Ancient chinese glass heritage classification based on compositional data and machine learning
Source abstract
Abstract
Ancient Chinese glass resembles foreign glass in appearance but differs in chemical composition, which is further altered by weathering, thereby complicating the classification of artefacts. According to classification information and compositional proportion data for a set of ancient glass samples, we applied compositional data analysis based on the centered log-ratio (CLR) transformation, combined with chi-square and Fisher’s exact tests, to investigate the relationships between surface weathering, glass type, emblazonry and color. Summary statistics, box plots, normality tests and two-sample t tests were used to compare chemical compositions before and after weathering and to estimate pre-weathering compositions from median ratios. Decision trees, logistic regression, support vector machines and random forests were then used to classify high-potassium and lead-barium glass, and ANOVA, significance tests and K-means clustering were used to divide their compositional sub-categories. The resulting models show robust classification performance and provide a reproducible, data-driven framework for the classification of ancient Chinese glass.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Cultural Heritage Materials Analysis · Mineralogy and Gemology Studies · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (50)
Show source-provided references
1. Lü, Q. Q., Henderson, J., Wang, Y. Q. & Wang, B. H. Natron glass beads reveal proto-Silk Road between the Mediterranean and China in the 1st millennium BCE. Sci. Rep. 11, 13 (2021).
2. Gan, F. X., Cheng, H. S. & Li, Q. H. Origin of Chinese ancient glasses - study on the earliest Chinese ancient glasses. Sci. China Ser. E Technol. Sci. 49, 701–713 (2006).10.1007/s11431-006-2036-8 ↗
3. Davies, T. E. et al. Experimental methods in chemical engineering: Scanning electron microscopy and X-ray ultra-microscopy-SEM and XuM. Can. J. Chem. Eng. 100, 3145–3159 (2022).10.1002/cjce.24405 ↗
4. de León, C. A. P., Montes-Bayón, M. & Caruso, J. A. Elemental speciation by chromatographic separation with inductively coupled plasma mass spectrometry detection. J. Chromatogr. A 974, 1–21 (2002).10.1016/S0021-9673(02)01239-6 ↗
5. Saniso, E. et al. Garcinia drying using mixed-mode solar dryer technique: Drying kinetics, mathematical modeling and quality characteristics. Case Stud. Therm. Eng. 66, 13 (2025).10.1016/j.csite.2024.105711 ↗
6. Xu, Y. S. et al. Investigation of the Dynamic Properties of Viscoelastic Dampers with Three-Chain Micromolecular Configurations and Tube Constraint Effects. J. Aerosp. Eng. 38, 17 (2025).10.1061/JAEEEZ.ASENG-5141 ↗
7. Tang, P. X., Li, H. T., Zhang, X. M. & Sun, X. A mathematical model of catalyst combination design and temperature control in the preparation of C4 olefins through ethanol coupling. Rsc Adv. 13, 10703–10714 (2023).10.1039/D3RA01363D ↗
8. Lai, Y. Z. et al. Machine learning for membrane bioreactor research: principles, methods, applications, and a tutorial. Front. Env. Sci. Eng. 19, 26 (2025).10.1007/s11783-025-1954-2 ↗
9. Wekalao, J., Alsalman, O. & Patel, S. K. Graphene metasurface biosensor design for label-free peptide detection with machine learning optimization based on support vector regression with polynomial kernel. Diam. Relat. Mat. 153, 16 (2025).10.1016/j.diamond.2025.112053 ↗
10. Mathur, P., Srivastava, S., Xu, X. W. & Mehta, J. L. Artificial Intelligence, Machine Learning, and Cardiovascular Disease. Clin. Med. Insights Cardiol. 14, 9 (2020).10.1177/1179546820927404 ↗
11. Bickler, S. H. Machine Learning Arrives in Archaeology. Adv. Archaeol. Pract. 9, 186–191 (2021).10.1017/aap.2021.6 ↗
12. Ling, Z. Y., Delnevo, G., Salomoni, P. & Mirri, S. Findings on Machine Learning for Identification of Archaeological Ceramics: A Systematic Literature Review. IEEE Access 12, 100167–100185 (2024).10.1109/ACCESS.2024.3429623 ↗
13. Li, Z. X. et al. Analysis of the Composition of Ancient Glass and Its Identification Based on the Daen-LR, ARIMA-LSTM and MLR Combined Process. Appl. Sci. 13, 24 (2023).
