journal article·2018-06-04Open access

Observation of a topological insulator Dirac cone reshaped by non-magnetic impurity resonance

Lin Miao, Yishuai Xu, Wenhan Zhang, Daniel Older, S. Alexander Breitweiser, Erica Kotta, Haowei He, Takehito Suzuki, Jonathan D. Denlinger, Rudro R. Biswas, Joseph G. Checkelsky, Weida Wu, L. Andrew Wray

npj Quantum Materials· Volume 3· Issue 1

Abstract

Abstract The massless Dirac electrons found at topological insulator surfaces are thought to be influenced very little by weak, non-magnetic disorder. However, a resonance effect of strongly perturbing non-magnetic impurities has been theoretically predicted to change the dispersion and physical nature of low-energy quasiparticles, resulting in unique particle-like states that lack microscopic translational symmetry. Here we report the direct observation of impurities reshaping the surface Dirac cone of the model three-dimensional topological insulator bismuth selenide. A pronounced kink-like dispersion feature is observed in disorder-enriched samples, and found to be closely associated with the anomaly caused by impurity resonance in the surface state density of states, as observed by dichroic angle-resolved photoemission spectroscopy. The experimental observation of these features, which closely resemble theoretical predictions, has significant implications for the properties of topological Dirac cones in applied scenarios that commonly feature point-defect disorder at surfaces or interfaces.
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Research context

OpenAlex topics: Topological Materials and Phenomena · Quantum optics and atomic interactions · Photorefractive and Nonlinear Optics

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References (47)

