journal article·2025-05-05Open access

The deterioration structure of tremolite jade artifacts from the Sanxingdui sacrificial pits dated to the Shang Dynasty in Guanghan, Sichuan, China

Chujing Xu, Jiancheng Liu, Yunpeng Wang, Honglin Ran, Haoze Wu, Hui Fang, Qinglin Ma

npj Heritage Science· Volume 13· Issue 1

Abstract

The Sanxingdui archaeological site, located in Guanghan City, Sichuan Province, is considered one of the most significant archaeological discoveries in China. Current research suggests that jade artifacts unearthed from the sacrificial pits at the site were subjected to high temperatures before being interred, which led to the transformation of tremolite into whitened pyroxene. In this study, tremolite and pyroxene samples from the sacrificial pits at the Sanxingdui site were selected for analysis. These samples were examined using a variety of analytical techniques, including ultra-depth-of-field microscopy, scanning electron microscopy with X-ray energy dispersive spectrometry, laser confocal Raman spectroscopy, and Fourier transform infrared spectroscopy. The objective of this study was to investigate the structural characteristics and deterioration status of the jade artifacts. The results indicate that jade artifacts with a higher degree of pyroxenization tend to exhibit more severe deterioration, while tremolite jade artifacts without pyroxenization generally remain in better condition.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Mineralogy and Gemology Studies · Archaeology and ancient environmental studies · Geological and Geochemical Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Archaeological Team at the Sanxingdui Site Sacrificial Area. Sacrificial area of the Sanxingdui Site in Guanghan City, Sichuan (in Chinese). Archaeology. 7, 15–33+2 (2022).
2. Li, Y., Qiu, T., Guo, J. & Li, Y. New discoveries at the Sanxingdui Bronze Age site in south-west China. Antiquity 97, e4 (2023).10.15184/aqy.2022.150 ↗
3. Sichuan Provincial Cultural Relics and Archeology Research Institute, National Center for Archaeology. Joint Laboratory for Archaeological Chronology, School of Archaeology and Museology, Peking University. AMS Radiocarbon dating of K4 sacrificial pit at Sanxingdui Site in Guanghan City, Sichuan (in Chinese). Sichuan Cult. Relics 2, 117–120 (2021).
4. Sichuan Provincial Institute of Cultural Relics and Archeology. Excavation of the Sacrificial Pits at Sanxingdui (in Chinese) (Cultural Relics Press, Beijing, 1999).
5. Lu, H. et al. Characterizing ancient jade by on-site analysis in Sanxingdui, China. Herit. Sci. 11, 121 (2023).10.1186/s40494-023-00960-1 ↗
6. Guo, Y. et al. The sacrificial record in burial pits of the late Shang Dynasty: evidences from the chroma and magnetic properties of the Sanxingdui site, Sichuan, China. Herit. Sci. 11, 258 (2023).10.1186/s40494-023-01105-0 ↗
7. Wang, R., Mai, Y. & Lin, L. Burnt jade sacrifices in the Chinese Neolithic: the Liangzhu cemetery at Sidun. Antiquity 96, 1495–1514 (2022).10.15184/aqy.2022.101 ↗
8. Wang, R., Wang, C. & Tang, J. A jade parrot from the tomb of Fu Hao at Yinxu and Liao sacrifices of the Shang Dynasty. Antiquity 92, 368–382 (2018).10.15184/aqy.2017.220 ↗
9. Wang, R. Progress review of the scientific study of Chinese ancient jade. Archaeometry 53, 674–692 (2011).10.1111/j.1475-4754.2010.00564.x ↗
10. Wang, Y. et al. Analysis of whitening mechanism of ancient tremolite jade: taking some of the jades excavated from the Sanxingdui site as examples (in Chinese). Sci. Conserv. Archaeol. 36, 17–33 (2024).
11. Lu, H. et al. A test report on the formulae of the jade and stone objects unearthed at the Sanxingdui ruin site and other related issues (in Chinese). J. Palace Mus. 64, 123–142+147 (2021).
12. Liu, J., Ming, W., Wang, Y., Wang, J. & Yu, J. Traceability study of large jade materials unearthed at the Sanxingdui site (in Chinese). Sichuan Cult. Relics 38, 84–94 (2021).
13. Rinaudo, C., Belluso, E. & Gastaldi, D. Assessment of the use of Raman spectroscopy for the determination of amphibole asbestos. Miner. Mag. 68, 455–465 (2004).10.1180/0026461046830197 ↗
14. Wang, R. & Zhang, W. Application of Raman spectroscopy in the nondestructive analyses of ancient Chinese jades. J. Raman Spectrosc. 42, 1324–1329 (2011).10.1002/jrs.2846 ↗
15. Chen, T. A Raman spectroscopic study of heat-treated nephrite. Phase Transit. 81, 205–216 (2008).10.1080/01411590701514367 ↗
16. Wang, R. & Zhang, B. Raman spectra of pyroxene (in Chinese). Spectrosc. Spect. Anal. 30, 376–381 (2010).
17. Tribaudino, M., Mantovani, L., Bersani, D. & Lottici, P. Raman spectroscopy of (Ca, Mg) MgSi2O6 clinopyroxenes. Am. Miner. 97, 1339–1347 (2012).10.2138/am.2012.4057 ↗
18. Wang, D., Xu, Z., Sun, M. & Cao, S. Study on the IR spectrum of jasper of different origin (in Chinese). Infrared Tech. 31, 698–701+707 (2009).
19. Korybska-Sadło, I., Gil, G., Gunia, P., Horszowski, M. & Sitarz, M. Raman and FTIR spectra of nephrites from the Złoty Stok and Jordanów Śląski (the Sudetes and Fore-Sudetic Block, SW Poland). J. Mol. Struct. 1166, 40–47 (2018).10.1016/j.molstruc.2018.04.020 ↗
20. Omori, K. Analysis of the infrared absorption spectrum of diopside. Am Miner 56, 1607–1616 (1971).
21. Bao, Y., Zhao, C., Li, Y. & Yun, X. A method of determining heated ancient nephrite jades in China. Sci. Rep. 8, 13523 (2018).10.1038/s41598-018-30564-w ↗