journal article·2022-01-21Open access

Trained laser-patterned carbon as high-performance mechanical sensors

Marco Hepp, Huize Wang, Katharina Derr, Simon Delacroix, Sebastian Ronneberger, Felix F. Loeffler, Benjamin Butz, Volker Strauss

npj Flexible Electronics· Volume 6· Issue 1

Abstract

Abstract We describe the mechanical properties of turbostratically graphitized carbon films obtained by carbon laser-patterning (CLaP) and their application as bending or mechanical pressure sensors. Stable conductive carbonized films were imprinted on a flexible polyethylene terephthalate (PET) substrate by laser-induced carbonization. After initial gentle bending, i.e. training, these sponge-like porous films show a quantitative and reversible change in resistance upon bending or application of pressure in normal loading direction. Maximum response values of ΔR/R0 = 388% upon positive bending (tensile stress) and −22.9% upon negative bending (compression) are implicit for their high sensitivity towards mechanical deformation. Normal mechanical loading in a range between 0 and 500 kPa causes a response between ΔR/R0 = 0 and −15%. The reversible increase or decrease in resistance is attributed to compression or tension of the turbostratically graphitized domains, respectively. This mechanism is supported by a detailed microstructural and chemical high-resolution transmission electron microscopic analysis of the cross-section of the laser-patterned carbon.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Adhesion, Friction, and Surface Interactions · Surface Modification and Superhydrophobicity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Corzo, D., Tostado-Blázquez, G. & Baran, D. Flexible electronics: status, challenges and opportunities. Front. Electron. 1, 594003 (2020).10.3389/felec.2020.594003 ↗
2. Zou, M. et al. Flexible devices: from materials, architectures to applications. J. Semicond. 39, 011010 (2018).10.1088/1674-4926/39/1/011010 ↗
3. Wang, P. et al. The evolution of flexible electronics: from nature, beyond nature, and to nature. Adv. Sci. 7, 2001116 (2020).10.1002/advs.202001116 ↗
4. Nag, A., Mukhopadhyay, S. C. & Kosel, J. Wearable flexible sensors: a review. IEEE Sens. J. 17, 3949–3960 (2017).10.1109/JSEN.2017.2705700 ↗
5. Chortos, A. & Bao, Z. Skin-inspired electronic devices. Mater. Today 17, 321–331 (2014).10.1016/j.mattod.2014.05.006 ↗
6. Wang, X., Liu, Z. & Zhang, T. Flexible sensing electronics for wearable/attachable health monitoring. Small 13, 1602790 (2017).10.1002/smll.201602790 ↗
7. Gong, S. et al. A wearable and highly sensitive pressure sensor with ultrathin gold nanowires. Nat. Commun. 5, 3132 (2014).10.1038/ncomms4132 ↗
8. Amjadi, M., Pichitpajongkit, A., Lee, S., Ryu, S. & Park, I. Highly stretchable and sensitive strain sensor based on silver nanowire–elastomer nanocomposite. ACS Nano 8, 5154–5163 (2014).10.1021/nn501204t ↗
9. Wang, B. et al. Flexible and stretchable metal oxide nanofiber networks for multimodal and monolithically integrated wearable electronics. Nat. Commun. 11, 2405 (2020).10.1038/s41467-020-16268-8 ↗
10. Yao, S. & Zhu, Y. Wearable multifunctional sensors using printed stretchable conductors made of silver nanowires. Nanoscale 6, 2345 (2014).10.1039/c3nr05496a ↗
11. Wang, X., Gu, Y., Xiong, Z., Cui, Z. & Zhang, T. Silk-molded flexible, ultrasensitive, and highly stable electronic skin for monitoring human physiological signals. Adv. Mater. 26, 1336–1342 (2014).10.1002/adma.201304248 ↗
12. Lipomi, D. J. et al. Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes. Nat. Nanotechnol. 6, 788–792 (2011).10.1038/nnano.2011.184 ↗
