journal article·2014-04

Cesium carbonate-doped 1,4,5,8-naphthalene-tetracarboxylic-dianhydride used as efficient electron transport material in polymer solar cells

A. Barbot, B. Lucas, C. Di Bin, B. Ratier

Organic Electronics· Volume 15· Issue 4
Publisher page

Abstract

The use of appropriate charge carrier transport materials in organic solar cells strongly influences the device performance. In this work, we focused on the molecular electron transport material 1,4,5,8-naphthalene-tetracarboxylic-dianhydride (NTCDA) doped by cesium carbonate (Cs2CO3). We first investigated the electrical properties of such n-type doped material as a function of the doping concentration before using it as electron transport layer (ETL) in polymer solar cells. The doped transparent ETL reduces the series resistance leading to an increased open circuit voltage. A power conversion efficiency of 3.8% was finally achieved in a device with a blend of poly(3-hexylthiophene-2,5-diyl): phenyl-C61-butyric acid methyl ester (P3HT:PCBM) as the active layer and a 5 nm-thick NTCDA: Cs2CO3 film with a molar ratio of 30% as ETL.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Organic Light-Emitting Diodes Research · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. “Heliatek consolidates its technology leadership by establishing a new world record for organic solar technology with a cell efficiency of 12%,” Press Release by Heliatek, “Heliatek Consol. Its Technol. Leadersh. by Establ. a New World Rec. Org. Sol. Technol. with a Cell Effic. 12%”, January 16 (2013).
2. Controlled p-doping of zinc phthalocyanine by coevaporation with tetrafluorotetracyanoquinodimethane: a direct and inverse photoemission study10.1063/1.1424067 ↗
3. Electronic structure and current injection in zinc phthalocyanine doped with tetrafluorotetracyanoquinodimethane :interface versus bulk effects10.1016/S1566-1199(02)00033-2 ↗
4. Organic Mip-diodes by p-doping of amorphous wide-gap semiconductors CV and impedance spectroscopy10.1016/S0379-6779(01)00623-3 ↗
5. Doping mechanism and electronic structure of alkali metal doped tris(8-hydroxyquinoline) aluminum10.1021/jp2102918 ↗
6. N-type doping of organic thin films using cationic dyes10.1002/adfm.200305053 ↗
7. Pyronin B as a donor for n-type doping of organic thin films10.1063/1.1583872 ↗
8. Thermoelectric properties of n-type C60 thin films and their application in organic thermovoltaic devices10.1063/1.3631633 ↗
9. N-type doping and thermoelectric properties of co-sublimed cesium-carbonate-doped fullerene10.1007/s10853-012-6824-1 ↗
10. Mechanism of Cs2CO3 as an n-type dopant in organic electron-transport film10.1063/1.3567526 ↗
11. Low-work-function surface formed by solution-processed and thermally deposited nanoscale layers of cesium carbonate10.1002/adfm.200700051 ↗
12. Cesium carbonate as a functional interlayer for polymer photovoltaic devices10.1063/1.2937202 ↗
13. Effect of cathode buffer layer on the stability of polymer bulk heterojunction solar cells10.1016/j.solmat.2010.05.043 ↗
14. Highly efficient inverted poly(3-hexylthiophene):methano-fullerene [6,6]-phenyl C71-butyric acid methyl ester bulk heterojunction solar cell with Cs2CO3 and MoO310.1016/j.orgel.2010.11.024 ↗
15. Efficient inverted polymer solar cells10.1063/1.2212270 ↗
16. Highly efficient organic devices based on electrically doped transport layers10.1021/cr050156n ↗
17. Doping of organic semiconductors10.1002/pssa.201228310 ↗
18. Efficient organic solar cells based on a double p-i-n architecture using doped wide-gap transport layers10.1063/1.1935771 ↗
19. Efficient p-i-n type organic solar cells incorporating 1,4,5,8-naphthalenetetracarboxylic dianhydride as transparent electron transport material10.1063/1.2963992 ↗
20. Efficient inverted polymer solar cells incorporating doped organic electron transporting layer10.1016/j.orgel.2012.01.009 ↗
21. Optimized inverted polymer solar cells incorporating Cs2CO3-doped C60 as electron transport layer Optimized inverted polymer solar cells incorporating Cs2CO3 -doped C60 as electron transport layer10.1063/1.4807388 ↗
22. Inverted polymer solar cells integrated with a low-temperature-annealed sol–gel-derived ZnO Film as an electron transport layer10.1002/adma.201004301 ↗
23. Air-stable inverted flexible polymer solar cells using zinc oxide nanoparticles as an electron selective layer10.1063/1.2945281 ↗
24. New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer10.1002/adma.200501825 ↗
25. Titanium suboxide as an optical spacer in polymer solar cells10.1063/1.3159622 ↗
26. Torsi · NTCDA organic thin- film-transistor as humidity sensor:weaknesses and strengths · 2001 · 77 · 7
27. Highly efficient inverted polymer solar cell by low temperature annealing of Cs2CO3 interlayer10.1063/1.2918983 ↗
28. Thermal-annealing-free inverted polymer solar cells using ZnO/Cs2CO3 bilayer as electron-selective layer10.1016/j.solmat.2012.04.022 ↗
29. Electron injection mechanisms of green organic light-emitting devices fabricated utilizing a double electron injection layer consisting of cesium carbonate and fullerene10.1016/j.tsf.2010.04.061 ↗
30. Controlled n-type doping of a molecular organic semiconductor: naphthalenetetracarboxylic dianhydride (NTCDA) doped with bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF)10.1063/1.373413 ↗
31. Grain size dependent mobility in polycrystalline organic field-effect transistors10.1016/S0379-6779(00)01351-5 ↗
32. Elliott · 1983
33. A general expression for the thermoelectric power10.1016/0038-1098(71)90096-2 ↗
34. Doping dependent conductivity in organic semiconductors
35. Organic solar cells: problems and perspectives10.1155/2010/123534 ↗
36. Cathode dependence of the open-circuit voltage of polymer:fullerene bulk heterojunction solar cells10.1063/1.1620683 ↗
37. On the pseudo-symmetric current–voltage response of bulk heterojunction solar cells10.1039/b718563d ↗
38. On the origin of the open-circuit voltage of polymer–fullerene solar cells10.1038/nmat2548 ↗
39. Analytical model for the open-circuit voltage and its associated resistance in organic planar heterojunction solar cells10.1103/PhysRevB.77.165332 ↗
40. Work function of indium tin oxide transparent conductor measured by photoelectron spectroscopy10.1063/1.116313 ↗
41. Direct determination of the electronic structure of the poly(3-hexylthiophene):phenyl-[6,6]-C61 butyric acid methyl ester blend10.1016/j.orgel.2010.07.023 ↗
42. Conductivity, work function, and environmental stability of PEDOT:PSS thin films treated with sorbitol10.1016/j.orgel.2008.05.006 ↗