Enhancing mechanical strength and tribological performance in tin bronze alloys via rolling treatment
Source abstract
Abstract
This study electroplates a 2 μm thick Al layer on mild steel, then uses wire-arc directed energy deposition (DED) to deposit Cu-4.2Sn alloy, forming a composite material which is subsequently cold-rolled. It investigates the microstructure, mechanical properties, and tribological behavior before and after rolling, along with underlying mechanisms. It indicates that Al coating completely suppresses penetration cracks on the steel side of the tin bronze/steel bimetal. After rolling, tin bronze grains are significantly refined (from 47.6 μm to 15.2 μm) with numerous twins formed, reducing matrix dislocation density. Compared to wire-arc DED alloy, rolled alloy hardness increases by 78%, yield strength by 51%, and tensile strength by 30%. Tribological tests indicate, under dry friction and simulated seawater conditions, the rolled alloy’s coefficient of friction (COF) and mass loss decrease by 30% and 24% respectively. Analysis of corrosion-friction synergy reveals interaction loss accounts for 13%, dominated by friction-promoted corrosion (11%).
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Research context
OpenAlex topics: Metallurgy and Material Science · Aluminum Alloys Composites Properties · Aluminum Alloy Microstructure Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (60)
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1. Hu, D. C., Chen, M. H., Wang, L. & Cheng, H. Dynamic tensile behaviour and deformational mechanism of C5191 phosphor bronze under high strain rates deformation. Mater. Sci. Eng., A 649, 68–73 (2016).10.1016/j.msea.2015.09.075 ↗
2. Liu, Y., Liu, X. H., Fu, H. D., Lou, M. X. & Xie, J. X. Effects of process parameters on surface quality, composition segregation, microstructure and properties of QSn6.5-0.1 alloy slabs fabricated by HCCM horizontal continuous casting. J. Iron Steel Res. Int. 24, 273–281 (2017).10.1016/S1006-706X(17)30040-7 ↗
3. Park, J. H., Kim, S. Y., Lee, H. S. & Wi, K. Influence of different metal types on the bonding strength of concrete using the arc thermal metal spraying method, Materials 16 https://doi.org/10.3390/ma16072651 (2023).10.3390/ma16072651 ↗
4. Wang, Y. et al. Friction and wear properties of wide-velocity range high-energy plasma sprayed CuSn-NiCr solid self-lubricating coatings under heavy load. Wear 550, 205417 (2024).10.1016/j.wear.2024.205417 ↗
5. Gan, R. et al. Preparation and properties of Cu/Cu-Sn alloy cladding layers on titanium alloy by laser cladding. J. Alloy. Compd. 1020, 179547 (2025).10.1016/j.jallcom.2025.179547 ↗
6. Ozdemir, I., Bulbul, B., Grund, T. & Lampke, T. Wear and corrosion behavior of cold-sprayed Cu-10Sn coatings, Crystals 13 https://doi.org/10.3390/cryst13030523 (2023).10.3390/cryst13030523 ↗
7. Wei, J. et al. Cold spray deposition and microstructure characterization of CuNi, CuSn, and CuNiSiCr coatings. Surf. Coat. Technol. 480 https://doi.org/10.1016/j.surfcoat.2024.130621 (2024).10.1016/j.surfcoat.2024.130621 ↗
8. Wang, C. et al. A novel cold wire gas metal arc (CW-GMA) process for high productivity additive manufacturing. Addit. Manuf. 73 https://doi.org/10.1016/j.addma.2023.103681 (2023).10.1016/j.addma.2023.103681 ↗