13. Wang, X. et al. Self-cross-linked arrays enabled flexible mechanical sensors for monitoring the body tremor. npj Flex. Electron. 4, 8 (2020).10.1038/s41528-020-0071-3 ↗
14. Liao, C. et al. Flexible organic electronics in biology: materials and devices. Adv. Mater. 27, 7493–7527 (2015).10.1002/adma.201402625 ↗
15. Zhang, F., Zang, Y., Huang, D., Di, C. & Zhu, D. Flexible and self-powered temperature–pressure dual-parameter sensors using microstructure-frame-supported organic thermoelectric materials. Nat. Commun. 6, 8356 (2015).10.1038/ncomms9356 ↗
16. Ge, G. et al. Muscle-inspired self-healing hydrogels for strain and temperature sensor. ACS Nano 14, 218–228 (2020).10.1021/acsnano.9b07874 ↗
17. Samori, P. & Palermo, V. Flexible Carbon-based Electronics (Wiley-VCH Verlag GmbH & Co. KGaA, 2018)10.1002/9783527804894 ↗
18. Rakitin, A., Papadopoulos, C. & Xu, J. M. Carbon nanotube self-doping: calculation of the hole carrier concentration. Phys. Rev. B 67, 33411 (2003).10.1103/PhysRevB.67.033411 ↗
19. Kuzmany, H. et al. Determination of SWCNT diameters from the Raman response of the radial breathing mode. Eur. Phys. J. B—Condens. Matter Complex Syst. 22, 307–320 (2001).10.1007/s100510170108 ↗
20. Wang, F., Dukovic, G., Brus, L. & Heinz, T. Time-resolved fluorescence of carbon nanotubes and its implication for radiative lifetimes. Phys. Rev. Lett. 92, 17–20 (2004).10.1103/PhysRevLett.92.177401 ↗
21. Tan, P. H. et al. Photoluminescence spectroscopy of carbon nanotube bundles: evidence for exciton energy transfer. Phys. Rev. Lett. 99, 137402 (2007).10.1103/PhysRevLett.99.137402 ↗
22. Gu, Y. et al. Flexible electronic eardrum. Nano Res. 10, 2683–2691 (2017).10.1007/s12274-017-1470-1 ↗
23. Yamamoto, Y. et al. Printed multifunctional flexible device with an integrated motion sensor for health care monitoring. Sci. Adv. 2, e1601473 (2016).10.1126/sciadv.1601473 ↗
24. Yuan, J., Giordano, C. & Antonietti, M. Ionic liquid monomers and polymers as precursors of highly conductive, mesoporous, graphitic carbon nanostructures. Chem. Mater. 22, 5003–5012 (2010).10.1021/cm1012729 ↗
25. Van Noorden, R. Chemistry: the trials of new carbon. Nature 469, 14–16 (2011).10.1038/469014a ↗
26. Ambrosi, A. & Pumera, M. 3D-printing technologies for electrochemical applications. Chem. Soc. Rev. 45, 2740–2755 (2016).10.1039/C5CS00714C ↗
27. Majumdar, J. D. & Manna, I. Laser-Assisted Fabrication of Materials. Springer Series in Materials Science Vol. 161, (Springer, 2013).10.1007/978-3-642-28359-8 ↗
28. Strong, V. et al. Patterning and electronic tuning of laser scribed graphene for flexible all-carbon devices. ACS Nano 6, 1395–1403 (2012).10.1021/nn204200w ↗
29. Kumar, R. et al. Laser-assisted synthesis, reduction and micro-patterning of graphene: Recent progress and applications. Coord. Chem. Rev. 342, 34–79 (2017).10.1016/j.ccr.2017.03.021 ↗
30. Gao, W. et al. Direct laser writing of micro-supercapacitors on hydrated graphite oxide films. Nat. Nanotechnol. 6, 496–500 (2011).10.1038/nnano.2011.110 ↗
31. Sokolov, D. A., Rouleau, C. M., Geohegan, D. B. & Orlando, T. M. Excimer laser reduction and patterning of graphite oxide. Carbon 53, 81–89 (2013).10.1016/j.carbon.2012.10.034 ↗
32. Sokolov, D. A., Shepperd, K. R. & Orlando, T. M. Formation of graphene features from direct laser-induced reduction of graphite oxide. J. Phys. Chem. Lett. 1, 2633–2636 (2010).10.1021/jz100790y ↗
