journal article·2025-07-24Open access

Nanostructured NiCoFeCr alloy with superior high-temperature irradiation resistance

Sri Tapaswi Nori, Pedro A. Ferreirós, Damian Kalita, Ruben Bjørge, Per Erik Vullum, Katarzyna Mulewska, Witold Chrominski, Mingyang Li, Yongqin Chang, Yanwen Zhang, Randi Holmestad, Lukasz Kurpaska

npj Materials Degradation· Volume 9· Issue 1

Abstract

Abstract The current research utilized a unique material design of nanostructured medium-entropy alloys with numerous defect sinks, offering great potential to withstand extreme conditions in advanced nuclear reactors. Hence, this work examined oxide dispersion strengthened (ODS)-NiCoFeCr alloy with nanosized grains after Ni+2 irradiation at 580 °C up to a peak damage of 101 displacements per atom. The alloy showed insignificant hardening and no detectable void formation following irradiation. Also, oxide nanoprecipitates and grains exhibited a limited growth of ~2 and ~5 nm, respectively, with irradiation. The volume-averaged dislocation length density remained on the order of ~1014 m−2, and the mean dislocation length showed a slight increase from 89 to 97 nm, with irradiation. A lower level of radiation-induced segregation was observed at the grain boundaries; however, the extent of RIS depended on the misorientation angles, with a maximum at 45.7° among the grain boundaries analyzed.
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Research context

OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Fusion materials and technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (65)

