journal article·1999-01

Phase separation process during solution casting of acrylate-copolymer/fluoro-copolymer blends

Yoshihisa Kano, Harumi Sato, Masami Okamoto, Tadao Kotaka, S. Akiyama

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Abstract

For the P(2EHA-AA-VAc)/P(VDF-HFA)/THF ternary system, the phase separation process during solution casting was examined via Rayleigh scattering measurement. The scattered intensity of the scattering vector q at various times for the P(2EHA-AA-VAc)/P(VDF-HFA) 30/70 blend having a gradient domain morphology revealed that the gradient structure formed according to both spinodal decomposition (SD) and nucleation growth (NG) mechanisms.
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Research context

OpenAlex topics: Polymer crystallization and properties · Block Copolymer Self-Assembly · Polymer Nanocomposites and Properties

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