Show source-provided references
1. Hasan, M. Z. & Kane, C. L. Colloquium: topological insulators. Rev. Mod. Phys. 82, 3045 (2010).10.1103/RevModPhys.82.3045 ↗
2. Qi, X.-L. & Zhang, S.-C. Topological insulators and superconductors. Rev. Mod. Phys. 83, 1057 (2011).10.1103/RevModPhys.83.1057 ↗
3. Fu, L., Kane, C. L. & Mele, E. J. Topological insulators in three dimensions. Phys. Rev. Lett. 98, 106803 (2007).10.1103/PhysRevLett.98.106803 ↗
4. Zhang, H. et al. Topological insulators in Bi2Se3, Bi2Te3 and Sb2Te3 with a single Dirac cone on the surface. Nat. Phys. 5, 438–442 (2009).10.1038/nphys1270 ↗
5. Xia, Y. et al. Observation of a large-gap topological-insulator class with a single Dirac cone on the surface. Nat. Phys. 5, 398–402 (2009).10.1038/nphys1274 ↗
6. Chen, Y. L. et al. Experimental realization of a three-dimensional topological insulator, Bi2Te3. Science 325, 178–181 (2009).10.1126/science.1173034 ↗
7. Qi, X.-L., Li, R., Zang, J. & Zhang, S.-C. Inducing a magnetic monopole with topological surface states. Science 323, 1184–1187 (2009).10.1126/science.1167747 ↗
8. Yu, R. et al. Quantized anomalous Hall effect in magnetic topological insulators. Science 329, 61–64 (2010).10.1126/science.1187485 ↗
9. Chang, C.-Z. et al. Experimental observation of the quantum anomalous Hall effect in a magnetic topological insulator. Science 340, 167–170 (2013).10.1126/science.1234414 ↗
10. Fu, L. & Kane, C. L. Superconducting proximity effect and Majorana fermions at the surface of a topological insulator. Phys. Rev. Lett. 100, 096407 (2008).10.1103/PhysRevLett.100.096407 ↗
11. Hsieh, D. et al. Observation of unconventional quantum spin textures in topological insulators. Science 323, 919–922 (2009).10.1126/science.1167733 ↗
12. Fu, L. & Kane, C. L. Topology, delocalization via average symmetry and the symplectic Anderson transition. Phys. Rev. Lett. 109, 246605 (2012).10.1103/PhysRevLett.109.246605 ↗
13. Roushan, P. et al. Topological surface states protected from backscattering by chiral spin texture. Nature 460, 1106–1109 (2009).10.1038/nature08308 ↗
14. Zhang, T. et al. Experimental demonstration of topological surface states protected by time-reversal symmetry. Phys. Rev. Lett. 103, 266803 (2009).10.1103/PhysRevLett.103.266803 ↗
15. Alpichshev, Z. et al. STM imaging of electronic waves on the surface of Bi2Te3: topologically protected surface states and hexagonal warping effects. Phys. Rev. Lett. 104, 016401 (2010).10.1103/PhysRevLett.104.016401 ↗
16. Beidenkopf, H. et al. Spatial fluctuations of helical Dirac fermions on the surface of topological insulators. Nat. Phys. 7, 939–943 (2011).10.1038/nphys2108 ↗
17. Hsieh, D. et al. A tunable topological insulator in the spin helical Dirac transport regime. Nature 460, 1101–1105 (2009).10.1038/nature08234 ↗
18. Wray, L. A. et al. Observation of topological order in a superconducting doped topological insulator. Nat. Phys. 6, 855859 (2010).10.1038/nphys1762 ↗
19. Valla, T., Pan, Z.-H., Gardner, D., Lee, Y. S. & Chu, S. Photoemission spectroscopy of magnetic and non-magnetic impurities on the surface of the Bi2Se3 topological insulator. Phys. Rev. Lett. 108, 117601 (2012).10.1103/PhysRevLett.108.117601 ↗
20. Alpichshev, Z. et al. STM imaging of impurity resonances on Bi2Se3. Phys. Rev. Lett. 108, 206402 (2012).10.1103/PhysRevLett.108.206402 ↗
21. Teague, M. L. et al. Observation of Fermi-energy dependent unitary impurity resonances in a strong topological insulator Bi2Se3 with scanning tunneling spectroscopy. Solid State Commun. 152, 747–751 (2012).10.1016/j.ssc.2012.01.041 ↗
22. Ugeda, M. M., Brihuega, I., Guinea, F. & GomezRodriguez, J. M. Missing atom as a source of carbon magnetism. Phys. Rev. Lett. 104, 096804 (2010).10.1103/PhysRevLett.104.096804 ↗
23. Wehling, T. O. et al. Local electronic signatures of impurity states in grapheme. Phys. Rev. B 75, 125425 (2007).10.1103/PhysRevB.75.125425 ↗
24. Biswas, R. R. & Balatsky, A. V. Impurity-induced states on the surface of three-dimensional topological insulators. Phys. Rev. B 81, 233405 (2010).10.1103/PhysRevB.81.233405 ↗
25. Black-Schaffer, A. M. & Balatsky, A. V. Subsurface impurities and vacancies in a three-dimensional topological insulator. Phys. Rev. B 86, 115433 (2012).10.1103/PhysRevB.86.115433 ↗
26. Black-Schaffer, A. M. & Balatsky, A. V. Strong potential impurities on the surface of a topological insulator. Phys. Rev. B 85, 121103(R) (2012).10.1103/PhysRevB.85.121103 ↗
27. Black-Schaffer, A. M. & Yudin, D. Spontaneous gap generation on the surface of weakly interacting topological insulators using non-magnetic impurities. Phys. Rev. B 90, 161413(R) (2014).10.1103/PhysRevB.90.161413 ↗
28. Xu, Y. et al. Disorder enabled band structure engineering of a topological insulator surface. Nat. Commun. 8, 14801 (2017).10.1038/ncomms14801 ↗
29. Zhong, M. et al. Effect of impurity resonant states on optical and thermoelectric properties on the surface of a topological insulator. Sci. Rep. 7, 3971 (2017).10.1038/s41598-017-04360-x ↗
30. Thouless, D. J. Electrons in disordered systems and the theory of localization. Phys. Rep. 13C, 93–142 (1974).10.1016/0370-1573(74)90029-5 ↗
31. Petrushevsky, M. et al. Probing the surface states in Bi2Se3 using the Shubnikov–de Haas effect. Phys. Rev. B 86, 045131(R) (2012).10.1103/PhysRevB.86.045131 ↗
32. Dai, J. et al. Toward the intrinsic limit of the topological insulator Bi2Se3. Phys. Rev. Lett. 117, 106401 (2016).10.1103/PhysRevLett.117.106401 ↗
33. Wray., L. A. et al. Spin-orbital ground states of superconducting doped topological insulators: a Majorana platform. Phys. Rev. B 83, 224516 (2011).10.1103/PhysRevB.83.224516 ↗
34. Xue, L. et al. First-principles study of native point defects in Bi2Se3. AIP Adv. 3, 052105 (2013).10.1063/1.4804439 ↗
35. Li, H. D. et al. The van der Waals epitaxy of Bi2Se3 on the vicinal Si(111) surface: an approach for preparing high-quality thin films of a topological insulator. N. J. Phys. 12, 103038 (2010).10.1088/1367-2630/12/10/103038 ↗
36. Luttinger, J. M. & Ward, J. C. Ground-state energy of a many-fermion system. II. Phys. Rev. 118, 1417–1427 (1960).10.1103/PhysRev.118.1417 ↗
37. Luttinger, J. M. Fermi surface and some simple equilibrium properties of a system of interacting fermions. Phys. Rev. 119, 1153–1163 (1960).10.1103/PhysRev.119.1153 ↗
38. Cao, Y. et al. Mapping the orbital wavefunction of the surface states in three-dimensional topological insulators. Nat. Phys. 9, 499–504 (2013).10.1038/nphys2685 ↗
39. Wray, L. A. et al. Chemically gated electronic structure of a superconducting doped topological insulator system. J. Phys. Conf. Ser. 449, 012037 (2013).10.1088/1742-6596/449/1/012037 ↗
40. Frantzeskakis, E. et al. Trigger of the ubiquitous surface band bending in 3D topological insulators. Phys. Rev. X 7, 041041 (2017).
41. Kordyuk, A. A. et al. Photoemission-induced gating of topological insulators. Phys. Rev. B 83, 081303 (2011).10.1103/PhysRevB.83.081303 ↗
42. Wray, L. A. et al. A topological insulator surface under strong Coulomb, magnetic and disorder perturbations. Nat. Phys. 7, 32–37 (2011).10.1038/nphys1838 ↗
43. Bianchi, M. et al. Coexistence of the topological state and a two-dimensional electron gas on the surface of Bi2Se3. Nat. Commun. 1, 128 (2010).10.1038/ncomms1131 ↗
44. Benia, H. M., Lin, C., Kern, K. & Ast, C. R. Reactive chemical doping of the Bi2Se3 topological insulator. Phys. Rev. Lett. 107, 177602 (2011).10.1103/PhysRevLett.107.177602 ↗
45. Bahramy, M. S. et al. Emergent quantum confinement at topological insulator surfaces. Nat. Commun. 3, 1159 (2012).10.1038/ncomms2162 ↗
46. Chen, C. et al. Robustness of topological order and formation of quantum well states in topological insulators exposed to ambient environment. Proc. Natl. Acad. Sci. USA 109, 3694 (2012).10.1073/pnas.1115555109 ↗
47. Jiang, R. et al. Reversible tuning of the surface state in a pseudobinary Bi2(Te-Se)3 topological insulator. Phys. Rev. B 86, 085112 (2012).10.1103/PhysRevB.86.085112 ↗