Show source-provided references
1. Zhang, Y., Osetsky, Y. N. & Weber, W. J. Tunable chemical disorder in concentrated alloys: defect physics and radiation performance. Chem. Rev. 122, 789–829 (2022).10.1021/acs.chemrev.1c00387 ↗
2. Yeh, J. W. et al. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299–303 (2004).10.1002/adem.200300567 ↗
3. Ye, Y. F., Wang, Q., Lu, J., Liu, C. T. & Yang, Y. High-entropy alloy: challenges and prospects. Mater. Today 19, https://doi.org/10.1016/j.mattod.2015.11.026 (2016).10.1016/j.mattod.2015.11.026 ↗
4. Zhang, Y., et al. Microstructures and properties of high-entropy alloys. Prog. Mater. Sci. 61, 1–93 (2014).10.1016/j.pmatsci.2013.10.001 ↗
5. Levo, E., Granberg, F., Fridlund, C., Nordlund, K. & Djurabekova, F. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys. J. Nucl. Mater. 490, 323–332 (2017).10.1016/j.jnucmat.2017.04.023 ↗
6. Yang, L. et al. Deformation mechanisms in single crystal Ni-based concentrated solid solution alloys by nanoindentation. Mater. Sci. Eng. A 856, 143685 (2022).10.1016/j.msea.2022.143685 ↗
7. Lach, T. G. et al. Dynamic substrate reactions during room temperature heavy ion irradiation of CoCrCuFeNi high entropy alloy thin films. npj Mater. Degrad. 6, 60 (2022).10.1038/s41529-022-00260-2 ↗
8. Pickering, E. J. et al. High-entropy alloys for advanced nuclear applications. Entropy 23, 1–28 (2021).10.3390/e23010098 ↗
9. Aguiar, J. A., Jokisaari, A. M., Kerr, M. & Allen Roach, R. Bringing nuclear materials discovery and qualification into the 21st century. Nat. Commun. 11, https://doi.org/10.1038/s41467-020-16406-2 (2020).10.1038/s41467-020-16406-2 ↗
10. Zhang, Y. Reassembled nanoprecipitates resisting radiation. Nat. Mater. 22, https://doi.org/10.1038/s41563-022-01283-5 (2023).10.1038/s41563-022-01283-5 ↗
11. Zinkle, S. J. & Busby, J. T. Structural materials for fission & fusion energy. Mater. Today 12, https://doi.org/10.1016/S1369-7021(09)70294-9 (2009).10.1016/S1369-7021(09)70294-9 ↗
12. Kombaiah, B. et al. Nanoprecipitates to enhance radiation tolerance in high-entropy alloys. ACS Appl. Mater. Interfaces 15, 3912–3924 (2023).10.1021/acsami.2c17540 ↗
13. He, M. R. et al. Mechanisms of radiation-induced segregation in CrFeCoNi-based single-phase concentrated solid solution alloys. Acta Mater. 126, 182–193 (2017).10.1016/j.actamat.2016.12.046 ↗
14. Zhao, S., Chen, D. & Kai, J. J. First-principles study of He behavior in a NiCoFeCr concentrated solid–solution alloy. Mater. Res. Lett. 7, 188–193 (2019).10.1080/21663831.2019.1574926 ↗
15. Fan, Z. et al. Diffusion-mediated chemical concentration variation and void evolution in ion-irradiated NiCoFeCr high-entropy alloy. J. Mater. Res. 36, 298–310 (2021).10.1557/s43578-020-00071-8 ↗
16. Fan, Z. et al. From suppressed void growth to significant void swelling in NiCoFeCr complex concentrated solid-solution alloy. Materialia 9, 100603 (2020).10.1016/j.mtla.2020.100603 ↗
17. Zhao, S., Zhang, Y. & Weber, W. J. Engineering defect energy landscape of CoCrFeNi high-entropy alloys by the introduction of additional dopants. J. Nucl. Mater. 561, 153573 (2022).10.1016/j.jnucmat.2022.153573 ↗
18. Lu, C. et al. High radiation tolerance of an ultrastrong nanostructured NiCoCr alloy with stable dispersed nanooxides and fine grain structure. J. Nucl. Mater. 557, 153316 (2021).10.1016/j.jnucmat.2021.153316 ↗
19. Esfandiarpour, A., Feghhi, S. A. H. & Shokri, A. A. Effects of atomic grain boundary structures on primary radiation damage in α-Fe. Nucl. Instrum. Methods Phys. Res. Sect. B Beam Interact. Mater. At. 362, 1–8 (2015).10.1016/j.nimb.2015.08.074 ↗
20. Du, C. et al. Ultrastrong nanocrystalline steel with exceptional thermal stability and radiation tolerance. Nat. Commun. 9, 5389 (2018).10.1038/s41467-018-07712-x ↗
21. Li, M., Guo, Y., Li, W., Zhang, Y. & Chang, Y. Property enhancement of CoCrNi medium-entropy alloy by introducing nano-scale features. Mater. Sci. Eng. A 817, 141368 (2021).10.1016/j.msea.2021.141368 ↗
22. Guo, Y. et al. Microstructure and mechanical properties of oxide dispersion strengthened FeCoNi concentrated solid solution alloys. J. Alloy. Compd. 820, 153104 (2020).10.1016/j.jallcom.2019.153104 ↗
23. Guo, Y. et al. Oxide dispersion strengthened FeCoNi concentrated solid-solution alloys synthesized by mechanical alloying. Intermetallics 117, 106674 (2020).10.1016/j.intermet.2019.106674 ↗