9. Zhang, H., Hu, S., Wang, Z. & Liang, Y. The effect of welding speed on microstructures of cold metal transfer deposited AZ31 magnesium alloy clad. Mater. Des. 86, 894–901 (2015).10.1016/j.matdes.2015.07.143 ↗
10. Wei, M. et al. Technology, Microstructure and bonding strength of tin-based Babbitt alloy on ASTM 1045 steel by MIG arc brazing. 32, 1–12 (2018).10.1080/01694243.2018.1464239 ↗
11. Evangeline, A. & Paulraj, S.J.M.R.E. Cold metal arc transfer (CMT) metal deposition of inconel 625 superalloy on 316L austenitic stainless steel: microstructural evaluation, corrosion and wear resistance properties. 6, 066516 (2019).10.1088/2053-1591/ab0a10 ↗
12. Wei, M., Sun, K., Zhang, X., Zhang, C. & Xue, F. Microstructure and bonding strength of tin-based Babbitt alloy on ASTM 1045 steel by MIG arc brazing. J. Adhes. Sci. Technol. 32, 1–12 (2018).10.1080/01694243.2017.1322767 ↗
13. Cai, X. et al. From cast to wire-arc DED: an investigation on NAB alloy MIC resistance. Corros. Sci. 251 https://doi.org/10.1016/j.corsci.2025.112910 (2025).10.1016/j.corsci.2025.112910 ↗
14. Cai, X. et al. Comparative analysis of cavitation erosion behavior in wire-arc directed energy deposition and cast nickel-aluminum bronze alloys. Ultrason. Sonochem. 113 https://doi.org/10.1016/j.ultsonch.2025.107235 (2025).10.1016/j.ultsonch.2025.107235 ↗
15. Mosleh-Shirazi, S., Akhlaghi, F. & Li, D. Y. Effect of graphite content on the wear behavior of Al/2SiC/Gr hybrid nano-composites respectively in the ambient environment and an acidic solution. Tribol. Int. 103, 620–628 (2016).10.1016/j.triboint.2016.08.016 ↗
16. Ren, S., Meng, J., Wang, J., Lu, J. & Yang, S. Tribo-corrosion behaviors of Ti3SiC2/Si3N4 tribo-pair in hydrochloric acid and sodium hydroxide solutions. Wear 274, 8–14 (2012).10.1016/j.wear.2011.08.007 ↗
17. Ebrahimi, M., Attarilar, S., Shaeri, M. H., Gode, C. & Djavanroodi, F. M. Engineering, An investigation into the effect of alloying elements on corrosion behavior of severely deformed Cu-Sn alloys by equal channel angular pressing. Arch. Civ. Mech. Eng. 19, 842–850 (2019).10.1016/j.acme.2019.03.009 ↗
18. Moharami, A. Improving the dry sliding-wear resistance of as-cast Cu-10Sn-1P alloy through accumulative back extrusion (ABE) process. J. Mater. Res. Technol. 9, 10091–10096 (2020).10.1016/j.jmrt.2020.07.022 ↗
19. J. Hui, W. Liu, B. Wang, Quasi-gradient variation of microstructures and properties of Cu–Sn alloy along the thickness direction under cold spinning. J. Alloy. Compd. 831 https://doi.org/10.1016/j.jallcom.2020.154701 (2020).10.1016/j.jallcom.2020.154701 ↗
20. Pantawane, M. V., Ho, Y. H., Joshi, S. S. & Dahotre, N. B. Computational assessment of thermokinetics and associated microstructural evolution in laser powder bed fusion manufacturing of Ti6Al4V Alloy. Sci. Rep. 10 https://doi.org/10.1038/s41598-020-63281-4 (2020).10.1038/s41598-020-63281-4 ↗
21. Orzolek, S. M., Semple, J. K. & Fisher, C. R. Influence of processing on the microstructure of nickel aluminum bronze (NAB). Addit. Manuf. 56 https://doi.org/10.1016/j.addma.2022.102859 (2022).10.1016/j.addma.2022.102859 ↗
22. Xing, Z. B., Nie, Z. R., Zou, J. X. & Gao, X. D. Effects of cooling rate on solidification and microstructure of Al-4.5Mg-0.7Mn-0.4Er alloy. Spec. Cast. nonferrous Alloy. 27, 3 (2007).