14. Guo, Y. H., Zhan, W. & Li, W. H. Application of Support Vector Machine Algorithm Incorporating Slime Mould Algorithm Strategy in Ancient Glass Classification. Appl. Sci. 13, 14 (2023).
15. Zou, Y. Molecular-Composition Analysis of Glass Chemical Composition Based on Time-Series and Clustering Methods. Molecules 28, 15 (2023).10.3390/molecules28020853 ↗
16. China Undergraduate Mathematical Contest in Modeling. Question C of the 2022 Chinese Contemporary Undergraduate Mathematical Contest in Modeling (China Undergraduate Mathematical Contest in Modeling, 2022).
17. Aitchison, J. & Greenacre, M. Biplots of compositional data. J. R. Stat. Soc. Ser. C Appl. Stat. 51, 375–392 (2002).10.1111/1467-9876.00275 ↗
18. Aitchison, J., Barceló-Vidal, C., Martín-Fernández, J. A. & Pawlowsky-Glahn, V. Logratio analysis and compositional distance. Math. Geol. 32, 271–275 (2000).10.1023/A:1007529726302 ↗
19. Aitchison, J. Principal component analysis of compositional data. Biometrika 70, 57–65 (1983).10.1093/biomet/70.1.57 ↗
20. Aitchison, J. Principles of Compositional Data Analysis. Multivariate Analysis and Its Applications IMS Lecture Notes Monograph Series, Vol. 24, 73–81 (Institute of Mathematical Statistics, 1994). https://doi.org/10.1214/lnms/121546378610.1214/lnms/1215463786 ↗
21. Goo, J., Sakhanenko, L. & Zhu, D. C. A chi-square type test for time-invariant fiber pathways of the brain. Stat. Infer. Stoch. Proc. 25, 449–469 (2022).10.1007/s11203-022-09268-6 ↗
22. Wu, Y. F., Ma, Y. R. & Jiang, Y. Double-state chi-square test based sparse grid quadrature filtering algorithm and its application in integrated navigation. IET Contr. Theory Appl. 17, 1203–1213 (2023).10.1049/cth2.12450 ↗
23. Sanchez, I., Keatley, D., Oklevski, S. & Speers, S. J. A large study evaluation of evidence types containing offender fingerprints from recorded crimes in North Macedonia from 2005 to 2015. Sci. Justice 62, 43–49 (2022).10.1016/j.scijus.2021.11.003 ↗
24. Sharif, O. et al. Analyzing the Impact of Demographic Variables on Spreading and Forecasting COVID-19. J. Healthc. Inform. Res. 6, 72–90 (2022).10.1007/s41666-021-00105-8 ↗
25. Gel, Y. R. & Gastwirth, J. L. A robust modification of the Jarque-Bera test of normality. Econ. Lett. 99, 30–32 (2008).10.1016/j.econlet.2007.05.022 ↗
26. Thadewald, T. & Büning, H. Jarque-Bera test and its competitors for testing normality -: A power comparison. J. Appl. Stat. 34, 87–105 (2007).10.1080/02664760600994539 ↗
27. Gonzalez, T., Sahni, S. & Franta, W. R. An Efficient Algorithm for the Kolmogorov-Smirnov and Lilliefors Tests. ACM Trans. Math. Softw. 3, 60–64 (1977).10.1145/355719.355724 ↗
28. Blain, G. C. Revisiting the critical values of the Lilliefors test: towards the correct agrometeorological use of the Kolmogorov-Smirnov framework. Bragantia 73, 192–202 (2014).10.1590/brag.2014.015 ↗
29. Kelter, R. A New Bayesian Two-Sample t Test and Solution to the Behrens-Fisher Problem Based on Gaussian Mixture Modelling with Known Allocations. Stat. Biosci. 14, 380–412 (2022).10.1007/s12561-021-09326-2 ↗
30. Al-Kassab, M. M. & Majeed, A. H. The use of two-sample t-test in the real data. Adv. Appl. Stat. 81, 13–22 (2022).
31. Amin, M., Fatima, A., Akram, M. N. & Kamal, M. Influential observation detection in the logistic regression under different link functions: an application to urine calcium oxalate crystals data. J. Stat. Comput. Simul. 14, 346–359 (2023).
