journal article·2013-01

Iron Particle Nanodrilling of Few Layer Graphene at Low Electron Beam Accelerating Voltages

Jessica Campos‐Delgado, Daniel L. Baptista, Miguel Fuentes‐Cabrera, Bobby G. Sumpter, Vincent Meunier, Humberto Terrones, Yoong Ahm Kim, Hiroyuki Muramatsu, Takuya Hayashi, Morinobu Endo, Mauricio Terrones, Carlos A. Achete

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Abstract

Atomic vacancies in graphene are created under relatively low energy electron bombardment, but the formation of vacancies is significanlty enhanced by iron nanocatalysis. The evolution of the overall process involves nanoparticle agglomeration, interlayer migration, and confinement to nearby defects. The catalytic activation of metal nanoparticles via elecron irradiation on graphene-like surfaces appears to be a novel process that can be used to obtain porous graphene sheets with high surface areas. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Research context

OpenAlex topics: Graphene research and applications · Advancements in Battery Materials · Ion-surface interactions and analysis

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References (52)

Show source-provided references
1. 10.1016/0009-2614(86)80661-310.1016/0009-2614(86)80661-3 ↗
2. 10.1103/PhysRevLett.81.143710.1103/PhysRevLett.81.1437 ↗
3. 10.1103/PhysRevB.57.R427710.1103/PhysRevB.57.R4277 ↗
4. 10.1038/nature0281710.1038/nature02817 ↗
5. 10.1021/nl801386m10.1021/nl801386m ↗
6. 10.1126/science.116699910.1126/science.1166999 ↗
7. 10.1088/1367-2630/11/8/08301910.1088/1367-2630/11/8/083019 ↗
8. 10.1038/nnano.2009.19410.1038/nnano.2009.194 ↗
9. 10.1103/PhysRevLett.102.20550110.1103/PhysRevLett.102.205501 ↗
10. 10.1103/PhysRevLett.105.04550110.1103/PhysRevLett.105.045501 ↗
11. 10.1073/pnas.111982710910.1073/pnas.1119827109 ↗
12. 10.1021/nl080583r10.1021/nl080583r ↗
13. 10.1021/nl900811r10.1021/nl900811r ↗
14. 10.1002/adma.20090094210.1002/adma.200900942 ↗
15. 10.1021/nl901631z10.1021/nl901631z ↗
16. 10.1021/nl803450910.1021/nl8034509 ↗
17. 10.1021/nl200928k10.1021/nl200928k ↗
18. 10.1021/nn103035y10.1021/nn103035y ↗
19. 10.1016/j.carbon.2011.09.02610.1016/j.carbon.2011.09.026 ↗
20. 10.1007/s12274-009-9073-010.1007/s12274-009-9073-0 ↗
21. 10.1021/nn100356q10.1021/nn100356q ↗
22. 10.1103/PhysRevLett.102.12680710.1103/PhysRevLett.102.126807 ↗
23. 10.1021/nn300452y10.1021/nn300452y ↗
24. 10.1021/jz201653g10.1021/jz201653g ↗
25. 10.1021/nl300985q10.1021/nl300985q ↗
26. 10.1038/nnano.2010.810.1038/nnano.2010.8 ↗
27. 10.1126/science.120077010.1126/science.1200770 ↗
28. 10.1021/ja205693t10.1021/ja205693t ↗
29. 10.1016/j.cplett.2008.12.08210.1016/j.cplett.2008.12.082 ↗
30. 10.1103/PhysRevLett.102.01550110.1103/PhysRevLett.102.015501 ↗
31. 10.1103/PhysRevLett.105.19610210.1103/PhysRevLett.105.196102 ↗
32. The comparison values were taken from: 1) a sequence shown in ref. [8] we measured the area of the shown images in Figure 2a–d; and 2) the first regime in the plot in Figure 4D extracted from ref. [6] both reports use 80 kV during TEM observation.
33. 10.1016/j.actamat.2005.09.03410.1016/j.actamat.2005.09.034 ↗
34. 10.1021/nn201825410.1021/nn2018254 ↗
35. 10.1103/PhysRevE.83.04160310.1103/PhysRevE.83.041603 ↗
36. 10.1038/nmat199610.1038/nmat1996 ↗
37. 10.1016/j.micron.2004.02.00310.1016/j.micron.2004.02.003 ↗
38. According to ref. [36] the energy to displace carbon atoms in a sp2configuration is between 15 and 20 eV. Using the formula given in ref. [37] to find the minimum value of incident energy E0to displace a carbon atom: Eth= E0(1.02+E0/106)/465.7×12 for an Ethof 15 eV the obtained value of E0is ≈76 keV.
39. 10.1038/nmat306410.1038/nmat3064 ↗
40. 10.1016/S0040-6031(00)00540-210.1016/S0040-6031(00)00540-2 ↗
41. 10.1147/rd.42.013010.1147/rd.42.0130 ↗
42. 10.1021/nl801316d10.1021/nl801316d ↗
43. 10.1016/j.susc.2007.08.01410.1016/j.susc.2007.08.014 ↗
44. 10.1016/0927-0256(96)00008-010.1016/0927-0256(96)00008-0 ↗
45. 10.1103/PhysRevB.54.1116910.1103/PhysRevB.54.11169 ↗
46. 10.1103/PhysRevB.50.1795310.1103/PhysRevB.50.17953 ↗
47. 10.1103/PhysRevB.59.175810.1103/PhysRevB.59.1758 ↗
48. 10.1103/PhysRevLett.45.56610.1103/PhysRevLett.45.566 ↗
49. 10.1103/PhysRevB.43.199310.1103/PhysRevB.43.1993 ↗
50. 10.1103/PhysRevLett.77.386510.1103/PhysRevLett.77.3865 ↗
51. 10.1063/1.44733410.1063/1.447334 ↗
52. 10.1006/jcph.1995.103910.1006/jcph.1995.1039 ↗