23. Kou, Z. et al. Observing dislocations transported by twin boundaries in Al thin film: unusual pathways for dislocation-twin boundary interactions. Nano Lett. 22, 6229–6234 (2022).10.1021/acs.nanolett.2c01763 ↗
24. Kou, Z. et al. Revealing the atomic-scale evolution of sessile disconnections on twin boundaries during deformation. Scr. Mater. 221 https://doi.org/10.1016/j.scriptamat.2022.114956 (2022).10.1016/j.scriptamat.2022.114956 ↗
25. Dey, S. N. P. Chatterjee, S. P. S. Gupta, Deformation stacking fault probability and dislocation microstructure of cold worked Cu-Sn-5Zn alloys by x-ray diffraction line profile analysis. J. Appl. Phys. 100 https://doi.org/10.1063/1.2356906 (2006).10.1063/1.2356906 ↗
26. Rizi, M. S., Minouei, H., Lee, B. J., Toroghinejad, M. R. & Hong, S. I. Effects of carbon and molybdenum on the nanostructural evolution and strength/ductility trade-off in Fe40Mn40Co10Cr10 high-entropy alloys. J. Alloy. Compd. 911, 165108 (2022).10.1016/j.jallcom.2022.165108 ↗
27. Rizi, M. S. et al. Enhancing mechanical properties in Ti-containing FeMn40Co10Cr10C0.5 high-entropy alloy through Chi (χ) phase dissolution and precipitation hardening. Mater. Lett. 377, 137516 (2024).10.1016/j.matlet.2024.137516 ↗
28. Cai, X. et al. Advanced mechanical properties of nickel-aluminum bronze/steel composite structure prepared by wire-arc additive manufacturing. Mater. Des. 221, 14 (2022).10.1016/j.matdes.2022.110969 ↗
29. Li, Y., Bushby, A. J. & Dunstan, D. J. The hall-petch effect as a manifestation of the general size effect. Proc. R. Soc. A-Math. Phys. Eng. Sci. 472 https://doi.org/10.1098/rspa.2015.0890 (2016).10.1098/rspa.2015.0890 ↗
30. Zhou, L. et al. Quasi-in situ electron backscatter diffraction analysis of twinning-detwinning behavior in AZ31 magnesium-alloy rolled plates subjected to compression loading in different directions. J. Magnes. Alloy. 13, 2358–2373 (2025).10.1016/j.jma.2024.10.007 ↗
31. Pouraliakbar, H. et al. Texture and grain refinement for enhanced strength and ductility in friction stir welding of cold-rolled thin-strip rapidly solidified AA5182 Al-Mg alloy. J. Mater. Res. Technol. 36, 10143–10156 (2025).10.1016/j.jmrt.2025.05.206 ↗
32. Cai, X. et al. Effect of quasicrystal I-phase on microstructure and mechanical properties of hot-rolled diphasic Mg-8 wt.% Li alloy. J. Mater. Eng. Perform. 31, 3054–3064 (2022).10.1007/s11665-021-06406-8 ↗
33. Lai, X. et al. Effect of annealing on microstructure and properties of AlCoCuFeTi high-entropy alloy fabricated by arc melting. Intermetallics 170 https://doi.org/10.1016/j.intermet.2024.108327 (2024).10.1016/j.intermet.2024.108327 ↗
34. Okoro, A. M. et al. Nanoindentation studies of the mechanical behaviours of spark plasma sintered multiwall carbon nanotubes reinforced Ti6Al4V nanocomposites. Mater. Sci. Eng., A 765, 138320 (2019).10.1016/j.msea.2019.138320 ↗
35. Cai, X., Qiao, Y. X., Wang, B. J., Zhou, H. L. & Wang, Y. X. Effect of cold rolling on microstructural and mechanical properties of Mg-7Li alloy. Int. J. Mod. Phys. B 34, 2040035 (2020).10.1142/S0217979220400354 ↗
36. Tian, S. et al. Intermetallics-induced directional growth of Sn whiskers in Sn-3.5Ag coating on Al substrate. Appl. Surf. Sci. 539, 148135 (2021).10.1016/j.apsusc.2020.148135 ↗
37. Tian, S. et al. Tin whiskers prefer to grow from the 001 grains in a tin coating on aluminum substrate. J. Mater. Sci. Technol. 80, 191–202 (2021).10.1016/j.jmst.2021.01.002 ↗
38. Kaneko, H., Eguchi, T. & Inoue, H. Recrystallization Texture and Young’s Modulus in Cu-3.8%Ni-0.9%Si Alloy Sheets. J. Jpn. I. Met. Mater. 77, 353–360 (2013).
