journal article·2012-12Open access

Dielectric composites with a high and temperature-independent dielectric constant

Xiaobing Shan, Lin Zhang, Xiqiao Yang, Z. -Y. Cheng

Journal of Advanced Ceramics· Volume 1· Issue 4

Abstract

Dielectric composites made using P(VDF-CTFE) 88/12 mol% as polymer matrix and both micro-sized and nano-sized CaCu3Ti4O12 (CCTO) particles as filler are developed. These composites exhibit high dielectric constant with a small dielectric loss. More importantly, it is found that the dielectric constant of these composites is almost independent of temperature from 25 °C to 125 °C. Comparing the composites made using micro-sized CCTO particles, the composites made using nano-sized CCTO particles exhibit a smaller dielectric loss. The dielectric properties of these composites indicate that the nano-sized CCTO particles have a smaller dielectric constant than the micro-sized CCTO particles.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Dielectric materials and actuators · Dielectric properties of ceramics · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Zhang L, Cheng ZY. Development of polymer-based 0-3 composites with high dielectric constant. J Adv Dielectrics 2011, 1: 389–406.10.1142/S2010135X11000574 ↗
2. Dang ZM, Yuan JK, Zha JW, et al. Fundamentals, processes and applications of high-permittivity polymer-matrix composites. Pro Mater Sci 2012, 57: 660–723.10.1016/j.pmatsci.2011.08.001 ↗
3. Sebastian MT, Jantunen H. Polymer-ceramic composites of 0–3 connectivity for circuits in electronics: A Review. Int J Appl Ceram Technol 2010, 7: 415–434.10.1111/j.1744-7402.2009.02482.x ↗
4. Dang ZM, Wang HY, Peng B, et al. Effect of BaTiO3 size on dielectric property of BaTiO3/PVDF composites. J Electroceram 2008, 21: 381–384.10.1007/s10832-007-9201-8 ↗
5. Kuo DH, Chang CC, Su TY, et al. Dielectric properties of three ceramic/epoxy composites. Mater Chem Phys 2004, 85: 201–206.10.1016/j.matchemphys.2004.01.003 ↗
6. Lam KH, Chan HLW, Luo HS, et al. Dielectric properties of 65PMN-35PT/P(VDF-TrFE) 0-3 composites. Microelectron Eng 2003, 66: 792–797.10.1016/S0167-9317(02)01001-8 ↗
7. Bai Y, Cheng ZY, Bharti V, et al. High dielectric constant ceramic powder polymer composites. Appl Phys Lett 2000, 76: 38043806.
8. Dong LJ, Xiong CX, Quan HY, et al. Polyvinyl-butyral/lead zirconate titanates composites with high dielectric constant and low dielectric loss. Scr Mater 2006, 55: 835–837.10.1016/j.scriptamat.2006.07.001 ↗
9. Adikary SU, Chan HLW, Choy CL, et al. Characterisation of proton irradiated Ba0.65Sr0.35TiO3/P(VDF-TrFE) ceramic-polymer composites. Compos Sci Technol 2002, 62: 2161–2167.10.1016/S0266-3538(02)00149-5 ↗
10. Cheng ZY, Katiyar RS, Yao X, et al. Temperature dependence of dielectric constant of relaxor ferroelectrics. Phys Rev B 1998, 57: 8166.10.1103/PhysRevB.57.8166 ↗
11. Cheng ZY, Zhang QM. Field actuated electroactive polymers. Mater Res Bull 2008, 33: 183–187.10.1557/mrs2008.43 ↗
12. Zhang QM, Bharti V, Zhao X. Giant electrostriction and relaxor ferroelectric behavior in electronirradiated poly (vinylidene fluoride-trifluoroethylene) copolymer. Science 1998, 280: 2101–2104.10.1126/science.280.5372.2101 ↗
