Cathodic delamination of polybutadiene from steel-A review
Source abstract
Abstract
The variables influencing the rate of the cathodic delamination of polybutadiene from steel in alkali halide solutions are discussed. The bond at the interface arises from the reaction of carboxyl groups in the polybutadiene with hydroxyl groups on the surface of the iron oxide at the interface. It is this bond that is broken by hydroxyl ions generated by the oxygen reduction reaction beneath the coating. The rate controlling step is the rate of charge transfer through the coating to support the oxygen reduction reaction.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: High voltage insulation and dielectric phenomena · Concrete Corrosion and Durability · Infrastructure Maintenance and Monitoring
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (32)
Show source-provided references
1. Touhsaent R. E. · Corrosion · 1972 · 28 · 43510.5006/0010-9312-28.12.435 ↗
2. Leidheiser, H. Jr. and Wang, W. 1981.Corrosion Control by Organic Coatings, 38Houston, Texas: Natl. Assoc. Corrosion Engrs.
3. Wang, W. and Leidheiser, H. Jr. October 21–26.Proc. 11th World Congr. Metal FinishingOctober 21–26, 262–269. Jerusalem
4. Parks J. · 1985
5. Leidheiser H. · Prog. Organic Coatings · 1983 · 11 · 1910.1016/0033-0655(83)80002-8 ↗
6. Leidheiser H. · J. Coatings Tech. · 1981 · 53 · 77
7. Catino J. · 1985
8. Leidheiser H. · J. Coatings Tech. · 1984 · 56 · 55
9. Atkinson J. M. · IBM J. Res. Dev · 1985 · 29 · 2710.1147/rd.291.0027 ↗
10. Leidheiser H. · Corrosion · 1976 · 32 · 6910.5006/0010-9312-32.2.69 ↗
11. Beard B. · J. Phys. Chem.
12. Leidheiser, H. Jr. unpublished work
13. Iezzi R. A. · Corrosion · 1981 · 37 · 2810.5006/1.3593835 ↗
14. Simmons G. W.
15. Rommal H. E. G. · 1985
16. Bilder, W. Lehigh University. unpublished work
17. Mills, D. J. Lehigh University. unpublished work
18. Mayne J. E. O. · J. Oil Colour Chem. Assoc. · 1975 · 58 · 155
19. Dickie R. A. · Ind. Eng. Chem. Prod. Res. Dev · 1984 · 23 · 29710.1021/i300014a025 ↗
20. Leidheiser H. · Nature · 1982 · 297 · 66710.1038/297667a0 ↗
21. Deck P. · 1986
22. Dickie R. A. · Ind. Eng. Chem. Prod. Res. Dev. 20 · 1981 · 339
23. Castle, J. E. and Watts, J. F. 1981.Corroson Control by Organic Coatings, Edited by: Leidheiser, H. Jr. 78Houston, Texas: Natl. Assoc. Corrosion Engrs.
24. Ritter, J. J. and Kruger, J. 1981.Corrosion Control by Organic Coatings, Edited by: Leidheiser, H. Jr. 28Houston, Texas: Natl. Assoc. Corrosion Engrs.
25. Rodriguez V. · 1985
26. Watts J. F. · J. Mat. Sci. · 1983 · 18 · 298710.1007/BF00700781 ↗
27. Funke W. · Ind. Eng. Chem. Prod. Res. Dev · 1978 · 17 · 5010.1021/i360065a014 ↗
28. Parks J. · Ind. Eng. Chem. Prod. Res. Dev. · 1986 · 25 · 110.1021/i300021a001 ↗
29. Leidheiser H. · J. Electrochem. Soc.
30. De Crosta M. · Corrosion.
31. Granata, R. D., De Crosta, M. A. and Leidheiser, H. Jr. 1984.Proc. Intern. Cong. Metallic Corrosion264–268. Toronto, Canada
32. Leidheiser H. · Corrosion Sci. · 1984 · 24 · 19710.1016/0010-938X(84)90050-7 ↗