39. Kurtulus, V., Gorgulu, B., Eraslan, F. S. & Gecu, R. Improving wear and corrosion resistance of Ti-alloyed nodular cast irons by Al2O3 and SiC-reinforced Al2O3 coatings. Surf. Coat. Technol. 498, 131809 (2025).10.1016/j.surfcoat.2025.131809 ↗
40. Boztepe, A. & Gecu, R. Influence of cryogenic treatment and tempering temperature on microstructural evolution and dry sliding wear behavior of AISI D3 cold-work tool steel. J. Tribol. 147, 064201 (2025).10.1115/1.4067045 ↗
41. Cai, X. et al. Experimental investigations on corrosion behavior and antibacterial property of nickel-aluminum bronze fabricated through wire-arc additive manufacturing (WAAM). Corros. Sci. 214 https://doi.org/10.1016/j.corsci.2023.111040 (2023).10.1016/j.corsci.2023.111040 ↗
42. Cai, X. et al. Investigation of mechanical and corrosion behavior of multi-pass nickel-aluminum bronze fabricated through wire-arc directed energy deposition, Addit. Manuf. 80 https://doi.org/10.1016/j.addma.2024.103967 (2024).10.1016/j.addma.2024.103967 ↗
43. Cai, X. et al. Experimental investigation on wear resistance and corrosion behavior of nickel-aluminum bronze alloy fabricated by wire-arc additive manufacturing. J. Mater. Res. Technol. 26, 5801–5815 (2023).10.1016/j.jmrt.2023.08.313 ↗
44. Palumbo, G. et al. Effect of grain size on the corrosion behavior of Fe-3 wt%Si-1 wt% Al electrical steels in pure water saturated with CO2. Materials 14 https://doi.org/10.3390/ma14175084 (2021).10.3390/ma14175084 ↗
45. Yamashita, M., Mimaki, T., Hashimoto, S. & Miura, S. Intergranular corrosion of copper and α-Cu-Al alloy bicrystals. Philos. Mag. A 63, 695–705 (1991).10.1080/01418619108213908 ↗
46. Miyamoto, H., Yoshimura, K., Mimaki, T. & Yamashita, M. Behavior of intergranular corrosion of〈0 1 1〉 tilt grain boundaries of pure copper bicrystals. Corros. Sci. 44, 1835–1846 (2002).10.1016/S0010-938X(01)00158-5 ↗
47. Runa, M. J., Mathew, M. T. & Rocha, L. A. Tribocorrosion response of the Ti6Al4V alloys commonly used in femoral stems. Tribol. Int. 68, 85–93 (2013).10.1016/j.triboint.2013.09.022 ↗
48. Huang, X. et al. Effect of surface oxidation on wear and tribocorrosion behavior of forged and selective laser melting-based TC4 alloys. Tribol. Int. 174 https://doi.org/10.1016/j.triboint.2022.107780 (2022).10.1016/j.triboint.2022.107780 ↗
49. Alghamdi, S. A., Ahmad, S. & Lawan, A. Optimization of concrete mixture design and cover thickness for reinforced concrete members under chloride exposure. Acids. Mater. J. 113, 589–598 (2016).
50. Yang, F. et al. The role of nickel in mechanical performance and corrosion behaviour of nickel-aluminium bronze in 3.5 wt% NaCl solution. Corros. Sci. 139, 333–345 (2018).10.1016/j.corsci.2018.05.012 ↗
51. Xin, J. M., Fan, L., Liu, Y. P. & Ma, L. Research progress on the corrosion mechanism of copper and Its alloys in marine environment. Equip. Environ. Eng. 21, 127–136 (2024).
52. Chang, T. et al. The role of Sn on the long-term atmospheric corrosion of binary Cu-Sn bronze alloys in architecture. Corros. Sci. 149, 54–67 (2019).10.1016/j.corsci.2019.01.002 ↗
53. Liang, Z., Jiang, K. & Zhang, T. A. Corrosion behaviour of lead bronze from the Western Zhou Dynasty in an archaeological-soil medium. Corros. Sci. 191 https://doi.org/10.1016/j.corsci.2021.109721 (2021).10.1016/j.corsci.2021.109721 ↗
54. Xie, W., Qian, L. & Yong, L. Corrosion Behavior of New Cu-Sn-Fe-Ni Alloy in 3.5wt% NaCl Solution. Rare Met. Mat. Eng. 52, 3893–3899 (2023).
55. Hou, Q. Y. et al. Liquid phase separation microstructure and properties of mixed Cu-Sn and Co-base alloys without or with molybdenum addition processed by plasma transferred arc hardfacing. Surf. Coat. Technol. 262, 87–96 (2015).10.1016/j.surfcoat.2014.12.022 ↗
56. Kostornov, A. G. et al. Service properties of Cu–Sn–CuWO4 –MoS2 composite and micromechanical characteristics of its friction surface. Powder Metall. Met. Ceram. 49, 647–653 (2011).10.1007/s11106-011-9282-4 ↗
57. Kresse, G. Matter, Ab initio molecular dynamics for liquid metals. Phys. Rev. B Condens Matter 48, 13115–13118 (1993).10.1103/PhysRevB.48.13115 ↗
58. Rice, J. R. & Wang, J. S. Embrittlement of interfaces by solute segregation. Mater. Sci. Eng., A 107, 23–40 (1989).10.1016/0921-5093(89)90372-9 ↗
59. Wu, X. B. et al. First-principles determination of grain boundary strengthening in tungsten: Dependence on grain boundary structure and metallic radius of solute. Acta Mater. 120, 315–326 (2016).10.1016/j.actamat.2016.08.048 ↗
60. Razumovskiy, V. I., Divinski, S. V. & Romaner, L. Solute segregation in Cu: DFT vs. Experiment 147, 122–132 (2018).