13. Li ZM, Li SQ, Cheng ZY. Crystalline structure and transition behavior of recrystallized-irradiated P(VDF-TrFE) 65/35 copolymer. J Appl Phys 2005, 97: 014102.10.1063/1.1827918 ↗
14. Li ZM, Arbatti MD, Cheng ZY. Recrystallization study of high-energy-electron irradiated P(VDF-TrFE) 65/35 copolymer. Macromolecules 2004, 37: 79–85.10.1021/ma035251h ↗
15. Cheng ZY, Zhang QM, Bateman FB. Dielectric relaxation behavior and its relation to microstructure in relaxor ferroelectric polymers — high-energy electron irradiated P(VDF-TrFE) copolymer. J Appl Phys 2002, 92: 6749–6755.10.1063/1.1518130 ↗
16. Cheng ZY, Bharti V, Xu TB, et al. Electrostrictive poly (vinylidene fluoride-trifluoroethylene) copolymers. Sens Actuators A: Phys 2001, 90: 138–147.10.1016/S0924-4247(01)00496-4 ↗
17. Subramanian MA, Li D, Duan N, et al. High dielectric constant in ACu(3)Ti(4)O(12) and ACu(3)Ti(3)FeO(12) phases. J Solid State Chem 2000, 151: 323–325.10.1006/jssc.2000.8703 ↗
18. Homes CC, Vogt T, Shapiro SM, et al. Optical response of high-dielectric-constant perovskite-related oxide. Science 2001, 293: 673–676.10.1126/science.1061655 ↗
19. Subramanian MA, Sleight AW. ACu(3)Ti(4)O(12) and ACu(3)Ru(4)O(12) perovskites: High dielectric constants and valence degeneracy. Solid State Sci 2002, 4: 347–351.10.1016/S1293-2558(01)01262-6 ↗
20. Arbatti MD, Shan XB, Cheng ZY. Ceramic-polymer composites with high dielectric Constant. Adv Mater 2007, 19: 1369.10.1002/adma.200601996 ↗
21. Zhang L, Shan XB, Wu PX, et al. Dielectric characteristics of CaCu3Ti4O12/P(VDF-TrFE) nanocomposites. Appl Phys A 2012, 107: 597–602.10.1007/s00339-012-6836-3 ↗
22. Thomas P, Varughese KT, Dwarakanath K, et al. Dielectric properties of poly (vinylidene fluoride)/CaCu3Ti4O12 composites. Compos Sci Technol 2010, 70: 539–545.10.1016/j.compscitech.2009.12.014 ↗
23. Amaral F, Rubinger CPL, Henry F, et al. Dielectric properties of polystyrene-CCTO composite. J Non-Cryst Sol 2008, 354: 5321–5322.10.1016/j.jnoncrysol.2008.05.056 ↗
24. Dang ZM, Zhou T, Yao SH, et al. Advanced calcium copper titanate/polyimide functional hybrid films with high dielectric permittivity. Adv Mater 2009, 21: 2077–2082.10.1002/adma.200803427 ↗
25. Li ZM. Novel electroactive poly (vinylidene fluoride)-based polymer systems and their applications. Ph.D. Dissertation. Auburn University, 2004.
26. Li ZM, Wang YH, Cheng ZY. Electromechanical properties of poly (vinylidene-fluoridechlorotrifluoroethylene) copolymer. Appl Phys Lett 2006, 88: 062904.10.1063/1.2170425 ↗
27. Chu BJ, Zhou X, Ren KL, et al. A dielectric polymer with high electric energy density and fast discharge speed. Science 2006, 313: 334–336.10.1126/science.1127798 ↗
28. Li JJ. Nanocomposites based on ferroelectric polymers for electrical energy storage Ph. D. Dissertation. Penn State University, 2009.10.1021/bk-2010-1034.ch004 ↗
29. Wang Q, Zhu L. Polymer nanocomposites for electrical energy storage. J Polym Sci 2011, B49: 1421–1429.10.1002/polb.22337 ↗
30. Xia WM, Xu Z, Wen F, et al. Electrical energy density and dielectric properties of poly (vinylidene fluoride-chlorotrifluoroethylene)/BaSrTiO3 nanocomposites. Ceram Int 2012, 38: 1071–1075.10.1016/j.ceramint.2011.08.033 ↗