24. Hadraba, H. et al. Oxide dispersion strengthened CoCrFeNiMn high-entropy alloy. Mater. Sci. Eng. A 689, 252–256 (2017).10.1016/j.msea.2017.02.068 ↗
25. Wang, S. et al. Unveiling deformation behavior and damage mechanism of irradiated high entropy alloys. J. Mater. Sci. Technol. 196, 71–87 (2024).10.1016/j.jmst.2024.02.017 ↗
26. Moghadasi, M. A., Nili-Ahmadabadi, M., Forghani, F. & Kim, H. S. Development of an oxide-dispersion-strengthened steel by introducing oxygen carrier compound into the melt aided by a general thermodynamic model. Sci. Rep. 6, 38621 (2016).10.1038/srep38621 ↗
27. Wu, Z. F. et al. Significant suppression of void swelling and irradiation hardening in a nanograined/nanoprecipitated 14YWT-ODS steel irradiated by helium ions. J. Nucl. Mater. 559, 153418 (2022).10.1016/j.jnucmat.2021.153418 ↗
28. Weber, W. J. & Zhang, Y. Predicting damage production in monoatomic and multi-elemental targets using stopping and range of ions in matter code: challenges and recommendations. Curr. Opin. Solid State Mater. Sci. 23, 100757 (2019).10.1016/j.cossms.2019.06.001 ↗
29. Jin, K. et al. Effects of compositional complexity on the ion-irradiation induced swelling and hardening in Ni-containing equiatomic alloys. Scr. Mater. 119, 65–70 (2016).10.1016/j.scriptamat.2016.03.030 ↗
30. Wyszkowska, E. et al. Investigation of the mechanical properties of ODS steels at high temperatures using nanoindentation technique. Nucl. Instruments Methods Phys. Res. Sect. B Beam Interact. with Mater. Atoms 444, 107–111 (2019).10.1016/j.nimb.2019.02.021 ↗
31. Frelek-Kozak, M. et al. Mechanical behavior of ion-irradiated ODS RAF steels strengthened with different types of refractory oxides. Appl. Surf. Sci. 610, 155465 (2023).10.1016/j.apsusc.2022.155465 ↗
32. Das, A. et al. Microstructural characterization of inhomogeneity in 9Cr ODS EUROFER steel. J. Nucl. Mater. 533, 152083 (2020).10.1016/j.jnucmat.2020.152083 ↗
33. Diao, S. Z. et al. The microstructure evolution and irradiation hardening in 15Cr-ODS steel irradiated by helium ions. Mater. Charact. 184, 111699 (2022).10.1016/j.matchar.2021.111699 ↗
34. Cui, L. J. et al. TEM characterization of irradiation-induced dislocation loops and voids in ion-irradiated pure chromium. J. Nucl. Mater. 569, 153920 (2022).10.1016/j.jnucmat.2022.153920 ↗
35. Holm, E. A., Hassold, G. N. & Miodownik, M. A. On misorientation distribution evolution during anisotropic grain growth. Acta Mater. 49, 2981–2991 (2001).10.1016/S1359-6454(01)00207-5 ↗
36. Was, G. S. Fundamentals of radiation materials science: Metals and alloys, second edition. Fundamentals of Radiation Materials Science: Metals and Alloys 2nd edn. https://doi.org/10.1007/978-1-4939-3438-6 (2016).10.1007/978-1-4939-3438-6 ↗
37. Yan, C. et al. Nanoindentation of supercrystalline nanocomposites: linear relationship between elastic modulus and hardness. JOM 74, 2261–2276 (2022).10.1007/s11837-022-05283-3 ↗
38. Mieszczynski, C. et al. Defect evolution in Ni and solid-solution alloys of NiFe and NiFeCoCr under ion irradiation at 16 and 300 K. J. Nucl. Mater. 534, 152138 (2020).10.1016/j.jnucmat.2020.152138 ↗
39. Liu, S. et al. NiCoCr-based medium-entropy alloys with superior resistance to radiation hardening and helium cavity growth. J. Nucl. Mater. 574, 154196 (2023).10.1016/j.jnucmat.2022.154196 ↗
40. Duan, B. et al. The effect of the initial microstructure in terms of sink strength on the ion-irradiation-induced hardening of ODS alloys studied by nanoindentation. J. Nucl. Mater. 495, 118–127 (2017).10.1016/j.jnucmat.2017.08.014 ↗
41. Ding, Z. N. et al. Hardening of ODS ferritic steels under irradiation with high-energy heavy ions. J. Nucl. Mater. 493, 53–61 (2017).10.1016/j.jnucmat.2017.05.040 ↗
42. Chen, T. et al. Microstructural changes and void swelling of a 12Cr ODS ferritic-martensitic alloy after high-dpa self-ion irradiation. J. Nucl. Mater. 467, 42–49 (2015).10.1016/j.jnucmat.2015.09.016 ↗
43. Li, F. et al. Microstructure evolution and void swelling of ODS ferritic/martensitic steel under high damage irradiation. Mater. Charact. 205, 113272 (2023).10.1016/j.matchar.2023.113272 ↗
44. Bufford, D. C., Abdeljawad, F. F., Foiles, S. M. & Hattar, K. Unraveling irradiation induced grain growth with in situ transmission electron microscopy and coordinated modeling. Appl. Phys. Lett. 107, 191901 (2015).10.1063/1.4935238 ↗
