journal article·2024-12Open access

Ultrafine-grained LaB 6–ZrB 2 composite ceramics with superior mechanical and thermionic emission properties prepared by high-pressure sintering

Xiaogang Guo, An Liu, Lingjuan Hao, Hang Zhou, Shuai Chen, Pan Ying, Bing Liu, Baozhong Li, Yufei Gao, Zhisheng Zhao, Ling Kong, Mengdong Ma, Xinyu Yang, Dongli Yu

Journal of Advanced Ceramics· Volume 13· Issue 12

Abstract

In this study, ultrafine-grained LaB6–ZrB2 composite ceramics were successfully synthesized by sintering a mixture of self-produced LaB6 nanopowder and commercial ZrB2 nanopowder under high pressure. Compared with their coarse-grained counterparts, ultrafine-grained ceramics exhibit improved mechanical properties. Notably, the ultrafine-grained LaB6–ZrB2 composite ceramic sintered at 4 GPa and 1673 K, with an average grain size of 286 nm, shows optimal mechanical performance characterized by a Vickers hardness of 25.6 GPa, a fracture toughness of 4.1 MPa·m1/2, and an elastic modulus of 338 GPa. Furthermore, the ultrafine-grained LaB6–ZrB2 composite ceramics displayed strong thermal emission, reaching a maximum current density of 27.5 A∙cm−2 at 1773 K. The structural and functional advantages of ultrafine-grained LaB6–ZrB2 composite ceramics render them suitable for potential use in thermionic emission cathodes.
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Research context

OpenAlex topics: Rare-earth and actinide compounds · Inorganic Chemistry and Materials · Boron and Carbon Nanomaterials Research

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