10.1016/j.surfcoat.2014.01.044 ↗
32. ZY Wei. Comprehensive dynamic failure mechanism of thermal barrier coatings based on a novel crack propagation and TGO growth coupling model. 2018, 44: 22556-22566.10.1016/j.ceramint.2018.09.028 ↗
33. XR Su. Region-function-matching design for YSZ-based thermal barrier coatings enables long thermal cyclic lifespan. 2024, 107: 8716-8731.10.1111/jace.20087 ↗
34. J Pyeon. Mechanisms of enhanced thermal durability in porosity-controlled multilayer thermal barrier coatings. 2025, 18: 917.10.3390/ma18050917 ↗
35. LQ Liu. Plasma sprayed thermal barrier coatings with outstanding ultrahigh temperature thermal shock resistances through gradient porosity level optimizations. 2025, 51: 17484-17491.10.1016/j.ceramint.2025.01.521 ↗
36. B Cheng. Prolong the durability of La 2 Zr 2 O 7 /YSZ TBCs by decreasing the cracking driving force in ceramic coatings. 2018, 38: 5482-5488.10.1016/j.jeurceramsoc.2018.08.033 ↗
37. ZL Xie. Durable GdTaO 4 /YSZ double-ceramic-layer thermal barrier coatings against ultrahigh-temperature thermal shock. 2025, 51: 29781-29791.10.1016/j.ceramint.2025.04.181 ↗
38. GL Liu. Achieving durable double-layered thermal barrier coatings by tailoring multi-scale structures. 2024, 13: 2068-2086.10.26599/JAC.2024.9221002 ↗
39. YM Wu. Design and evaluation of multilayer Yb 4 Hf 3 O 12 -based T/EBCs with enhanced thermal stability for high-temperature applications. 2025, 14: 9221139.10.26599/JAC.2025.9221139 ↗
40. AH Esmaeilkhanian. Thermal barrier coating with improved durability: An overview of doped, nanostructured, multilayered, and gradient-structured zirconia-based thermal barrier coatings. 2023, 37: 107514.10.1016/j.mtcomm.2023.107514 ↗
41. TJ Shi. Microstructural optimization of Gd 2 O 3 –Yb 2 O 3 –Y 2 O 3 co-stabilized ZrO 2 /YSZ coatings with enhanced thermal shock resistance. 2025, 254: 114142.10.1016/j.matdes.2025.114142 ↗
42. G Pedrizzetti. Influence of microstructural parameters on thermal cycling behavior of DVC-TBC systems. 2025, 499: 131881.10.1016/j.surfcoat.2025.131881 ↗
43. GR Li. Stiffening-resistant composite TBCs counteracting the substrate constraint effect during thermal exposure. 2024, 972: 172832.10.1016/j.jallcom.2023.172832 ↗
44. CJ Li. A novel plasma-sprayed durable thermal barrier coating with a well-bonded YSZ interlayer between porous YSZ and bond coat. 2012, 21: 383-390.10.1007/s11666-012-9771-0 ↗
45. GH Meng. Highly oxidation resistant MCrAlY bond coats prepared by heat treatment under low oxygen content. 2019, 368: 192-201.10.1016/j.surfcoat.2019.04.046 ↗
46. GR Li. A comprehensive sintering mechanism for TBCs—Part I: An overall evolution with two-stage kinetics. 2017, 100: 2176-2189.10.1111/jace.14784 ↗
47. GR Li. Dynamic-stiffening-induced aggravated cracking behavior driven by metal-substrate-constraint in a coating/substrate system. 2021, 65: 154-163.10.1016/j.jmst.2020.04.076 ↗
48. ZY Wei. Dynamic crack growth mechanism and lifetime assessment in plasma sprayed thermal barrier system upon temperature cycling. 2019, 45: 14896-14907.10.1016/j.ceramint.2019.04.223 ↗
49. B Cheng. Gradient thermal cyclic behaviour of La 2 Zr 2 O 7 /YSZ DCL-TBCs with equivalent thermal insulation performance. 2018, 38: 1888-1896.10.1016/j.jeurceramsoc.2017.10.058 ↗
50. LH Gao. Microstructure, thermal conductivity and thermal cycling behavior of thermal barrier coatings prepared by plasma spray physical vapor deposition. 2015, 276: 424-430.10.1016/j.surfcoat.2015.06.033 ↗