45. Zhou, J., Islam, M. I., Guo, S., Zhang, Y. & Lu, F. Radiation-induced grain growth of nanocrystalline alxcocrfeni high-entropy alloys. J. Phys. Chem. C 125, 3509–3516 (2021).10.1021/acs.jpcc.0c09061 ↗
46. Nori, S. T. et al. 4D evolution of Cr23C6 precipitates in neutron-irradiated and annealed HT-UPS steel observed via synchrotron micro-computed tomography. J. Mater. Res. 37, 208–224 (2022).10.1557/s43578-021-00474-1 ↗
47. Ribis, J. et al. Nano-structured materials under irradiation: oxide dispersion-strengthened steels. Nanomaterials 11, 2590 (2021).10.3390/nano11102590 ↗
48. Chen, T. et al. Temperature dependent dispersoid stability in ion-irradiated ferritic-martensitic dual-phase oxide-dispersion-strengthened alloy: Coherent interfaces vs. incoherent interfaces. Acta Mater. 116, 29–42 (2016).10.1016/j.actamat.2016.05.042 ↗
49. Tuomisto, F. et al. Segregation of Ni at early stages of radiation damage in NiCoFeCr solid solution alloys. Acta Mater. 196, 44–51 (2020).10.1016/j.actamat.2020.06.024 ↗
50. Lu, C. et al. Radiation-induced segregation on defect clusters in single-phase concentrated solid-solution alloys. Acta Mater. 127, 98–107 (2017).10.1016/j.actamat.2017.01.019 ↗
51. Lin, W. T. et al. He-enhanced heterogeneity of radiation-induced segregation in FeNiCoCr high-entropy alloy. J. Mater. Sci. Technol. 101, 226–233 (2022).10.1016/j.jmst.2021.05.053 ↗
52. Barr, C. M. et al. Exploring radiation induced segregation mechanisms at grain boundaries in equiatomic CoCrFeNiMn high entropy alloy under heavy ion irradiation. Scr. Mater. 156, 80–84 (2018).10.1016/j.scriptamat.2018.06.041 ↗
53. Ashkenazy, Y. & Averback, R. S. Irradiation induced grain boundary flow—a new creep mechanism at the nanoscale. Nano Lett. 12, 4084–4089 (2012).10.1021/nl301554k ↗
54. Jawaharram, G. S. et al. Irradiation induced creep in nanocrystalline high entropy alloys. Acta Mater. 182, 68–76 (2020).10.1016/j.actamat.2019.10.022 ↗
55. Tai, K., Averback, R. S., Bellon, P. & Ashkenazy, Y. Irradiation-induced creep in nanostructured Cu alloys. Scr. Mater. 65, 163–166 (2011).10.1016/j.scriptamat.2011.04.001 ↗
56. Zhang, Y. et al. New ion beam materials laboratory for materials modification and irradiation effects research. Nucl. Instrum. Methods Phys. Res. Sect. B Beam Interact. Mater. At. 338, 19–30 (2014).10.1016/j.nimb.2014.07.028 ↗
57. ASTM Standard E521-16. Standard Practice for Investigating the Effects of Neutron Radiation Damage Using Charged-Particle Irradiation. In Annual Book of ASTM Standards. Vol. 12, 1-21 (ASTM International, West Conshohocken, PA, 2016) https://doi.org/10.1520/E0521-16.10.1520/E0521-16 ↗
58. Agarwal, S., Lin, Y., Li, C., Stoller, R. E. & Zinkle, S. J. On the use of SRIM for calculating vacancy production: Quick calculation and full-cascade options. Nucl. Instrum. Methods Phys. Res. Sect. B Beam Interact. Mater. At. 503, 11–29 (2021).10.1016/j.nimb.2021.06.018 ↗
59. Lin, Y. R. et al. Predicting displacement damage for ion irradiation: origin of the overestimation of vacancy production in SRIM full-cascade calculations. Curr. Opin. Solid State Mater. Sci. 27, 101120 (2023).10.1016/j.cossms.2023.101120 ↗
60. Qiao, X. G., Starink, M. J. & Gao, N. The influence of indenter tip rounding on the indentation size effect. Acta Mater. 58, 3690–3700 (2010).10.1016/j.actamat.2010.03.004 ↗
61. Yang, L. et al. Nanoindentation study on early-stage radiation damage in single-phase concentrated solid solution alloys. Mater. Sci. Eng. A 908, 146746 (2024).10.1016/j.msea.2024.146746 ↗
62. Ali, M.dL., Haque, E. & Rahaman, M.dZ. Pressure- and temperature-dependent physical metallurgy in a face-centered cubic NiCoFeCrMn high entropy alloy and its subsystems. J. Alloy. Compd. 873, 159843 (2021).10.1016/j.jallcom.2021.159843 ↗
63. Schindelin, J. et al. Fiji: an open-source platform for biological-image analysis. Nat. Methods 9, https://doi.org/10.1038/nmeth.2019 (2012).10.1038/nmeth.2019 ↗
64. Rauch, E. F. et al. Automated nanocrystal orientation and phase mapping in the transmission electron microscope on the basis of precession electron diffraction. Z. Krist. 225, 103–109 (2010).10.1524/zkri.2010.1205 ↗
65. Nolze, G. & Hielscher, R. Orientations—perfectly colored. J. Appl. Crystallogr. 49, 1786–1802 (2016).10.1107/S1600576716012942 ↗