Fluorescent film sensor for nitroaromatics via monolayer assembly of arylethenyl-branched s-triazine on glass slide surfaces

Abstract A fluorescent compound, arylethenyl-branched s -triazine ( II ), is synthesized. It can be immobilized onto the glass surface with the molecule plane parallel to the surface, decreasing the π–π stacking between molecules on glass surface. Measurements of contact angle to water, XPS spectra and light absorbance of the functionalized glass confirm the success of grafting II onto the surface of the glass. The quenching efficiency of this sensor reaches 68.7% and 89.3% when C DNT in THF is 2 × 10 − 5 and 2 × 10 − 3 mol/L, respectively. From recycle 2–10, the recovered fluorescence intensity of the glass sensor remains between 72.4% and 58.0% of the original emission intensity, which implies good reversibility of the quenching process. The quenching efficiency of the glass sensor reaches 95% immediately once upon it is exposed to saturated DNT vapor, showing no time delay to get to the quenching equilibrium.