journal article·2018-06-04Open access

Multiscale nanowire-microfluidic hybrid strain sensors with high sensitivity and stretchability

Songjia Han, Chunrui Liu, Huihua Xu, Dongyuan Yao, Kanghong Yan, Huanliang Zheng, Hui-Jiuan Chen, Xuchun Gui, Sheng Chu, Chuan Liu

npj Flexible Electronics· Volume 2· Issue 1

Abstract

Abstract Nanomaterials with low-dimensional morphology have been explored for enhancing the performance of strain sensors, but it remains difficult to achieve high stretchability and sensitivity simultaneously. In this work, a composite structure strain sensor based on nanomaterials and conductive liquid is designed, demonstrated, and engineered. The nanowire-microfluidic hybrid (NMH) strain sensor responds to multiscale strains from 4% to over 400%, with a high sensitivity and durability under small strain. Metal nanowires and carbon nanotubes are used to fabricate the NMH strain sensors, which simultaneously exhibit record-high average gauge factors and stretchability, far better than the conventional nanowire devices. Quantitative modeling of the electrical characteristics reveals that the effective conductivity percolation through the hybrid structures is the key to achieving high gauge factors for multiscale sensing. The sensors can operate at low voltages and are capable of responding to various mechanical deformations. When fixed on human skin, the sensors can monitor large-scale deformations (skeleton motion) and small-scale deformations (facial expressions and pulses). The sensors are also employed in multichannel, interactive electronic system for wireless control of robotics. Such demonstrations indicate the potential of the sensors as wearable detectors for human motion or as bionic ligaments in soft robotics.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications · Tactile and Sensory Interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Xiao, X. et al. High-strain sensors based on ZnO nanowire/polystyrene hybridized flexible films. Adv. Mater. 23, 5440–5444 (2011).10.1002/adma.201103406 ↗
2. Cohen, D. J., Mitra, D., Peterson, K. & Maharbiz, M. M. A highly elastic, capacitive strain gauge based on percolating nanotube networks. Nano Lett. 12, 1821–1825 (2012).10.1021/nl204052z ↗
3. Amjadi, M., Kyung, K.-U., Park, I. & Sitti, M. Stretchable, skin-mountable, and wearable strain sensors and their potential applications: a review. Adv. Funct. Mater. 26, 1678–1698 (2016).10.1002/adfm.201504755 ↗
4. Cai, L. et al. Super-stretchable, transparent carbon nanotube-based capacitive strain sensors for human motion detection. Sci. Rep. 3, 3048 (2013).10.1038/srep03048 ↗
5. Shin, U.-H. et al. Highly stretchable conductors and piezocapacitive strain gauges based on simple contact-transfer patterning of carbon nanotube forests. Carbon 80, 396–404 (2014).10.1016/j.carbon.2014.08.079 ↗
6. Yao, S. & Zhu, Y. Wearable multifunctional sensors using printed stretchable conductors made of silver nanowires. Nanoscale 6, 2345–2352 (2014).10.1039/c3nr05496a ↗
7. Roh, E., Hwang, B. U., Kim, D., Kim, B. Y. & Lee, A. N. E. Stretchable, transparent, ultrasensitive, and patchable strain sensor for human-machine interfaces comprising a nanohybrid of carbon nanotubes and conductive elastomers. ACS Nano 9, 9 (2015).10.1021/acsnano.5b01613 ↗
8. Yi, F. et al. Stretchable-rubber-based triboelectric nanogenerator and its application as self-powered body motion sensors. Adv. Funct. Mater. 25, 3688–3696 (2015).10.1002/adfm.201500428 ↗