51. AF Renteria. Effect of morphology on thermal conductivity of EB-PVD PYSZ TBCs. 2006, 201: 2611-2620.10.1016/j.surfcoat.2006.05.003 ↗
52. HB Guo. Microstructures and properties of plasma-sprayed segmented thermal barrier coatings. 2006, 89: 1432-1439.10.1111/j.1551-2916.2005.00912.x ↗
53. H Dong. Effect of TGO thickness on thermal cyclic lifetime and failure mode of plasma-sprayed TBCs. 2014, 97: 1226-1232.10.1111/jace.12868 ↗
54. JQ Shi. Isothermal oxidation and TGO growth behavior of NiCoCrAlY–YSZ thermal barrier coatings on a Ni-based superalloy. 2020, 844: 156093.10.1016/j.jallcom.2020.156093 ↗
55. YZ Liu. Microstructural evolution at interfaces of thermal barrier coatings during isothermal oxidation. 2016, 36: 1765-1774.10.1016/j.jeurceramsoc.2016.02.011 ↗
56. AG Evans. Mechanisms controlling the durability of thermal barrier coatings. 2001, 46: 505-553.10.1016/S0079-6425(00)00020-7 ↗
57. LY Ni. Thermal cycling behavior of thermal barrier coatings with HVOF NiCrAlY bond coat. 2011, 20: 1133-1138.10.1007/s11666-011-9647-8 ↗
58. SS Yang. Achieving superior interfacial stability of the typical MCrAlY bond coat by microstructural regulation. 2026, 266: 115-126.10.1016/j.jmst.2025.12.006 ↗
59. M Shinozaki. A methodology, based on sintering-induced stiffening, for prediction of the spallation lifetime of plasma-sprayed coatings. 2013, 61: 579-588.10.1016/j.actamat.2012.09.079 ↗
60. GR Irwin. Fracture strength of relatively brittle structures and materials. 1970, 290: 513-521.10.1016/0016-0032(70)90234-6 ↗
61. K Xiong. Failure behaviors of EB-PVD thermal barrier coatings under isothermal oxidation and thermal cycling conditions. 2024, 478: 130439.10.1016/j.surfcoat.2024.130439 ↗
62. ZH Xu. Thermal cycling behavior of EB-PVD TBCs on CVD platinum modified aluminide coatings. 2015, 637: 226-233.10.1016/j.jallcom.2015.02.177 ↗
63. YH Sohn. Thermal cycling of EB-PVD/MCrAlY thermal barrier coatings: I. Microstructural development and spallation mechanisms. 2001, 146–147: 70-78.10.1016/S0257-8972(01)01478-5 ↗
64. N Kumar. Columnar thermal barrier coatings produced by different thermal spray processes. 2021, 30: 1437-1452.10.1007/s11666-021-01228-5 ↗
65. XF Zhang. Al 2 O 3 -modified PS-PVD 7YSZ thermal barrier coatings for advanced gas-turbine engines. 2020, 4: 31.10.1038/s41529-020-00134-5 ↗
66. A Thibblin. Influence of microstructure on thermal cycling lifetime and thermal insulation properties of yttria-stabilized zirconia thermal barrier coatings for diesel engine applications. 2018, 350: 1-11.10.1016/j.surfcoat.2018.07.005 ↗
67. Y Wang. Thermal shock resistance and mechanical properties of La 2 Ce 2 O 7 thermal barrier coatings with segmented structure. 2009, 35: 2639-2644.10.1016/j.ceramint.2009.02.025 ↗
68. HB Guo. Thermal cycling behavior of plasma sprayed segmented thermal barrier coatings. 2006, 47: 306-309.10.2320/matertrans.47.306 ↗
69. ZY Shen. Rare earth oxides stabilized La 2 Zr 2 O 7 TBCs: EB-PVD, thermal conductivity and thermal cycling life. 2019, 357: 427-432.10.1016/j.surfcoat.2018.10.045 ↗
70. ZY Shen. The thermal property and failure behaviors of SmErZrO thermal barrier coatings by EB-PVD. 2022, 25: 101543.10.1016/j.mtla.2022.101543 ↗
71. L Guo. Thermophysical properties of Yb 2 O 3 doped Gd 2 Zr 2 O 7 and thermal cycling durability of (Gd 0.9 Yb 0.1 ) 2 Zr 2 O 7 /YSZ thermal barrier coatings. 2014, 34: 1255-1263.10.1016/j.jeurceramsoc.2013.11.035 ↗
72. G Mehboob. Matching design of thickness ratio to extend the lifespan of double-layered thermal-barrier coatings. 2024, 50: 1505-1518.10.1016/j.ceramint.2023.10.241 ↗