32. Sopitpongstorn, N., Silvapulle, P., Gao, J. T. & Fenech, J. P. Local logit regression for loan recovery rate. J. Bank Financ. 126, 14 (2021).10.1016/j.jbankfin.2021.106093 ↗
33. Dong, G. S. & Mu, X. W. A novel second-order cone programming support vector machine model for binary data classification. J. Intell. Fuzzy Syst. 39, 4505–4513 (2020).
34. Qin, Z. F. & Li, Q. Q. An uncertain support vector machine with imprecise observations. Fuzzy Optim. Decis. Mak. 22, 611–629 (2023).10.1007/s10700-022-09404-0 ↗
35. Ghosh, D. & Cabrera, J. Enriched Random Forest for High Dimensional Genomic Data. IEEE ACM Trans. Comput. Biol. Bioinform. 19, 2817–2828 (2022).10.1109/TCBB.2021.3089417 ↗
36. Rhodes, J. S., Cutler, A. & Moon, K. R. Geometry- and Accuracy-Preserving Random Forest Proximities. IEEE Trans. Pattern Anal. Mach. Intell. 45, 10947–10959 (2023).10.1109/TPAMI.2023.3263774 ↗
37. Breiman, L. Random forests. Mach. Learn. 45, 5–32 (2001).10.1023/A:1010933404324 ↗
38. Breiman, L., Friedman, J. H., Olshen, R. A. & Stone, C. J. Classification and Regression Trees. Biometrics 40, 874 (1984).10.2307/2530946 ↗
39. Cutler, D. R., Edwards, T. C., Beard, K. H., Cutler, A. & Hess, K. T. Random forests for classification in ecology. Ecology 88, 2783–2792 (2007).10.1890/07-0539.1 ↗
40. Zanini, R., Franceschin, G., Cattaruzza, E. & Traviglia, A. A review of glass corrosion: the unique contribution of studying ancient glass to validate glass alteration models. NPJ Mater. Degrad. 7, 17 (2023).10.1038/s41529-023-00355-4 ↗
41. Degryse, P. & Shortland, A. J. Interpreting elements and isotopes in glass: A review. Archaeometry 62, 117–133 (2020).10.1111/arcm.12531 ↗
42. Rodrigues, A., Fearn, S. & Vilarigues, M. Historic K-rich silicate glass surface alteration: Behaviour of high-silica content matrices. Corrosion Sci. 145, 249–261 (2018).10.1016/j.corsci.2018.10.010 ↗
43. Greenacre, M. Compositional data analysis. In Annual Review of Statistics and Its Application, Vol. 8 (ed. Reid, N.) 271–299 (Annual Reviews, 2021).10.1146/annurev-statistics-042720-124436 ↗
44. Vera Pawlowsky-Glahn, J. J. E. T.-D. Compositional data and their sample space. In Modelling and Analysis of Compositional Data 8–22 (Wiley, 2015).10.1002/9781119003144.ch2 ↗
45. Filzmoser, P., Hron, K. & Reimann, C. Principal component analysis for compositional data with outliers. Environmetrics 20, 621–632 (2009).10.1002/env.966 ↗
46. Chen, W. & Chen, D. Research on the classification of ancient silicate glass artifacts based on machine learning. Archaeometry 67, 72–86 (2025).10.1111/arcm.13001 ↗
47. Ma, Q., Braekmans, D., Shortland, A. & Pollard, A. M. The Production and Composition of Chinese Lead-Barium Glass through Experimental Laboratory Replication. J. Non Cryst. Solids 551, 8 (2021).10.1016/j.jnoncrysol.2020.120409 ↗
48. Henderson J. Ancient Glass: An Interdisciplinary Exploration (Cambridge University Press, 2013).10.1017/CBO9781139021883 ↗
49. Yogurtcu, B., Cebi, N., Koçer, A. T. & Erarslan, A. A Review of Non-Destructive Raman Spectroscopy and Chemometric Techniques in the Analysis of Cultural Heritage. Molecules 29, 19 (2024).10.3390/molecules29225324 ↗
50. Zumpano, R., Simonetti, F., Genova, C., Mazzei, F. & Favero, G. Raman spectroscopy and SERS: Recent advances in cultural heritage diagnostics and the potential use of anisotropic metal nanostructures. J. Cult. Herit. 71, 282–301 (2025).10.1016/j.culher.2024.12.010 ↗