9. Liu, Z. et al. Thickness-gradient films for high gauge factor stretchable strain sensors. Adv. Mater. 27, 6230–6237 (2015).10.1002/adma.201503288 ↗
10. Zhou, J. et al. Flexible piezotronic strain sensor. Nano Lett. 8, 5 (2008).
11. Amjadi, M., Yoon, Y. J. & Park, I. Ultra-stretchable and skin-mountable strain sensors using carbon nanotubes-Ecoflex nanocomposites. Nanotechnology 26, 375501 (2015).10.1088/0957-4484/26/37/375501 ↗
12. Yamada, T. et al. A stretchable carbon nanotube strain sensor for human-motion detection. Nat. Nanotechnol. 6, 296–301 (2011).10.1038/nnano.2011.36 ↗
13. Wang, T., Wang, R., Cheng, Y. & Sun, J. Quasi in situ polymerization to fabricate copper nanowire-based stretchable conductor and its applications. ACS Appl. Mater. Interfaces 8, 9297–9304 (2016).10.1021/acsami.5b11143 ↗
14. Gong, S. et al. Tattoolike polyaniline microparticle-doped gold nanowire patches as highly durable wearable sensors. ACS Appl. Mater. Interfaces 7, 19700–19708 (2015).10.1021/acsami.5b05001 ↗
15. Gong, S. et al. Highly stretchy black gold E-skin nanopatches as highly sensitive wearable biomedical sensors. Adv. Electron. Mater. 1, 1400063 (2015).10.1002/aelm.201400063 ↗
16. Boland, C. S. et al. Sensitive, high-strain, high-rate bodily motion sensors based on graphene-rubber composites. ACS Nano 8, 11 (2014).10.1021/nn503454h ↗
17. Yan, C. et al. Highly stretchable piezoresistive graphene-nanocellulose nanopaper for strain sensors. Adv. Mater. 26, 2022–2027 (2014).10.1002/adma.201304742 ↗
18. Jeong, Y. R. et al. Highly stretchable and sensitive strain sensors using fragmentized graphene foam. Adv. Funct. Mater. 25, 4228–4236 (2015).10.1002/adfm.201501000 ↗
19. Mattmann, C., Clemens, F. & Troster, G. Sensor for measuring strain in textile. Sensors (Basel) 8, 3719–3732 (2008).10.3390/s8063719 ↗
20. Kong, J.-H., Jang, N.-S., Kim, S.-H. & Kim, J.-M. Simple and rapid micropatterning of conductive carbon composites and its application to elastic strain sensors. Carbon 77, 199–207 (2014).10.1016/j.carbon.2014.05.022 ↗
21. Li, Q. et al. Wide-range strain sensors based on highly transparent and supremely stretchable graphene/Ag-nanowires hybrid structures. Small 12, 5058–5065 (2016).10.1002/smll.201600487 ↗
22. Zhang, H. et al. Piezoresistive sensor with high elasticity based on 3D hybrid network of sponge@CNTs@Ag NPs. ACS Appl. Mater. Interfaces 8, 22374–22381 (2016).10.1021/acsami.6b04971 ↗
23. Amjadi, M., Pichitpajongkit, A., Lee, S., Ryu, S. & Park, I. Highly stretchable and sensitive strain sensor based on silver nanowire–elastomer nanocomposite. ACS Nano 8, 9 (2014).10.1021/nn501204t ↗
24. Zhang, S. et al. Fully printed silver-nanoparticle-based strain gauges with record high sensitivity. Adv. Electron. Mater. 3, 1700067 (2017).10.1002/aelm.201700067 ↗
25. Park, B. et al. Dramatically enhanced mechanosensitivity and signal-to-noise ratio of nanoscale crack-based sensors: effect of crack depth. Adv. Mater. 28, 8130–8137 (2016).10.1002/adma.201602425 ↗
26. Yang, T. et al. Structural engineering of gold thin films with channel cracks for ultrasensitive strain sensing. Mater. Horiz. 3, 248–255 (2016).10.1039/C6MH00027D ↗
27. Kang, D. et al. Ultrasensitive mechanical crack-based sensor inspired by the spider sensory system. Nature 516, 222–226 (2014).10.1038/nature14002 ↗
28. Choi, D. Y. et al. Highly stretchable, hysteresis-free ionic liquid-based strain sensor for precise human motion monitoring. ACS Appl. Mater. Interfaces 9, 1770–1780 (2017).10.1021/acsami.6b12415 ↗