33. Ghoniem, E., Mori, S. & Abdel-Moniem, A. Low-cost flexible supercapacitors based on laser reduced graphene oxide supported on polyethylene terephthalate substrate. J. Power Sources 324, 272–281 (2016).10.1016/j.jpowsour.2016.05.069 ↗
34. Trusovas, R. et al. Reduction of graphite oxide to graphene with laser irradiation. Carbon 52, 574–582 (2013).10.1016/j.carbon.2012.10.017 ↗
35. Bürger, A., Fitzer, E., Heym, M. & Terwiesch, B. Polyimides as precursors for artificial carbon. Carbon 13, 149–157 (1975).10.1016/0008-6223(75)90225-0 ↗
36. Inagaki, M. et al. Carbonization of polyimide film “Kapton”. Carbon 27, 253–257 (1989).10.1016/0008-6223(89)90131-0 ↗
37. Stanford, M. G., Yang, K., Chyan, Y., Kittrell, C. & Tour, J. M. Laser-induced graphene for flexible and embeddable gas sensors. ACS Nano 13, 3474–3482 (2019).10.1021/acsnano.8b09622 ↗
38. Huang, L., Su, J., Song, Y. & Ye, R. Laser-induced graphene: en route to smart sensing. Nano-Micro Lett. 12, 157 (2020).10.1007/s40820-020-00496-0 ↗
39. Ye, R., James, D. K. & Tour, J. M. Laser-induced graphene: from discovery to translation. Adv. Mater. 31, 1803621 (2019).10.1002/adma.201803621 ↗
40. Mamleyev, E. R. et al. Laser-induced hierarchical carbon patterns on polyimide substrates for flexible urea sensors. npj Flex. Electron. 3, 2 (2019).10.1038/s41528-018-0047-8 ↗
41. Lin, J. et al. Laser-induced porous graphene films from commercial polymers. Nat. Commun. 5, 5714 (2014).10.1038/ncomms6714 ↗
42. Strauss, V., Marsh, K., Kowal, M. D., El-Kady, M. F. & Kaner, R. B. A simple route to porous graphene from carbon nanodots for supercapacitor applications. Adv. Mater. 30, 1704449 (2018).10.1002/adma.201704449 ↗
43. Delacroix, S., Wang, H., Heil, T. & Strauss, V. Laser‐induced carbonization of natural organic precursors for flexible electronics. Adv. Electron. Mater. 6, 2000463 (2020).10.1002/aelm.202000463 ↗
44. Wang, H. et al. Laser-carbonization: peering into the formation of micro-thermally produced (N-doped)carbons. Carbon 176, 500–510 (2021).10.1016/j.carbon.2021.01.145 ↗
45. Delacroix, S. et al. Using carbon laser patterning to produce flexible, metal-free humidity sensors. ACS Appl. Electron. Mater. 2, 4146–4154 (2020).10.1021/acsaelm.0c00942 ↗
46. Wang, H. et al. In situ synthesis of molybdenum carbide nanoparticles incorporated into laser‐patterned nitrogen‐doped carbon for room temperature VOC sensing. Adv. Funct. Mater. 31, 2104061 (2021).10.1002/adfm.202104061 ↗
47. Holm, R. Electric Contacts (Springer, 1967).10.1007/978-3-662-06688-1 ↗
48. Pantea, D., Darmstadt, H., Kaliaguine, S. & Roy, C. Electrical conductivity of conductive carbon blacks: influence of surface chemistry and topology. Appl. Surf. Sci. 217, 181–193 (2003).10.1016/S0169-4332(03)00550-6 ↗
49. Adinaveen, T., Vijaya, J. J. & Kennedy, L. J. Comparative study of electrical conductivity on activated carbons prepared from various cellulose materials. Arab. J. Sci. Eng. 41, 55–65 (2016).10.1007/s13369-014-1516-6 ↗
50. Sánchez-González, J., Macías-García, A., Alexandre-Franco, M. F. & Gómez-Serrano, V. Electrical conductivity of carbon blacks under compression. Carbon 43, 741–747 (2005).10.1016/j.carbon.2004.10.045 ↗
51. Shi, J. et al. Graphene reinforced carbon nanotube networks for wearable strain sensors. Adv. Funct. Mater. 26, 2078–2084 (2016).10.1002/adfm.201504804 ↗
52. Zhang, W., Liu, Q. & Chen, P. Flexible strain sensor based on carbon black/silver nanoparticles composite for human motion detection. Materials 11, 1836 (2018).10.3390/ma11101836 ↗
53. Mitchell, M., Muftakhidinov, B. & Winchen, T. Engauge Digitizer Software. Available at: http://markummitchell.github.io/engauge-digitizer (2021).