29. Wang, C. et al. Carbonized silk fabric for ultrastretchable, highly sensitive, and wearable strain sensors. Adv. Mater. 28, 6640–6648 (2016).10.1002/adma.201601572 ↗
30. Ge, J. et al. A stretchable electronic fabric artificial skin with pressure-, lateral strain-, and flexion-sensitive properties. Adv. Mater. 28, 722–728 (2016).10.1002/adma.201504239 ↗
31. Kim, K. K. et al. Highly sensitive and stretchable multidimensional strain sensor with prestrained anisotropic metal nanowire percolation networks. Nano Lett. 15, 5240–5247 (2015).10.1021/acs.nanolett.5b01505 ↗
32. Muth, J. T. et al. Embedded 3D printing of strain sensors within highly stretchable elastomers. Adv. Mater. 26, 6307–6312 (2014).10.1002/adma.201400334 ↗
33. Rahimi, R., Ochoa, M., Yu, W. & Ziaie, B. Highly stretchable and sensitive unidirectional strain sensor via laser carbonization. ACS Appl. Mater. Interfaces 7, 4463–4470 (2015).10.1021/am509087u ↗
34. Yao, S. & Zhu, Y. Nanomaterial-enabled stretchable conductors: strategies, materials and devices. Adv. Mater. 27, 1480–1511 (2015).10.1002/adma.201404446 ↗
35. Lu, N., Lu, C., Yang, S. & Rogers, J. Highly sensitive skin-mountable strain gauges based entirely on elastomers. Adv. Funct. Mater. 22, 4044–4050 (2012).10.1002/adfm.201200498 ↗
36. Hwang, B. U. et al. Transparent stretchable self-powered patchable sensor platform with ultrasensitive recognition of human activities. ACS Nano 9, 9 (2015).
37. Liu, Q., Chen, J., Li, Y. & Shi, G. High-performance strain sensors with fish-scale-like graphene-sensing layers for full-range detection of human motions. ACS Nano 10, 7901–7906 (2016).10.1021/acsnano.6b03813 ↗
38. Ding, S. et al. One-step fabrication of stretchable copper nanowire conductors by a fast photonic sintering technique and its application in wearable devices. ACS Appl. Mater. Interfaces 8, 6190–6199 (2016).10.1021/acsami.5b10802 ↗
39. Xu, F. & Zhu, Y. Highly conductive and stretchable silver nanowire conductors. Adv. Mater. 24, 5117–5122 (2012).10.1002/adma.201201886 ↗
40. Liu, Y. L. et al. Stretchable electrochemical sensor for real-time monitoring of cells and tissues. Angew. Chem. Int. Ed. 55, 4537–4541 (2016).10.1002/anie.201601276 ↗
41. De Vivo, B. et al. Simulation and experimental characterization of polymer/carbon nanotubes composites for strain sensor applications. J. Appl. Phys. 116, 054307 (2014).10.1063/1.4892098 ↗
42. Matsuzaki, R. & Tabayashi, K. Highly stretchable, global, and distributed local strain sensing line using GaInSn electrodes for wearable electronics. Adv. Funct. Mater. 25, 3806–3813 (2015).10.1002/adfm.201501396 ↗
43. Jidong, S. et al. Graphene reinforced carbon nanotube networks for wearable strain sensors. Adv. Funct. Mater. 26, 2078–2084 (2016).10.1002/adfm.201504804 ↗
44. Zhu, Y. & Xu, F. Buckling of aligned carbon nanotubes as stretchable conductors: a new manufacturing strategy. Adv. Mater. 24, 1073–1077 (2012).10.1002/adma.201103382 ↗
45. Pang, C. et al. Highly skin-conformal microhairy sensor for pulse signal amplification. Adv. Mater. 27, 634–640 (2015).10.1002/adma.201403807 ↗
46. Kim, J. et al. Stretchable silicon nanoribbon electronics for skin prosthesis. Nat. Commun. 5, 5747 (2014).10.1038/ncomms6747 ↗
47. Zhong, Z. et al. Roll-to-roll-compatible, flexible, transparent electrodes based on self-nanoembedded Cu nanowires using intense pulsed light irradiation. Nanoscale 8, 8995–9003 (2016).10.1039/C6NR00444J ↗